Epifluorohydrin
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Epifluorohydrin
structure -
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CAS No:
503-09-3
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Formula:
C3H5FO
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Chemical Name:
Epifluorohydrin
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Synonyms:
Oxirane,2-(fluoromethyl)-;Propane,1,2-epoxy-3-fluoro-;Epifluorohydrin;Oxirane,(fluoromethyl)-;2-(Fluoromethyl)oxirane;3-Fluoropropene 1,2-oxide;1,2-Epoxy-3-fluoropropane;(Fluoromethyl)oxirane;1-Fluoro-2,3-epoxypropane;Oxirane,(fluoromethyl)-,(±)-;3-Fluoro-1,2-epoxypropane;NSC 21303;NSC 88608;(±)-2-(Fluoromethyl)oxirane;103129-23-3
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CAS No:
Description
clear colourless liquid
Epifluorohydrin is a clear colorless liquid. (NTP, 1992)
Epifluorohydrin is a clear colorless liquid. (NTP, 1992)
Characteristics
12.5
0.35470
Epifluorohydrin is a clear colorless liquid. (NTP, 1992)
1.090 g/cm3 @ Temp: 20 °C
85.5 °C
40 °F
n20/D 1.368(lit.)
greater than or equal to 100 mg/mL at 61° F (NTP, 1992)
0-6°C
Highly flammable. Water soluble.
Halogenated Organic Compounds
Highly Flammable
A halogenated epoxide. Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts. The chlorinated derivative has been shown to be incompatible with aniline, strong oxidizers, sulfuric acid, isopropylamine, zinc, aluminum, iron, etc. see epichlorohydrin.
Safety Information
I
6.1(a)
UN 2924 3/PG 2
3
11-23/24/25-34
16-26-45-38-36/37/39-33
TZ3325000
F,T
Flammable/Highly Toxic
P210-P261-P280-P301 + P310-P305 + P351 + P338-P310
H225-H301-H311-H314-H331
This chemical is flammable. (NTP, 1992)
Fires involving this material can be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
Excerpt from ERG Guide 131 [Flammable Liquids - Toxic]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material in a refrigerator. STORE AWAY FROM SOURCES OF IGNITION. (NTP, 1992)
RECOMMENDED RESPIRATOR: When working with this chemical, wear a NIOSH-approved full face chemical cartridge respirator equipped with the appropriate organic vapor cartridges. If that is not available, a half face respirator similarly equipped plus airtight goggles can be substituted. However, please note that half face respirators provide a substantially lower level of protection than do full face respirators. (NTP, 1992)
Drug Information
ACUTE/CHRONIC HAZARDS: This compound is a lacrimator. When heated to decomposition it emits toxic fumes. (NTP, 1992)
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Computed Properties
Molecular Weight:76.07
XLogP3:-0.2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:76.032442941
Monoisotopic Mass:76.032442941
Topological Polar Surface Area:12.5
Heavy Atom Count:5
Complexity:37.9
Undefined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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