SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified, according to the CLP regulation.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008: Not applicable.
Hazard pictograms: Not applicable.Page 2/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 08.02.2021
Revision: 08.02.2021
Version number 1
Trade name: Tripotassium citrate monohydrate
(Contd. of page 1)
51.1.4
Signal word: Not applicable.
Hazard statements: Not applicable.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: No PBT.
vPvB: No vPvB.
SECTION 3: Composition/information on ingredients
3.1 Substances
CAS Number. Description.
6100-05-6 Tripotassium citrate monohydrate
Identification number(s)
EC number: 212-755-5
SECTION 4: First aid measures
4.1 Description of first aid measures
After inhalation: Move patient to fresh air, if symptoms persist consult a doctor.
After skin contact: Generally the product does not irritate the skin.
After eye contact:
Rinse cautiously with water for several minutes as a precaution. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
After swallowing: Do not induce vomiting; call for medical help immediately.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
5.2 Special hazards arising from the substance or mixture
Carbon monoxide (CO)
Carbon dioxide (CO2)
5.3 Advice for firefighters
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
Additional information:
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Avoid dust formation.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. No special environmental precautions required.
(Contd. on page 3)Page 3/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 08.02.2021
Revision: 08.02.2021
Version number 1
Trade name: Tripotassium citrate monohydrate
(Contd. of page 2)
51.1.4
6.3 Methods and material for containment and cleaning up
Pick up and transfer to properly labelled containers. After cleaning, flush away traces with water.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Avoid contact with the eyes and skin.
Ensure good ventilation/exhaustion at the workplace.
Provide suction extractors if dust is formed.
Do not inhale dust / smoke / mist.
Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
Store in cool, dry conditions in well sealed receptacles.
Information about storage in one common storage facility: Not required.
7.3 Specific end use(s): No further relevant information available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace: Not required.
PNECs
866-84-2 Tripotassium citrate
PNEC 0.44 mg/L (Water (Freshwater))
0.044 mg/L (Water (Marine Water))
3.46 mg/kg sedim. dw (Sediment (Marine Water))
34.6 mg/kg sedim. dw (Sediment (Freshwater))
33.1 mg/kg soil dw (Soil)
1000 mg/L (Sewage Treatment Plant (STP))
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Do not get in eyes, on skin, or on clothing.
Wash hands before breaks and at the end of work.
Keep away from sparks. - No smoking.
Do not eat, drink, smoke or sniff while working.
Immediately remove all soiled and contaminated clothing
Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation.
Protection of hands:
Protective gloves.
(Contd. on page 4)Page 4/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 08.02.2021
Revision: 08.02.2021
Version number 1
Trade name: Tripotassium citrate monohydrate
(Contd. of page 3)
51.1.4
Eye protection:
Safety glasses with side-shields (EN 166).
Body protection: Protective work clothing.
Limitation and supervision of exposure into the environment
Avoid the release of the product into the environment. Comply with local and national law.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form:
Solid.
Crystalline
Colour:
White.
Odour:
Not determined.
Odour threshold:
Not determined.
pH-value:
Not determined.
Melting point/freezing point:
230 °C (Decomposition)
Initial boiling point and boiling range: Decomposes without boiling
Flash point:
Not applicable.
Flammability (solid, gas):
Product is not flammable.
Ignition temperature:
Not determined.
Decomposition temperature:
230 °C
Explosive properties:
Product does not present an explosion hazard.
Explosion limits:
Lower:
Not applicable.
Upper:
Not applicable.
Oxidising properties
Not oxidising.
Vapour pressure:
negligible
Density:
Not determined.
Relative density at 20 °C
1.98
Vapour density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with
Water at 25 °C:
606 g/l
Partition coefficient: n-octanol/water: -0.2 to -1.8 Log Kow (Citric acid)
Viscosity:
Dynamic:
Not applicable.
Kinematic:
Not applicable.
9.2 Other information
No further relevant information available.
SECTION 10: Stability and reactivity
10.1 Reactivity No data available.
(Contd. on page 5)Page 5/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 08.02.2021
Revision: 08.02.2021
Version number 1
Trade name: Tripotassium citrate monohydrate
(Contd. of page 4)
51.1.4
10.2 Chemical stability
Thermal decomposition / conditions to be avoided: Stable at environment temperature.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid
Keep away from heat and direct sunlight.
Keep away from water/moisture, acids and bases.
10.5 Incompatible materials No further relevant information available.
10.6 Hazardous decomposition products Carbon monoxide and carbon dioxide.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
LD/LC50 values:
866-84-2 Tripotassium citrate
Oral LD50
5400 mg/Kg bw (Mouse) ((Read across : citric acid), OECD 401)
Dermal LD50/24h >2000 mg/Kg bw (Rat) ((Read across : citric acid), OECD 402)
Primary irritant effect:
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Serious eye damage/irritation: Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation: Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Based on available data, the classification criteria are not met.
STOT-single exposure: Based on available data, the classification criteria are not met.
STOT-repeated exposure: Based on available data, the classification criteria are not met.
Aspiration hazard: Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:
866-84-2 Tripotassium citrate
LC50/24h
LC50/48h
1535 mg/L (Daphnia Magna) ((Read across : citric acid))
440 mg/L (Fish) ((Read across : citric acid), OECD 203)
12.2 Persistence and degradability Readily Biodegradable.
12.3 Bioaccumulative potential Bioaccumulation is not expected due to log Kow.
12.4 Mobility in soil Not applicable.
12.5 Results of PBT and vPvB assessment
PBT: No PBT.
vPvB: No vPvB.
12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation: Must be specially treated adhering to official regulations.
(Contd. on page 6)Page 6/6
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 08.02.2021
Revision: 08.02.2021
Version number 1
Trade name: Tripotassium citrate monohydrate
(Contd. of page 5)
51.1.4
Uncleaned packaging:
Recommendation:
Packaging that may not be cleansed must be disposed of in the same manner as the product.
SECTION 14: Transport information
14.1 UN Number
ADR, ADN, IMDG, IATA
Not applicable.
14.2 UN proper shipping name
ADR
Not applicable.
ADN, IMDG, IATA
Not applicable.
14.3 Transport hazard class(es)
ADR, ADN, IMDG, IATA
Class
Not applicable.
14.4 Packing group
ADR, IMDG, IATA
Not applicable.
14.5 Environmental hazards
Marine pollutant:
No
14.6 Special precautions for user
Not applicable.
14.7 Transport in bulk according to Annex II
of MARPOL 73/78 and the IBC Code
Not applicable.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment A Chemical Safety Assessment has been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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Safety data sheet
