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Home > Encyclopedia > Zinc dibutyldithiocarbamate

Zinc dibutyldithiocarbamate

Zinc dibutyldithiocarbamate structure

Zinc dibutyldithiocarbamate 

structure
  • CAS No:

    136-23-2

  • Formula:

    C18H36N2S4Zn

  • Chemical Name:

    Zinc dibutyldithiocarbamate

  • Synonyms:

    Zinc,bis(dibutylcarbamodithioato-κS,κS′)-,(T-4)-;Zinc,bis(dibutyldithiocarbamato)-;Zinc,bis(dibutylcarbamodithioato-S,S′)-,(T-4)-;Carbamodithioic acid,dibutyl-,zinc complex;(T-4)-Bis(dibutylcarbamodithioato-κS,κS′)zinc;Aceto ZDBD;Butazate;Butazate 50D;Butyl zimate;Dibutyldithiocarbamic acid zinc salt;Vulcacure ZB;Zinc dibutyldithiocarbamate;Zinc N,N-dibutyldithiocarbamate;Soxinol BZ;(Dibutyldithiocarbamato)zinc(II);Bis(dibutyldithiocarbamato)zinc;Zinc bis(dibutyldithiocarbamate);Carbamodithioic acid,dibutyl-,zinc salt;Bis(N,N-dibutyldithiocarbamato)zinc;Butyl ziram;Vulkacit LDB;Zinc bis(N,N-dibutyldithiocarbamate);Accel BZ;Nocceler BZ;ZnBDC;Vulkacit LDS;Sanceler BZ;Perkacit ZDBC;Nocceler BZ-P;Nocceler BZ-G;Zinc di-n-butylthiocarbamate;NSC 36548;NSC 3880;Vulcafor ZDBC;Rhenogran ZBDC 80;Rhenogran ZDBC 75;Accelerator BZ;Antioxidant BZ;Rhenogran ZDBC 80;ZDBC;BZ;T 202;T 202 (antioxidant);ZDBC 80;BZ-P;ZDBC 50;Rhexon ZDBC 75;T 353;BZ 75;ZDBC 75;Nocceler BZ-S;13497-84-2;20609-60-3;942266-56-0;1192843-75-6;1883563-94-7

  • Categories:

    Cosmetic Ingredient  >  Antioxidant Ingredient

Description

White powder; pleasant odor. Soluble in carbondisulfide, benzene, and chloroform; insolublein water.


DryPowder; DryPowder, PelletsLargeCrystals; DryPowder, WetSolid; Liquid|DryPowder


Zinc dibutyldithiocarbamate is a dermatological sensitizer and allergen. Sensitivity to zinc dibutyldithiocarbamate may be identified with a clinical patch test.

Zinc dibutyldithiocarbamate Basic Attributes

474.14

472.105286

205-232-8

DTXSID2020927

Dark green flakes

2930909090

Characteristics

128.05000

6.73950

DryPowder; DryPowder, PelletsLargeCrystals; DryPowder, WetSolid; Liquid

1.24 g/cm3 @ Temp: 20 °C

104-108 °C

257.7ºC at 760 mmHg

109.6ºC

Sol in carbon disulfide, benzene, chloroform; insol in water

Keep in a cool dry location in a sealed container.

0.0144mmHg at 25°C

Peritoneal-mouse LD50: 100 mg/kg

Flammable; heat produces toxic nitrogen oxides, sulfur oxides and zinc oxide fumes

Pleasant odor

Safety Information

III

9

3077

36/37/38-50/53-43

26-36/37/39-61-60-37-24

ZH0175000

Xi,N

Treasury is ventilated, low temperature and dry; stored separately from food materials

Stable at normal temperatures and pressures.

P261, P271, P272, P273, P280, P302+P352, P304+P340, P312, P321, P333+P313, P363, P391, P403+P233, P405, P501

H317

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

|Danger|H317 (14.29%): May cause an allergic skin reaction [Warning Sensitization, Skin]|P201, P202, P261, P264, P272, P273, P280, P281, P285, P302+P352, P304+P341, P305+P351+P338, P308+P313, P321, P333+P313, P337+P313, P342+P311, P363, P405, and P501|Aggregated GHS information provided by 11 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Not Classified|H350: May cause cancer [Danger Carcinogenicity]|P201, P202, P281, P308+P313, P405, and P501

Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 1 mg/cu m. /Nickel, metal and insoluble cmpd, as Ni/

NIOSH considers nickel metal and other compounds (as Ni) to be a potential occupational carcinogen. /Nickel metal and other compounds (as Ni)/|NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. /Nickel metal and other compounds (as Ni)/|Recommended Exposure Limit: 10 Hr TWA 0.015 mg/cu m. /Nickel metal and other compounds (as Ni)/

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Nickel, bis(dibutyldithiocarbamato)- is included on this list.

Toxicity

highly toxic

Drug Information

Zinc dibutyldithiocarbamate is approved for use within allergenic epicutaneous patch tests which are indicated for use as an aid in the diagnosis of allergic contact dermatitis (ACD) in persons 6 years of age and older.

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilation if necessary. Administer oxygen by nonrebreather mask at 10 t0 15 L/min. Monitor for shock and treat if necessary ... . Monitor for pulmonary edema and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . /Nickel and related compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Positive pressure ventilation techniques with a bag valve mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Consider drug therapy for pulmonary edema ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors for hypotension with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Nickel and related compounds/

Zinc dibutyldithiocarbamate Use and Manufacturing

Methods of Manufacturing

REACTION OF AQUEOUS SOLUTIONS OF SODIUM DIBUTYLDITHIOCARBAMATE AND NICKEL CHLORIDE, ACETATE, OR SULFATE

Uses

Accelerator for latex dispersions and cements,etc; ultra-accelerator for lubricating oil additive.It is an effective peroxide decomposer, often used in combination with the main antioxidant, used in polypropylene, polyvinyl chloride, and also used as a rubber adhesive, latex curing accelerator, natural rubber, synthetic rubber and latex super accelerator.


Adhesives and sealant chemicals|Processing aids, not otherwise listed


Adhesives and sealants

Production

1,000,000 - 10,000,000 lb|< 25,000 lb|(1972) PROBABLY GREATER THAN 4.54X10+5 GRAMS|(1975) PROBABLY GREATER THAN 4.54X10+5 GRAMS

"NBC" /IS DU PONT DE NEMOURS, EI & CO/ DESIGNATION FOR NICKEL DIBUTYLDITHIOCARBAMATE.|RYLEX NBC|VANGUARD N

Adhesive manufacturing|Zinc, bis(dibutylcarbamodithioato-.kappa.S,.kappa.S')-, (T-4)-: ACTIVE|Rubber product manufacturing|Nickel, bis(N,N-dibutylcarbamodithioato-.kappa.S,.kappa.S')-, (SP-4-1)-: ACTIVE

STABILIZERS

Computed Properties

Molecular Weight:474.1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:12
Exact Mass:472.105276
Monoisotopic Mass:472.105276
Topological Polar Surface Area:72.7
Heavy Atom Count:25
Complexity:272
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

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