Metribuzin
2 Inquiries
21087-64-9
Agricultural Grade
98%
QINGDAO
1kg/0.2kg Bag
2016-09-05
Glufosinate-ammonium ,tricyclazole ,Amitraz ,Dimethomorph ,Triazinone ,4-Methyl-2-hydrazino benzothiazole
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Product Description
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Seller Information
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Inquiry History
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Description
The toxicity of Low toxicity for human. Rat acute oral LD50 is 1100-2300 mg/kg, in rats with acute percutaneous LD50 > 20000 mg/kg. Chronic toxicity test did not see abnormalities. Two years full feed dogs and rats no effect dose of 100 mg/kg. The fish and aquatic organisms, the birds and the bees are low toxicity.
The English common name metribuzin
The name of the other Metribuzin, cyc (Sencor) and Eric (Lexone), Beyer94337, a grass lamictal.
Chemical name: amino - 4-6 - (1, 1-2 methyl ethyl) - 3 - methyl sulfonium - 1, 4-trichlorobenzene triazine - 5 - four hydrogen.
The physical and chemical properties Single product is colorless crystalline, density 1. 28 g/cm3 (20 ℃), melting point 125.5 ℃ to 126.5 ℃. 20 ℃ solubility in water of 1.2 g/l. , 120 g/L toluene, methanol, 450 g/L.
Formulations were 50%, 70% wettable powder, 50% dry suspending agent.
Characteristics is the selective herbicide, absorbed by the root, stem, leaf also can be absorbed. For 1 year broadleaf weeds and part of gramineous weeds has good control effect, the perennial weeds is invalid. Efficacy of how much affected by soil type, organic matter content, humidity, temperature influence is bigger, the strict conditions of use, improper use, or invalid, or producing the adr.
Scope of application Apply soy, potato, tomato, alfalfa, asparagus, crops such as sugar cane field control smartweed, amaranth and quinoa, mustard, potentilla, chickweed, buckwheat vines, Chinese mosla herb, a. annua, ghost needle grass, green bristlegrass, duck plantar grass, xanthium sibiricum, morel, digitaria, wild oats born broadleaf and grass in part 1 in gramineous weeds.
Method of use
1. Soybean fields use Before spring soybean seeding, with 70% wettable powder per acre 53-76 grams, 30 kilograms of water, soil surface evenly spray cloth. Before the summer soybean after sowing, with 70% wettable powder 33 per acre - 57 grams, spring soybean processing.
2. Potato fields use Use before seeding emergence, per mu with 70% wettable powder 66-76 grams, 30 kilograms of water, soil surface evenly spray cloth, used after emergence, generally at the potato plant height more than 10 cm, resistance to drop, easy generation the adr.
Matters needing attention
1. Soybean fields can only be used before seedling, seedling stage using the adr.
2. Sandy soil organic matter content less than 2% under unfavorable use.
3. High temperature low organic matter content areas, the medication with a low limit, in contrast with the high limit.
4. On or after every other crops are Chinese cabbage, pea under such as have the adr, pay attention to use period.
Basic Info-
Product Name:
Metribuzin
Other Name:1,2,4-Triazin-5(4H)-one,4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-;as-Triazin-5(4H)-one,4-amino-6-tert-butyl-3-(methylthio)-;4-Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one;4-Amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H)-one;BAY 94337;4-Amino-6-tert-butyl-3-(methylthio)-1,2,4-triazin-5-one;Sencor;Metribuzin;BAY 61597;4-Amino-6-tert-butyl-3-(methylthio)-1,2,4-triazin-5(4H)-one;4-Amino-6-tert-butyl-3-(methylthio)-4,5-dihydro-1,2,4-triazin-5-one;Bayer 6159;Sencorex;BAY 6159H;BAY 6159;Lexone;4-Amino-6-tert-butyl-3-(methylthio)-1,2,4-triazine-5(4H)-one;3-Methylthio-4-amino-6-tert-butyl-1,2,4-triazin-5-one;3-Methylthio-4-amino-6-tert-butyl-1,2,4-triazin-5(4H)-one;Sencorex L.F.;Sencor 4F;Sencor 75DF;Lexone DF;Metribuzine;Senkor;DPX 2504;Zontran;DIC 1468;4-Amino-6-tert-butyl-4,5-dihydro-3-methylthio-1,2,4-triazin-5-one;Sencor 480;Soccer;Soccer (herbicide);Tribute;Tribute (metribuzin herbicide);Sencor Extra;Sencor 70 WG;Sencor SC;Qincaotong;Metribuzin 70 WP
CAS No.:21087-64-9
UN No.:3077
Molecular Formula:C8H14N4OS
InChIKeys:InChIKey=FOXFZRUHNHCZPX-UHFFFAOYSA-N
Molecular Weight:214.28800
Exact Mass:214.29
EC Number:244-209-7
UNII:QO836138OV
ICSC Number:0516
UN Number:3077
DSSTox ID:DTXSID6024204
Color/Form:Colorless crytals|White crystalline solid
HScode:2933699014
Categories:
Characteristics-
PSA:
99.10000
XLogP3:0.95270
Appearance:Metribuzin is a colorless crystalline solid. Used as an herbicide. (NIOSH, 2016)
Density:1.28 g/cm3 @ Temp: 20 °C
Melting Point:126.2 °C
Boiling Point:132 °C @ Press: 0.02 Torr
Flash Point:142.7ºC
Refractive Index:1.617
Water Solubility:Slightly soluble
Storage Conditions:APPROX 4ºC
Vapor Pressure:0.000531mmHg at 25°C
Toxicity:LD50 orally in rats: 2200 mg/kg; LC50 in rainbow trout: >10 ppm (Loeser, Kimmerle)
Flammability characteristics:Noncombustible Solid
Odor:Weak characteristic odor
Dissociation Constants:pKa= 1.0
Collision Cross Section:150.5 Ų [M+H]+ [CCS Type: DT, Method: stepped-field]|171.27 Ų [M+Na]+ [CCS Type: DT, Method: stepped-field]|146.95 Ų [M+H]+ [CCS Type: TW]|150.94 Ų [M-H]-|149.5 Ų [M+H]+
Experimental Properties:Slight sulfurous odor /Technical metribuzin/
Air and Water Reactions:No rapid reaction with air. No rapid reaction with water.
Reactive Group:Amides and Imides
Reactivity Profile:A triazine derivative. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
Flammable Limits:Noncombustible Solid
Corrosivity:Non-corrosive
Hazard IdentificationClassification of the substance or mixture
Acute toxicity - Category 4, Oral
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
GHS label elements, including precautionary statements
Pictogram(s)
Signal word Warning
Hazard statement(s) H302 Harmful if swallowed
H410 Very toxic to aquatic life with long lasting effects
Precautionary statement(s) Prevention P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
Response P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P391 Collect spillage.
Storage none
Disposal P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
Other hazards which do not result in classification
no data available
Handling and StoragePrecautions for safe handling
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Store in an area without drain or sewer access.Estimated shelf life in excess of 2 yr under normal storage conditions.
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Seller Information
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Business Type:
Manufactory
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Main Products:
Glufosinate-ammonium,tricyclazole,Amitraz,Dimethomorph,Triazinone,4-Methyl-2-hydrazino benzothiazole
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Location:
Guannan heap groove port town of chemical industrial park
Hang lung crop protection co., LTD., jiangsu changzhou wujin henglong pesticide co., LTD and jiangsu yabang investment holding group cooperation of new pesticide chemical industry enterprises. Company is located in lianyungang city chemical industrial park, east yellow sea, south depends on the river, west coastal highway, the amphibious transportation is convenient. New company of changzhou wujin henglong pesticide co., LTD., pesticide production technology advantages and resources advantages of jiangsu yabang investment holding group, the combination of strive to become bigger and stronger pesticide industry. The company registered capital of 100 million yuan, with a total investment of 350 million, covers an area of 100000 square meters, building area of 90000 square meters. Company is a comprehensive pesticide production enterprises, the product covers herbicide, fungicide, insecticide and pesticide intermediates. The main products are grass oxazine ketone, double amidine, dimethomorph, benzene of pine, imidacloprid, triazine ketone, etc. Company existing staff 280, chemical and other professional engineering and technical personnel 70, personnel reasonable structure, strong reserve talented person. Pesticide company has advanced production equipment, advanced production technology and perfect production monitoring, detection means, scientific research and production integration, with well-known multinational companies have long-term and stable technical cooperation and trade. Company with credibility and sincerity for the industry is fundamental, in line with "quality and enterprise coexistence, credibility with the user, the product on a par with the international" tenet, with the idea of "honesty" and "truthfulness", actively develop new pesticides and pesticide intermediates, pesticide business around the world to provide quality and cheap products. Willing to work with pesticide industry colleagues to join hands in creating a better tomorrow.
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Inquiry History2 Inquiries
Country Product Purchase Quantity Date Posted
Jordan
METRIBUZIN
2000 KG Jul 29, 2024
Egypt
metribuzin
10 TON Apr 15, 2025 Post an enquiry for this product