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Ethyl 3-methyl-3-phenylglycidate 77-83-8

Name: Ethyl 3-methyl-3-phenylglycidate 77-83-8
Brand: Orient
SKU: pr2512121427
Price: 4 USD
Availability: InStock

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CAS No.:

77-83-8

Grade:

Industrail Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2026-01-12

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Qingdao Orient Chemical Co.,LTD

Company Type:

Trader

Location:

China

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Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

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Product Description
Seller Information
Inquiry History

Description

Ethyl 3-methyl-3-phenylglycidate Basic information

Product Name:	Ethyl 3-methyl-3-phenylglycidate
Synonyms:	2,3-epoxy-3-phenyl-butanoicaciethylester;2,3-Epoxy-3-phenylbutyric acid, ethyl ester;3-methyl-3-phenyl-oxiranecarboxylicacid,ethylester;3-methyl-3-phenyl-oxiranecarboxylicacidethylester;3-methyl-3-phenyl-oxiranecarboxylicaciethylester;alpha,beta-Epoxy-beta-methylhydrocinnamic acid, ethyl ester;alpha,beta-epoxy-beta-methylhydrocinnamicacid,ethylester;alpha,beta-epoxy-beta-methyl-hydrocinnamicaciethylester
CAS:	77-83-8
MF:	C12H14O3
MW:	206.24
EINECS:	201-061-8
Product Categories:
Mol File:	77-83-8.mol

Ethyl 3-methyl-3-phenylglycidate Chemical Properties

Boiling point	272-275 °C(lit.)
density	1.087 g/mL at 25 °C(lit.)
FEMA	2444 \| ETHYL METHYLPHENYLGLYCIDATE
refractive index	n20/D 1.505(lit.)
Fp	>230 °F
storage temp.	2-8°C
form	clear liquid
color	Colorless to Light orange to Yellow
Odor	at 100.00 %. sweet fruity strawberry floral honey fatty
Odor Type	fruity
biological source	synthetic
JECFA Number	1577
BRN	12299
LogP	2.43
CAS DataBase Reference	77-83-8(CAS DataBase Reference)
NIST Chemistry Reference	Glycidic acid, 3-methyl-3-phenyl, ethyl ester(77-83-8)
EPA Substance Registry System	Ethyl methylphenylglycidate (77-83-8)

Safety Information

Hazard Codes	Xi
Risk Statements	10-36/37/38
Safety Statements	16-26-36/37/39
RIDADR	UN 1993 3/PG 3
WGK Germany	2
RTECS	MW5250000
TSCA	Yes
HazardClass	3
HS Code	29189090
Hazardous Substances Data	77-83-8(Hazardous Substances Data)
Toxicity	LD50 orally in Rabbit: 5470 mg/kg

MSDS Information

Ethyl 3-methyl-3-phenylglycidate Usage And Synthesis

Chemical Properties	clear yellow liquid
Chemical Properties	Ethyl 3-Methyl-3-phenylglycidate exists as two optically active pairs of cis- and trans-isomers; each isomer has a characteristic odor . The commercial product is a racemic mixture of all four isomers and has a strong, sweetish, strawberry odor. The cis/trans ratio obtained in the Darzens condensation of acetophenone (R==CH3) and ethyl chloroacetate depends on the base used in the reaction.
Chemical Properties	Ethyl methylphenylglycidate on dilution has a strong fruity odor suggestive of strawberry. It has a characteristic, slightly acid taste reminiscent of strawberry.
Chemical Properties	Perennial, herbaceous plant; grows wild or cultivated in central–southern Europe, North America and Asia. The plant grows 10 to 20 cm (4 to 8 in.) in height and has thick rhizomes; radical leaves with long, small, white flowers blossoming from April to July; and fleshy, ovoidal, red berries covered with numerous achenes. The only part used is the berries. Strawberry has a sweet–sour taste and a characteristic odor.
Occurrence	Has apparently not been reported to occur in nature.
Uses	Ethyl 3-Methyl-3-phenylglycidate, also known as “strawberry aldehyde”, is commonly used in the flavor industry for artificial fruit flavors, in particular strawberry.
Uses	Perfumery, flavors.
Uses	Ethyl 3-methyl-3-phenylglycidate is a synthetic flavoring agent that is a glycidic acid ester. It is a colorless to pale yellow liquid with a strong fruit odor suggestive of strawberries. It is unstable to alkali and moderately stable to weak organic acids. It should be stored in glass, tin, or aluminum containers. It is soluble in fixed oils and in propylene glycol. It is used in flavors for strawberry note and has application in candy, beverages, and ice cream at 6–20 ppm. It is also termed aldehyde c-16.
Preparation	By reaction of acetophenone and the ethyl ester of monochloroacetic acid in the presence of an alkaline condensing agent.
Definition	ChEBI: Phenylmethylglycidic ester is a carboxylic acid and an epoxide.
Composition	Strawberry aroma has been the subject of extensive investigation. Several components have been identified, of which only 7% appear to be responsible for the aroma. Strawberry aroma varies widely with the strawberry variety. The most valuable part, aroma, is from wild strawberry.

First aid measures

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

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—— Q&A ——

Q1:Do you provide sample?

A: Yes, we can provide free sample, you only need pay the shipping cost.

Q2: What is the lead time?

A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

Q3: How can I buy? What is the payment method?

A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer,

Q4:What if there are quality issues？

A：We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.

Certificates

Basic Info

Product Name:

Ethyl 3-methyl-3-phenylglycidate

Other Name:

2-Oxiranecarboxylic acid,3-methyl-3-phenyl-,ethyl ester;Hydrocinnamic acid,α,β-epoxy-β-methyl-,ethyl ester;Oxiranecarboxylic acid,3-methyl-3-phenyl-,ethyl ester;Aldehyde C16;Ethyl α,β-epoxy-β-methylhydrocinnamate;Ethyl methylphenylglycidate;Fraeseol;3-Methyl-3-phenylglycidic acid ethyl ester;Strawberry aldehyde;Ethyl 3-methyl-3-phenylglycidate;NSC 27905;Ethyl 3-methyl-3-phenyloxirane-2-carboxylate;FRAISE PURE;1322-04-9

CAS No.:

77-83-8

Molecular Formula:

C12H14O3

InChIKeys:

InChIKey=LQKRYVGRPXFFAV-UHFFFAOYSA-N

Molecular Weight:

206.24

Exact Mass:

206.24

BRN:

12299

EC Number:

201-061-8

NSC Number:

251076|27905

DSSTox ID:

DTXSID8020591

Color/Form:

COLORLESS TO PALE-YELLOW LIQUID

HScode:

29189090

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

38.83000

XLogP3:

2.43

Appearance:

3-methyl-3-phenylglycidic acid ethyl ester is a clear, colorless to yellowish liquid with a strawberry-like odor. (NTP, 1992)

Density:

1.0442 g/cm³ @ Temp: 20 °C

Boiling Point:

272-275 °C

Flash Point:

>230 °F

Refractive Index:

1.525

Water Solubility:

1:3 & MORE IN 70% ALCOHOL; 1:2 IN 80% ALC; INSOL IN WATER; SOL IN MOST ORGANIC SOLVENTS

Storage Conditions:

Store below +30°C.

Toxicity:

LD50 orally in Rabbit: 5470 mg/kg

Odor:

ON DILUTION, STRONG FRUITY ODOR

Taste:

CHARACTERISTIC SLIGHTLY ACID TASTE REMINISCENT OF STRAWBERRY

Experimental Properties:

ACID VALUE: NOT MORE THAN 2 (0.9); KETONE CONTENT: 1% MAX (AS C8-H8-O)

Air and Water Reactions:

Insoluble in water.

Reactive Group:

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

Reactivity Profile:

Esters, such as 3-METHYL-3-PHENYLGLYCIDIC ACID ETHYL ESTER, react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

See More Ethyl 3-methyl-3-phenylglycidate Properties 

Hazard Identification

Classification of the substance or mixture

Skin sensitization, Sub-category 1B

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Warning
Hazard statement(s)	H317 May cause an allergic skin reaction H411 Toxic to aquatic life with long lasting effects
Prevention	P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P273 Avoid release to the environment.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P333+P317 If skin irritation or rash occurs: Get medical help. P321 Specific treatment (see ... on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.
Storage	none
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

See More Ethyl 3-methyl-3-phenylglycidate Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

Website: orientchem.cc
Email: scarlett@orientchem.cc
WhatsApp: +86 17753254221

Inquiry History

1 Inquiries

Country	Product	Purchase Quantity	Date Posted
Poland	Flavour & Fragrance Methyl-3-Phenyl Glycidic Acid Ethyl Ester CAS 77-83-8	50 KG	Sep 21, 2023

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