1.1 Product identifier: Methyl anthranilate CAS Number: 134-20-3
EC number: 205-132-4
1.2 Relevant identified uses of the substance or mixture and uses advised against. Identified use: SU24 Scientific research and development
1.3 Details of the supplier of the safety data sheet Company: EAST CHEMSOURCES LIMITED
Address: No.666 HAIBAIN 12TH ROAD, HUANGDAO QINGDAO,CHINA
In case of emergency contact:
Tel:+86-532-81906761 Fax:+86-532-81906761
SECTION 2: Hazards identification
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Classification of the substance or mixture
Skin Irrit.2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
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Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant R36/38:Irritating to eyes and skin.
Information concerning particular hazards：Not For human and environment:applicable
Other hazards that do not result in classification：No information known.
2.2 Label elements
Labelling according to Regulation (EC) No：1272/2008.The substance is classified and labelled according to the CLP regulation.
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Hazard pictograms：GHS07 Signal word:Warning
Hazard statements:H315 Causes skin irritation. Precautionary statements:
H319 Causes serious eye irritation. P280 Wear protective gloves.
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P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Results of PBT and vPvB assessment ：Not applicable. PBT:Not applicable.
vPvB:Not applicable.
SECTION 3: Composition/information on ingredients.
3.1 Substances
CAS# Designation: 134-20-3 Methyl anthranilate Identification number(s):205-132-4
EC number:205-132-4
SECTION 4: First aid measures
4.1 Description of first aid measures
After inhalation:Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms.
After skin contact :Seek immediate medical advice.Instantly wash with water and soap and rinse thoroughly.
After eye contact: Seek immediate medical advice.Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing:Seek medical treatment.
4.2 Most important symptoms and effects
Both acute and delayed: No further relevant information available.
4.3 Indication of any immediate medical
Attention and special treatment needed:No further relevant information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents:Use carbon dioxide, extinguishing powder or foam. Water may be ineffective but may be used for cooling
5.2 Special hazards arising from the exposed containers.substance or mixture exposed containers.If this product is involved in a fire, the following can be released:Carbon monoxide and carbon dioxide.Nitrogen oxides(NOx)
5.3 Advice for firefighters
Protective equipment:Wear self-contained breathing apparatus. Wear full protective suit.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective
Equipment and emergency procedures:Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions: Ensure adequate ventilation,
Do not allow material to be released to the environment without proper governmental permits.Do not allow product to reach sewage system or water bodies.
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Methods and material for containmentand cleaning up:Do not allow to enter the ground/soil.Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Prevention of secondary hazards: No special measures required.
6.4 Reference to other sections:
See Section 7 for information on safe handling;
See section 8 for information on personal protection equipment; See Section 13 for information on disposal;
SECTION 7: Handing and storage
7.1 Precautions for safe handling
Keep containers tightly sealed.Store in cool, dry place in tightly closed containers. Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:No information known.
7.2 Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and containers:No special requirements. Information about storage in one common storage facility:
Store away from acid chlorides. Store away from acid anhydrides. Store away from chloroformates. Store away from strong bases.
Further information about storage conditions:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers. Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:No information known.
7.3 Specific end use(s):No further relevant information available.
SECTION 8: Exposure controls/personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
8.1 Control parameters
Components with critical values that require monitoring at the workplace:Not required. Additional information: No data
8.2 Exposure controls
Personal protective equipment General protective and hygienic measures:
The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:Use breathing protection with high concentrations.
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Protection of hands: Check protective gloves prior to each use for their proper condition.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Material of gloves:Impervious gloves.
Penetration time of glove material:Not determined. Eye protection:Safety glasses.
Body protection:Protective work clothing.Face protection.
SECTION 9: Physical and chemical properties.
9.1 Information on basic physical and chemical properties General Information
Appearance:
Form:Low melting solid Colour:Colourless Smell: Ester-like
Odour threshold:Not determined. PH-value: Not determined.
Change in condition
Melting point/Melting range: 24 °C Boiling point/Boiling range: 260 °C
Sublimation temperature / start: Not determined Flash point: 104 °C
Inflammability (solid, gaseous)：Not determined. Ignition temperature: 530 °C
Decomposition temperature: Not determined Self-inflammability: Not determined.
Danger of explosion:Product is not explosive. Critical values for explosion:
Lower: 1.4 Vol % Upper: 7.8 Vol %
Steam pressure: Not determined Density at 20°C：1.17 g/cm³ Relative density： Not determined. Vapour density： Not determined.
Evaporation rate： Not determined.
Solubility in / Miscibility withWater at 20°C: 2.9 g/l Alcohols: Soluble
Organic solvents:Soluble in ether.
Partition coefficient (n-octanol/water): Not determined. Viscosity:
Dynamic: Not determined. Kinematic:Not determined.
9.2 Other information
No further relevant information available.
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SECTION 10: Stabilityand reactivity
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- 1 Reactivity ：No information known.
- 2 Chemical stability：Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:No decomposition if used and stored according to specifications.
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- 3 Possibility of hazardous reactions：No dangerous reactions known.
- 4 Incompatible materials: Oxidizing agents
Acid chlorides Acid anhydrides Chloroformates Bases
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- 5 Hazardous decomposition products: Carbon monoxide and carbon dioxide, Nitrogen Oxides(NOx).
SECTION 11: Toxicological information
11.1 Information on toxicological effects. Acute toxicity: No effects known.
LD/LC50 values that are relevant for classification or corrosion:No data. Skin irritation or corrosion:Causes skin irritation.
Eye irritation or corrosion:Causes serious eye irritation. Sensitization：No sensitizing effect known.
Germ cell mutagenicity:No effect known.
Carcinogencity:No classification data on carcinogenic properties of this material is available from the EPA,IARC,NTP,OSHA or ACGIH.
Reproductive toxicity:No effect known.
Specific target organ system toxicity-repeated exposure:No effect known. Specific target organ system toxicity-single exposure:No effect known.
Aspiration hazard:No effect known.
Other information(about experimental toxicology):Reproductive effects have been observed on tests with laboratory animals.Mutagenic effects have been observed on tests with bacteria.
Additional toxicological information:To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:No further relevant information available.
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- 2 Persistence and degradability:No further relevant information available.
- 3 Bioaccumulative potential：No further relevant information available.
- 4 Mobility in soil:No further relevant information available.
Additional ecological information:No further relevant information available. General notes:Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
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Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Avoid transfer into the environment.
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- 5 Results of PBT and vPvB assessment PBT:Not applicable.
VPvB:Not applicable.
12.6 Other adverse effects
No further relevant information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation:Hand over to disposers of hazardous waste.Must be specially treated under adherence to official regulations.Consult state, local or national regulations for proper disposal.
Uncleaned packagings
Recommendation:Disposal must be made according to official regulations.
SECTION 14: Transportinformation
14.1 UN-Number ADR,IMDG,IATA:None
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- 2 UN proper shipping name ADR,IMDG,IATA:None
- 3 Transport hazard class(es) ADR,IMDG,IATA Class:None
- 4 Packing group ADR,IMDG,IATA:None
- 5 Environmental hazards:Not applicable.
- 6 Special precautions for user:Not applicable.
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code:Not applicable.
Transport/Additional information:Not dangerous according to the above specifications.
SECTION 15:Regulatory information
15.1 Safety,health and environmental regulation/legislation specific for the substance or mixture
Australian Inventory of Chemical substance;Substance is listed.
Standard for the Uniform Scheduling of Drugs and poisons: Substance is not listed. National regulations Information about limitation of use: Employment restrictions concerning young persons must be observed.For use only by technically qualified individuals.
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water. Other regulations,limitations and prohibitive regulations
ELINCS(European List of Notified Chemical Substances):Substance is not listed. Substances of very high concern (SVHC) according to REACH, Article 57：Substance is not listed.
REACH - Pre-registered substances：Substance is listed.
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- 2 Chemical safety assessment:
A chemical safety assessment has not been carried out.
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SECTION 16: Other information
Employers should use this information only as a supplement to other information gathered by them,and should make independent judgment of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty,and any use of the product not in conformance with this material safety data sheet,or in combination with any other product or process, is the responsibility of the user.
Department issuing data specification sheet: Health, Safety and Environmental Department.
Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" ICAO(IATA) : International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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