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3-Chloro-2-methylaniline CAS:87-60-5

Name: 3-Chloro-2-methylaniline CAS:87-60-5
Brand: Orient
SKU: pr2512263151
Price: 4 USD
Availability: InStock

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CAS No.:

87-60-5

Grade:

Industrail Grade

Content:

99%

Port:

shanghai

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2026-01-26

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Qingdao Orient Chemical Co.,LTD

Company Type:

Trader

Location:

China

Qualification:

Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

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Product Description
Seller Information
Inquiry History

Description

Product Name:	3-Chloro-2-methylaniline
Synonyms:	2-Chloro-2-Methyl Aniline;3-Chloro-2-methylaniline, 98+%;3-CHLORO-ORTHO-TOLUIDINE;3-Chlor-o-toluidin;3-chloro-2-toluidin;3-CHLORO-2-METHYLANILINE / 2-AMINO-6-CHLOROTOLUENE;3-chloro-o-toluidin;6-Chloro-2-amino-1-methylbenzene
CAS:	87-60-5
MF:	C7H8ClN
MW:	141.6
EINECS:	201-756-6
Product Categories:	API intermediates;Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:	87-60-5.mol

3-Chloro-2-methylaniline Chemical Properties

Melting point	2 °C (lit.)
Boiling point	115-117 °C/10 mmHg (lit.)
density	1.185 g/mL at 25 °C (lit.)
refractive index	n20/D 1.588(lit.)
Fp	>230 °F
storage temp.	Store below +30°C.
solubility	4.5g/l
pka	pK1:2.49(+1) (25°C)
form	Liquid
color	Clear yellow to red or red-brown
Specific Gravity	1.19
Water Solubility	1g/L at 20℃
BRN	471697
InChIKey	ZUVPLKVDZNDZCM-UHFFFAOYSA-N
LogP	2.4
CAS DataBase Reference	87-60-5(CAS DataBase Reference)
NIST Chemistry Reference	Benzenamine, 3-chloro-2-methyl-(87-60-5)
EPA Substance Registry System	3-Chloro-2-methylaniline (87-60-5)

Safety Information

Hazard Codes	C,N,Xn
Risk Statements	22-34-43-51/53-36/37/38
Safety Statements	26-36/37/39-45-61-37/39
RIDADR	UN 3429 6.1/PG 3
WGK Germany	2
RTECS	XU4760000
TSCA	Yes
HazardClass	6.1
PackingGroup	III
HS Code	29214300
Hazardous Substances Data	87-60-5(Hazardous Substances Data)

MSDS Information

3-Chloro-2-methylaniline Usage And Synthesis

Synthesis	It is obtained by chlorination and reduction of o-nitrotoluene. 1. Chlorination reaction In o-nitrotoluene, add 2% ferric chloride as a catalyst, pass chlorine gas at 50-60 ° C until the relative density of the reaction solution reaches 1.27-1.29 (50 ° C), wash with 5% hydrochloric acid, and then Wash with water, and finally adjust pH to 7 with liquid caustic soda. Divide the water layer, evaporate the water, carry out vacuum distillation, collect 120-150 ℃ (5.33-8.0kPa) fractions, crystallize by cooling and filter to obtain 2-chloro-6-nitrotoluene. 2. Reduction reaction Add hydrochloric acid and iron powder to the reaction pot, stir and heat to 90°C, slowly add melted 2-chloro-6-nitrotoluene, complete the addition, and reflux for 3 hours. Cooling, adding liquid alkali to adjust pH to 8, steam distillation to obtain 3-chloro-o-toluidine.
Description	The chloromethylanilines are colorless orwhite crystalline solids or liquids, some have a mild fishyodor. Molecular weight (all isomers) =141.61. HazardIdentification (based on NFPA 704 M Rating System): (87-60-5) Health 2, Flammability 1, Reactivity 0. All are soluble in water and include:
Chemical Properties	clear yellow to red or red-brown liquid
Chemical Properties	The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.
Uses	Intermediate.
Uses	3-Chloro-2-Methylaniline can be used for dyeing cotton, viscose, silk, nylon and acetate, as well as printing on cotton. It is mainly used for dyeing red, such as coupling with chromophenol AS, AS-BO, AS-ITR, etc.
Preparation	By 1-Methyl-2-nitrobenzene chlorination byproducts 3-Chloro-2-methylbenzenamine?reduction.

First aid measures

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak. Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

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—— Q&A ——

Q1:Do you provide sample?

A: Yes, we can provide free sample, you only need pay the shipping cost.

Q2: What is the lead time?

A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

Q3: How can I buy? What is the payment method?

A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer,

Q4:What if there are quality issues？

A：We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.

Certificates

Basic Info

Product Name:

3-Chloro-2-methylaniline

Other Name:

Benzenamine,3-chloro-2-methyl-;o-Toluidine,3-chloro-;3-Chloro-2-methylbenzenamine;Fast Scarlet TR Base;3-Chloro-2-methylaniline;3-Chloro-o-toluidine;2-Amino-6-chlorotoluene;2-Methyl-3-chloroaniline;6-Chloro-2-aminotoluene;3-Chloro-2-methylphenylamine;o-Methyl-m-chloroaniline;3-Chloro-2-toluidine;Scarlet TR base;6-Chloro-2-amino-1-methylbenzene;NSC 6184;1-Amino-2-methyl-3-chlorobenzene;3-Amino-1-chloro-2-methylbenzene;1-Chloro-2-methyl-3-aminobenzene

CAS No.:

87-60-5

Molecular Formula:

C7H8ClN

InChIKeys:

InChIKey=ZUVPLKVDZNDZCM-UHFFFAOYSA-N

Molecular Weight:

141.6

Exact Mass:

141.60

BRN:

471697

EC Number:

201-756-6

UNII:

QG8LP81715

NSC Number:

6184

DSSTox ID:

DTXSID3024815

Color/Form:

LIQUID

HScode:

29214300

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

XLogP3:

Appearance:

Clear yellow to red or red-brown Liquid

Density:

1.2±0.1 g/cm3

Melting Point:

1 °C

Boiling Point:

245 °C @ Press: 760 Torr

Flash Point:

>230 °F

Refractive Index:

1.585

Water Solubility:

SOL IN ALCOHOL

Storage Conditions:

Store below +30°C.

Vapor Pressure:

0.0443 mm Hg at 25 deg C (est)

Henrys Law Constant:

Henry's Law constant= 1.56X10-6 atm-cu m/mole (est)

See More 3-Chloro-2-methylaniline Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Acute toxicity - Category 3, Dermal

Skin sensitization, Sub-category 1B

Serious eye damage, Category 1

Specific target organ toxicity â repeated exposure, Category 2

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H302 Harmful if swallowed H311 Toxic in contact with skin H317 May cause an allergic skin reaction H318 Causes serious eye damage H373 May cause damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment.
Response	P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P316 Get emergency medical help immediately. P321 Specific treatment (see ... on this label). P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P333+P317 If skin irritation or rash occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P317 Get medical help. P319 Get medical help if you feel unwell. P391 Collect spillage.
Storage	P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

See More 3-Chloro-2-methylaniline Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

A reliable supplier is like insurance.

We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

Website: orientchem.cc
Email: scarlett@orientchem.cc
WhatsApp: +86 17753254221

Inquiry History

2 Inquiries

Country	Product	Purchase Quantity	Date Posted
India	3-Chloro-2-methylaniline	350.00 KG	Jun 28, 2024
India	3-Chloro-2-methylaniline	1000 KG	May 18, 2024

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