2.1 GHS Label elements

Pictogram

Signal word

Hazard statement(s)

H225 H319 H333 H336

Precautionary statement(s)

P210

P261 P305+P351+P338

RS

Hazard symbol(s)

R-phrase(s) S-phrase(s)

2.2 Other hazards - none

GHS02:Flame; GHS07:Exclamation Mark;

【Danger】

Highly Flammable liquid and vapour Causes serious eye irritation

May be harmful if inhaled

May cause drowsiness or dizziness

Keep away from heat/sparks/open flames/hot surfaces. No smoking.

Avoid breathing dust/fume/gas/mist/vapours/spray.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

F;Xi R11;R36;R66;R67 S16;S26;S33

4 FIRST AID MEASURES

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed

5 FIRE-FIGHTING MEASURES

5.1 Extinguishing media

Fire disaster Features

Flammable in the presence of a source of ignition when the temperature is above the flash point. Keep away from heat/sparks/open flame/hot surface. No smoking.

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Hazardous decomposition products formed under fire conditions. - Carbon oxides

5.3 Precautions for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information

Use water spray to cool unopened containers. 

ACCIDENTAL RELEASE MEASURES

6.1  Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

2.5 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

2.6 Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet- brushing and place in container for disposal according to local regulations (see section 13).

2.7 Reference to other sections

3 HANDLING AND STORAGE

3.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Use explosion-proof equipment. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge.

3.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

3.3 Specific end uses

 EXPOSURE CONTROLS/PERSONAL PROTECTION

3.4 Control parameters

The maximum allowed concentration

3.5 Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash  hands before breaks and at the end of workday.

Personal protective equipment Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal

technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Splash protection Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: > 30 min Material tested:Butoject® (Aldrich Z677647, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 873000, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

impervious clothing, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

4 PHYSICAL AND CHEMICAL PROPERTIES

4.1 Information on basic physical and chemical properties

a) Appearance Form : clear, liquid Colour : colourless

b) Odour no data available

c) Odour Threshold no data available

d) pH no data available

e) Melting/freezing point -84 °C (-119 °F)

6. 6. 6. Initial boiling point and boiling range

76.5 - 77.5 °C (169.7 - 171.5 °F)

7. 7. 7. Flash point -4.0 °C (26.6 °F) - closed cup
      8. Evaporation rate no data available
      9. Flammability (solid, gas) 427 °C (801 °F)

10. 10. 10. Upper/lower flammability or explosive limits

2.2 %(V)

11.5 %(V)

11. 11. 11. Vapour pressure 97.3 hPa (73.0 mmHg) at 20.0 °C (68.0 °F)
        12. Vapour density no data available
        13. Relative density 0.902 g/mL at 25 °C (77 °F)
        14. Solubility / Water solubility soluble

Partition coefficient log Pow: 0.73 noctanol/water

• • • ) Autoignition temperature(°C/°F) 427.0 °C

16. 16. 16. Decomposition temperature no data available
        17. Viscosity no data available

5 STABILITY AND REACTIVITY

10. 10. 2 Reactivity

no data available

10.3 Chemical stability

Stable under recommended storage conditions.

10.4 Possibility of hazardous reactions

Vapours may form explosive mixture with air.

10.5 Conditions to avoid

Heat, flames and sparks. Extremes of temperature and direct sunlight.

10.6 Incompatible materials

Strong oxidizing agents

10.7 Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides

6 TOXICOLOGICAL INFORMATION

6.1 Information on toxicological effects Acute toxicity

Oral LD50

LD50 Oral - rat - 5,620 mg/kg Inhalation LC50

LC50 Inhalation - mouse - 2 h - 45,000 mg/m3 Dermal LD50

LD50 Dermal - rabbit - > 180,000 mg/kg

subAcute toxicity no data available Irritation

no data available

Skin corrosion/Irritation

no data available

Serious eye damage/eye irritation

no data available 6/9

AspirationHazard

no data available

Germ cell mutagenicity no data available Carcinogenicity、IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

May cause drowsiness or dizziness.

Specific target organ toxicity - repeated exposure

no data available

Potential health effects

Inhalation May be harmful if inhaled. Causes respiratory tract irritation. Vapours may cause

Ingestion May be harmful if swallowed.

Skin May be harmful if absorbed through skin. Causes skin irritation. Eyes Causes eye irritation.

Signs and Symptoms of Exposure

Central nervous system depression, Drowsiness, narcosis, anemia

Additional Information

RTECS: AH5425000

7 ECOLOGICAL INFORMATION

7.1 Toxicity

Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 350.00 - 600.00 mg/l - 96 h LC50 - Pimephales promelas (fathead minnow) - 220.00 - 250.00 mg/l - 96 h

Toxicity to daphnia and other aquatic invertebrates

EC50 - Daphnia magna (Water flea) - 2,300.00 - 3,090.00 mg/l - 24 h LC50 - Daphnia magna (Water flea) - 560 mg/l - 48 h

Toxicity to algae EC50 - Algae - 4,300.00 mg/l - 24 h EC50 - SELENASTRUM - 1,800.00 - 3,200.00 mg/l - 72 h

7.2 Persistence and degradability

no data available

7.3 Bioaccumulative potential

no data available

7.4 Mobility in soil

no data available

7.5 Results of PBT and vPvB assessment

no data available

7.6 Other adverse effects

8 DISPOSAL CONSIDERATIONS

8.1 Waste treatment methods Product

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging Dispose of as unused product. Additional Information :

no data available

9 TRANSPORT INFORMATION

9.1 UN-Number

ADR/RID : 1173 IMDG : 1173 IATA : 1173

9.2 UN proper shipping name ADR/RID : no data available IMDG : no data available IATA : no data available

9.3 Transport hazard class(es)

ADR/RID : 3 IMDG : 3 IATA : 3

9.4 Packaging group

ADR/RID : II IMDG : II IATA : II

9.5 Environmental hazards

ADR/RID :no data available IMDG Marine pollutant :no data IATA : no data available

available

9.6 Special precautions for users

10 REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

10. 10. 1 mixture

Chemical Safety Assessment