Product Name:Ammonium Bisulfite Solution
Other Name:/
Recommended use of the chemical and restriction on use:Used as a preservative, reducing agent, also used in the manufacture of sulfur dioxide, insurance powder etc.. Supplier’s details:EAST CHEMSOURCES LIMITED NO.666 HAIBIN 12TH ROAD,HUANGDAO,QINGDAO,CHINA Tel:0532-81906761
Emergency tel/Fax:0532-81906761
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
Skin corrosion / irritation category 1C,Eye irritation category 1.
GHS label elements, including the precautionary statements:
![Shop Ammonium Bisulfite 10192-30-0-Detailed Image 2]()
Signal word:Warning
Hazard statement(s):Causes skin irritation,Causes serious eye irritation Prevention:
Prevention: Avoid inhalation of dust or smoke. wash thoroughly after the operation. Wear protective gloves, protective clothing, wear protective goggles, wearing protective masks.
Emergency: Such as: swallow mouth. Do not induce vomiting. Such as skin (or hair) contamination: immediately remove contaminated clothing / off all. Use water to clean the skin / shower. Clothes washing contaminated before reuse. Such as wrong inhalation: remove victim to fresh air, keep breathing and comfortable resting posture. Immediately call a poison center or doctor. If in eyes: use water to rinse a few minutes. Such as wearing video-shaped glasses and can be easily removed, remove contact lenses. Continue rinsing. Immediately call a poison center or doctor.
Storage: Lockup.
Disposal: in accordance with the relevant rules and the disposal of the contents and the container.
Does not cause other risk classification (such as storm risk) or not for other dangerous global unified system.
SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Concentration%
Ammonium Bisulfite
Ammonium sulfite
Ammonium thiosulfate
Water
10192-30-0
10196-04-0
7783- 18-8
7732- 18-5
67.2
3.3
0.60
full to 100%
SECTION 4 FIRST AID MEASURES
Description of necessary first aid measures
Inhalation: remove to fresh air. To maintain airway. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Medical treatment.
Skin contact: wash skin with plenty of water for 15 minutes, remove contaminated clothing and shoes, clothing and wash contaminated before they can be worn, medical treatment.
Eye contact: immediately filed eyelid, with large flows of water for flushing for at least 15 minutes. Medical treatment..
Ingestion: No emetic. If a patient vomiting, make patient incline or left side (if possible, keep your head down position) to maintain airway patency, prevent choking aspiration.
The most important of acute and delayed symptoms/effect.
If necessary, indicate the immediate medical attention and special treatment needed:/
SECTION 5 FIREFIGHTING MEASURES
Applicable and not applicable to the fire extinguishing agent: according to the surrounding environment to choose appropriate fire extinguishing agent. The production of hazardous chemicals: Non-flammable. Don't think that can cause a significant hazard of fire, but still burning container.
Special protective behavior of fire: fire personnel must carry oxygen respirator, wear full protective clothing.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions,protective equipment and emergency procedure:Strengthen the ventilation, avoid dust formation.The evacuation to a safe place, isolation leakage polluted area and restricted access.
Environmental precautions: prevent leakage into the water, sewer.
Depressing and cleaning methods and materials: As far as possible to cut off the source of leakage, do not make the leakage substances into the sewers and restricted areas. A small leak: sand, vermiculite or other inert material absorption. Large spills: constructing dike or dig a hole. Pump is transferred to the tank or exclusive collector, a place to deal with recycled or transported to the waste disposal.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling:Prevent all individual contact, including inhalation. When there is contact, wear protective clothing.
Conditions for safe storage,including any incompatibilities:Store in original container.Keep the container sealed.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters:/
Appropriate engineering controls:Generally use the local ventilation. If there is excessive contact the material, wear approved respirator.
Personal protective equipment
Eyes protection:Chemical goggles.Full face protection can be used as auxiliary protective eye but cannot do the main protection. Contact lenses may cause a special hazards; soft contact lenses may absorption and accumulation of stimuli.
Skin protection: wear chemical protective gloves (such as PVC).Wear safety shoes or boots (such as rubber material). Note: the substance of susceptible individuals may cause skin allergic reaction. Have to be careful when removing gloves and other protective equipment, as far as possible to avoid contact with skin.
Respiratory protection: in engineering and management control can not effectively prevent the exposure, it may be necessary to use a respirator. Whether to use respiratory protection, should depend on the expertise and judgment.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odour
Odour Threshold
PH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability(Solid,gas)
Upper/lower flammability or explosive limits
Vapour pressure
Vapour density
Relative density
Water solubility
Partition coefficient:noctanol/water
Autoignition temperature
Decomposition temperature
Viscosity
light yellow liquid
/
/
5.5
/
104-111C
/
/
/
/
/
/
1.253 - 1.380
Easy to dissolve in water
/
/
/
/
SECTION 10 STABILITY AND REACTIVITY
Reactivity:/
Chemical stablity:In accordance with the recommendations of disposal and storage stability at room temperature, sealed container under.
Possibility of hazardous reactions: Not polymerize dangerous.
Conditions to avoid:smoking,light,heat or touch fire
Inompatible material: alkali.
Hazardous decomposition products:ecomposition may produce toxic smoke. Nitrogen oxides (NOx), sulfur oxides (SOx)
SECTION 11 TOXICOLOGICAL INFORMATION
Acute health effects
Ingestion:Accidental ingestion of the substance can cause damage to the individual health. Ammonia or injection of large dose of ammonium salt can cause diarrhea, and can be fully absorbed and lead to increased urination and in vivo systemic poisoning. Eyes:If in eyes, severe damage of material will cause the eyes.
Skin: direct contact with the substance can be immediate or delayed for a period of time after the slight but still significant inflammation of the skin. Repeated contact may cause dermatitis, manifested as redness, swelling and blistering.
Inhalation:The respiratory system of the substance can stimulate some people. The body of this stimulus will further cause lung injury.
Chronic health effects:Long-term exposure to respiratory stimuli may lead to organ disease, include difficulty breathing and body tissue diseases. Limited evidence suggests that repeated or long-term occupation exposure may produce relates to health effects of cumulative organ or biochemical system. There is some evidence that, some people inhaled material will more easily than most people allergic reaction.
Numerical measures of toxicity(Such as acute toxicity estimates):/
SECTION 12 ECOLOGICAL INFORMATION
Toxicity:/.
Presistence and degradability:/
Bioaccumulative potential:/
Mobility in soil:/
Other adverse effects:/
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal methods:Recycling as much as possible leakage. Method of recovering the relevant advisory manufacturers, without proper governance or disposal facilities, disposal of related substances in contact or local waste management department. Treatment should include: neutralized with soda ash or lime; landfill then again permit for landfill or incineration incineration in the field have permits (with flammable substances mixed with proper). With 5% sodium hydroxide solution or soda ash container to air of decontamination, and then rinse with water. Comply with the labeling requirement for all, until the container is cleaned or destroyed so far.
SECTION 14 TRANSPORT INFORMATION
UN Number:2693
UN proper shipping name:Ammonium Bisulfite Solution
Transport hazard class:8
Packing group:III
Marine pollutant(Y/N):No
Special precautions for user:/
SECTION 15 REGULATORY INFORMATION
The chemical safety management regulations:
The safety data sheet in accordance with the relevant national standards and related laws and regulations:
Ammonium busulfite
(CAS:10192-30-0)GB16483-2008,GB13690-2009,GB6944-2005,GB/T15098-2008,G B18218-2009,GB15258-2009,GB190-2009,GB191-2009,GB12268-2008,G57- 1993, GB/T 15098-2008,GBZ 2-2007: code>, , ,referred to as UN RTDG。
SECTION 16 OTHER INFORMATION
References:
UN UN
Form date:2022-5-9
Note 1:When the product is a mixture containing two boxes total above dangerous substances, should be based on the mixture of the risk, making the safety data sheets. Note 2:The manufacturer / supplier shall ensure the correctness of the safety data sheet contains information according to the actual situation, and timely updates. Note 3:As a result of product characteristics and does not exist or can't get some information (such as solid without boiling point), should be in the form of "/" .
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