2-Methylindoline
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2-Methylindoline
structure -
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CAS No:
6872-06-6
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Formula:
C9H11N
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Chemical Name:
2-Methylindoline
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Synonyms:
1H-Indole,2,3-dihydro-2-methyl-;Indoline,2-methyl-;2,3-Dihydro-2-methyl-1H-indole;2-Methylindoline;2-Methyl-2,3-dihydroindole;2,3-Dihydro-2-methylindole;α-Methyldihydroindole;NSC 65598;2-Methyl-2,3-dihydro-1H-indole;2-Methyl-1H-indoline;(±)-2-Methylindoline;138380-84-4
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CAS No:
Characteristics
12
2.4
Clear yellow to brown Liquid
1.023 g/mL at 25 °C(lit.)
60.0-61.0 °C
115-117 °C
200 °F
n20/D 1.569(lit.)
H2O: negligible soluble
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Safety Information
NONH for all modes of transport
3
36/37/38-52/53-22
26-36/37/39-60-57
NM1926350
Xi,Xn
Irritant
Stable under normal temperatures and pressures.
P261-P305 + P351 + P338
H315-H319-H335
|Warning|H302 (27.59%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P391, P403+P233, P405, and P501|Aggregated GHS information provided by 74 companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
2-Methylindoline Use and Manufacturing
From the hydrogenation of 2-methylindole. Heat a mixture of 130 parts of 2-methylindole, 100 parts of water and zinc amalgam (made from 196 parts of zinc) to 90°C, add 626 parts of concentrated hydrochloric acid within 30 minutes, and heat at 90-100°C for 90 minutes, Sodium hydroxide solution was added to make it alkaline, distilled, and the distillate was extracted with benzene. 2-methyl indoline was obtained.
2-Methylindoline is an intermediate in the production of various indole derivatives
1H-Indole, 2,3-dihydro-2-methyl-: INACTIVE
Computed Properties
Molecular Weight:133.19
XLogP3:2.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Exact Mass:133.089149355
Monoisotopic Mass:133.089149355
Topological Polar Surface Area:12
Heavy Atom Count:10
Complexity:122
Undefined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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