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Pentane109-66-0

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CAS No.:

109-66-0

Grade:

Industrial Grade

Content:

99.5%

Port:

上海

Brand:

OORENT

Packaging:

Vial/Bottle/Bag/Carton

Price valid (until):

2026-07-18

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Description

Product Detail

Pentane Basic information

Product Name:	Pentane
Synonyms:	PETANE;PENTANE;PENTANE-195;PENTANE FRACTION;PETROLEUM SPIRIT 30/40;N-PENTAN;N-PENTANE;NORMAL PENTANE
CAS:	109-66-0
MF:	C5H12
MW:	72.15
EINECS:	203-692-4
Product Categories:	Anhydrous Solvents;Organics;refrigerants;Pestanal/Residue Analysis;GC Capillary;ReagentSolvents;Carbon Steel Cans with NPT Threads;Reagent Grade Solvents;ReagentSemi-Bulk Solvents;Solvent by Application;GC Capillary;Aluminum Bottles;Amber Glass Bottles;Reagent;Standard Materials for GC;Analytical Chemistry;Solvent Bottles;Solvent Packaging Options;Purge &;Purge and Trap Solvents;Trap Solvents;Analytical Reagents;Chromatography Reagents &;GC Solvents;Solvents for GC applications;CHROMASOLV for HPLC;HPLC &;HPLC Grade Solvents (CHROMASOLV);HPLC/UHPLC Solvents (CHROMASOLV);Semi-Bulk Solvents;n-Paraffins (GC Standard);CHROMASOLV(R) HPLC Grade Solvents;Alpha Sort;P;PA - PEN;P-SAlphabetic;Volatiles/ Semivolatiles;Analytical Reagents for General Use;O-P, Puriss p.a.;Puriss p.a.;CHROMASOLV for HPLCSolvents;Semi-Bulk Solvents;VerSA-Flow? Products;Anhydrous Grade SolventsSolvents;AnhydrousSolvents;Returnable Container Solvents;Solvent Bottles;Sure/Seal? Bottles;Amber Glass Bottles;Spectrophotometric Grade Solvents;Spectrophotometric GradeSolvents;Purge&Trap;Chromatography/CE Reagents;Solvents - GC/SH;Analytical Reagents;Analytical/Chromatography;Trace Analysis Reagents;Chemical Class;Hydrocarbons;NeatsAlphabetic;UHPLC Solvents (CHROMASOLV);VerSA-Flow Products;CHROMASOLV Solvents (HPLC, LC-MS);Solvents
Mol File:	109-66-0.mol

Pentane Chemical Properties

Melting point	-130 °C
Boiling point	36 °C
density	0.626 g/mL at 25 °C(lit.)
vapor density	2.48 (vs air)
vapor pressure	26.98 psi ( 55 °C)
refractive index	n20/D 1.358
Fp	−57 °F
storage temp.	Store at +5°C to +30°C.
solubility	ethanol: soluble(lit.)
form	Liquid
pka	>14 (Schwarzenbach et al., 1993)
Specific Gravity	0.63
color	Colorless
Odor	Like a gasoline.
Relative polarity	0.009
Odor Threshold	1.4ppm
explosive limit	1.4-8%(V)
Water Solubility	insoluble
Thermal Conductivity	0.1119 W/(m·K) at 25 ℃
λmax	λ: 200 nm Amax: ≤0.70 λ: 210 nm Amax: ≤0.20 λ: 220 nm Amax: ≤0.07 λ: 230 nm Amax: ≤0.02 λ: 250 nm Amax: ≤0.004
Merck	14,7116
BRN	969132
Henry's Law Constant	1.20 at 25 °C (Jnsson et al., 1982)
Exposure limits	ACGIH:TLV-TWA 1000 ppm (2950 mg/m3) OSHA:PEL-TWA 1000 ppm (2950 mg/m3) NIOSH:REL-TWA 120 ppm; REL-Ceiling 610 ppm [15-min]
Dielectric constant	1.8（20℃）
Cosmetics Ingredients Functions	SOLVENT PROPELLANT
InChI	1S/C5H12/c1-3-5-4-2/h3-5H2,1-2H3
InChIKey	OFBQJSOFQDEBGM-UHFFFAOYSA-N
SMILES	CCCCC
LogP	3.390
Surface tension	15.93mN/m at 293.15K
CAS DataBase Reference	109-66-0(CAS DataBase Reference)
NIST Chemistry Reference	Pentane(109-66-0)
EPA Substance Registry System	Pentane (109-66-0)

Safety Information

Hazard Codes	F+,Xn,N,F
Risk Statements	12-51/53-65-66-67
Safety Statements	9-16-29-33-61-62
RIDADR	UN 1265 3/PG I/II (PENTANES, liquid)
OEB	A
OEL	TWA: 120 ppm (350 mg/m3), Ceiling: 610 ppm (1800 mg/m3) [15-minute]
WGK Germany	2
RTECS	RZ9450000
F	3-10
Autoignition Temperature	500 °F
TSCA	TSCA listed
HazardClass	3
PackingGroup	II
HS Code	29011090
Storage Class	3 - Flammable liquids
Hazard Classifications	Aquatic Chronic 2 Asp. Tox. 1 Flam. Liq. 2 STOT SE 3
Hazardous Substances Data	109-66-0(Hazardous Substances Data)
Toxicity	LC (in air) in mice: 377 mg/l (Fühner)
IDLH	1,500 ppm [10% LEL]

MSDS Information

Provider	Language
Pentane	English
SigmaAldrich	English
ACROS	English
ALFA	English

Pentane Usage And Synthesis

Chemical Properties	n-Pentane is a flammable liquid. It has applications in industry as an aerosol propellant and as an important component of engine fuel. pentane lewis structure N-propane is a CNS depressant. Studies with dogs have indicated that it induces cardiac sensitization. In high concentrations it causes incoordination and inhibition of the righting refl exes. N-pentane is being used primarily in Europe in integral-skin flexible foams. Pentane is twice as effective as CFC-11 as a blowing agent.
Chemical Properties	Pentane is a colorless liquid. Gas above 36C. Gasoline-like odor.
Physical properties	Clear, colorless, volatile liquid with an odor resembling gasoline. An odor threshold concentration of 1.4 ppm_v was reported by Nagata and Takeuchi (1990).
Uses	n-Pentane occurs in volatile petroleum fractions(gasoline) and as a constituent ofpetroleum ether. It is used as a solvent, in themanufacture of low-temperature thermometers,and as a blowing agent for plastics.
Uses	n-Pentane is a flammable liquid. It has diverse uses in industry—for instance, as an aerosol propellant and as an important component of engine fuel. n-Pentane is a CNS depressant. Laboratory studies in dogs indicate that prolonged exposure to high concentrations of n-pentane induces cardiac sensitization, poor coordination, and inhibition of the righting reflexes. NIOSH has recommended limits of n-pentane for working areas.
Uses	Fuel; solvent; chemical synthesis
Production Methods	Pentane is produced by fractional distillation of natural gas liquids and crude oil. It is also produced by the catalytic crackdown of naphtha.
Definition	A straightchain alkane obtained by distillation of crude oil.
Definition	pentane: A straight-chain alkanehydrocarbon, C5H12; r.d. 0.63; m.p.–129.7°C; b.p. 36.1°C. It is obtainedby distillation of petroleum.
General Description	A clear colorless liquid with a petroleum-like odor. Flash point 57°F. Boiling point 97°F. Less dense than water and insoluble in water. Hence floats on water. Vapors are heavier than air.
Air & Water Reactions	Highly flammable. Insoluble in water.
Reactivity Profile	Pentane is incompatible with strong oxidizers. Pentane is also incompatible with strong acids, alkalis, and oxygen. Mixtures with chlorine gas have produced explosions. Pentane will attack some forms of plastics, rubber, and coatings. .
Health Hazard	n-Pentane did not exhibit any marked toxicityin animals. However, inhalation ofits vapors at high concentrations can causenarcosis and irritation of the respiratorypassages. Such effects may be observedwithin the range 5–10% concentration inair. In humans, inhalation of 5000 ppm for10 minutes did not cause respiratory tractirritation or other symptoms (Patty and Yant1929). There is no report in the literature indicatingany adverse effects from pentaneother than narcosis and irritation. An intravenousLD50 value in mouse is recorded as446 mg/kg (NIOSH 1986).
Fire Hazard	Behavior in Fire: Containers may explode
Flammability and Explosibility	Extremely flammable
Chemical Reactivity	Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Safety Profile	Moderately toxic by inhalation and intravenous routes. Narcotic in high concentration. The liquid can cause blisters on contact. Flammable liquid. Highly dangerous fire hazard when exposed to heat, flame, or oxidizers. Severe explosion hazard when exposed to heat or flame. Shock can shatter metal containers and release contents. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes
Potential Exposure	Pentane is used in manufacture of ice, low-temperature thermometers; in solvent extraction processes; as a blowing agent in plastics; as a fuel; as a chemical intermediate (for amylchlorides, e.g.).
Source	Schauer et al. (1999) reported pentane in a diesel-powered medium-duty truck exhaust at an emission rate of 1,860 μg/km. A constituent in gasoline. Harley et al. (2000) analyzed the headspace vapors of three grades of unleaded gasoline where ethanol was added to replace methyl tert-butyl ether. The gasoline vapor concentrations of pentane in the headspace were 14.2 wt % for regular grade, 12.6 wt % for midgrade, and 9.3 wt % for premium grade. California Phase II reformulated gasoline contained pentane at a concentration of 27.6 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 4.29 and 536 mg/km, respectively (Schauer et al., 2002). Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission rate of pentane was 4.7 mg/kg of pine burned. Emission rates of pentane were not measured during the combustion of oak and eucalyptus.
Environmental fate	Biological. n-Pentane may biodegrade in two ways. The first is the formation of pentyl hydroperoxide, which decomposes to 1-pentanol followed by oxidation to pentanoic acid. The other pathway involves dehydrogenation to 1-pentene, which may react with water giving 1- pentanol (Dugan, 1972). Microorganisms can oxidize alkanes under aerobic conditions (Singer and Finnerty, 1984). The most common degradative pathway involves the oxidation of the terminal methyl group forming 1-pentanol. The alcohol may undergo a series of dehydrogenation steps forming an aldehyde (valeraldehyde) then a fatty acid (valeric acid). The fatty acid may then be metabolized by β-oxidation to form the mineralization products, carbon dioxide and water (Singer and Finnerty, 1984). Mycobacterium smegnatis was capable of degrading pentane to 2- pentanone (Riser-Roberts, 1992). Photolytic. When synthetic air containing gaseous nitrous acid and pentane was exposed to artificial sunlight (λ = 300–450 nm) methyl nitrate, pentyl nitrate, peroxyacetal nitrate, and peroxypropionyl nitrate formed as products (Cox et al., 1980). Chemical/Physical. Complete combustion in air yields carbon dioxide and water. Pentane will not hydrolyze because it does not contain a hydrolyzable functional group.
Shipping	UN1265 Pentanes Hazard Class: 3; Labels: 3-Flammable liquid.
Purification Methods	Stir the pentane with successive portions of conc H2SO4 until there is no further coloration during 12hours, then with 0.5N KMnO4 in 3M H2SO4 for 12hours, wash with water and aqueous NaHCO3. Dry it with MgSO4 or Na2SO4, then P2O5 and fractionally distil it through a column packed with glass helices. It is also purified by passage through a column of silica gel, followed by distillation and storage with sodium hydride. An alternative purification is by azeotropic distillation with MeOH, which is subsequently washed out from the distillate (using water), followed by drying and re-distilling. For removal of carbonyl-containing impurities, see n-heptane. Also purify it by fractional freezing (ca 40%) on a copper coil through which cold air is passed, then wash with conc H2SO4 and fractionally distil it. [Beilstein 1 IV 303.]
Toxicity evaluation	The mechanism of toxicity is suspected to be similar to other solvents that rapidly induce anesthesia-like effects, that is a ‘nonspecific narcosis’ due to disruption (solvation) of the integrity of the cellular membranes of the central nervous system. The effect is similar to the ‘high’ experienced upon exposure to other aliphatic hydrocarbon solvents. As seen with other short-chain alkanes, upon inhalation, pentane is moderately toxic and may cause irritation of the respiratory tract and narcosis. The narcotic action of pentane (observed following 1-h exposure to 90 000–120 000 ppm) is, however, much less pronounced than effects seen following exposure to the C1–C4 alkanes. Although the actual biochemical mechanismof toxicity has not been discerned, the narcotic effects seen are most likely related to its physical solvent properties.
Incompatibilities	Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some plastics, rubbers, and coatings.
Toxics Screening Level	The initial threshold screening level (ITSL) for pentane is 17700 μg/m3 based on an 8-hour averaging time.
Waste Disposal	Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Pentane Preparation Products And Raw materials

Preparation Products

1-AMINOCYCLOPROPANECARBONITRILE-->2-AMINOPENT-4-YNENITRILE-->ETHYL 1-TERT-BUTYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE-4-CARBOXYLATE-->4-BROMO-3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-->2,2,4,6,7-Pentamethyldihydrobenzofuran-5-sulfonyl chloride-->1-TERT-BUTYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE-4-CARBOXYLIC ACID-->tert-Butyldimethylsilyl chloride-->Bis(pinacolato)diboron-->2-Bromo-5-hydroxypyridine radical ion(1+)-->2,4,6-Triisopropylbenzenesulfonyl chloride-->Di-tert-butylchlorophosphane-->5-METHOXY-QUINAZOLIN-4-YLAMINE-->TERT-BUTYL 4-FORMYLPYRIDIN-3-YLCARBAMATE-->1-Heptanol-->1-Bromo-4-methoxybutane-->EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE-->1-TERT-BUTYL-4-BROMO-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE-->(TRIMETHYLSILYL)ACETIC ACID-->4-BROMO-1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE-->3-TRIFLUOROACETYL-D-CAMPHOR-->HEPTENOPHOS-->Fexofenadine-->4,6-DIHYDROXY-5-METHYLPYRIMIDINE-->2-METHOXYPHENOXYACETIC ACID-->Cyclopentane-->2-Methylbutane-->Ketamine hydrochloride-->Cyclobutanol-->4-Benzyloxybenzeneboronic acid-->1-Cyclopentenecarboxylic acid-->2-(4-Bromophenyl)-2-methylpropionic acid-->3-Aminopyridazine hydrochloride-->ORNOPROSTIL-->(S)-2-Methylproline-->3,6,9,12-tetraoxahexadecan-1-ol-->2-Amino-5-nitropyrimidine-->1,4-Dibromopentane-->DI-TERT-BUTYLDICHLOROSILANE-->Cefepime-->CHLOROMETHYL METHYL SULFIDE

Shop 3-Chloro-1-propene107-05-1-Detailed Image 2

Basic Info

Product Name:

n-Pentane

Other Name:

Pentane;n-Pentane;Skellysolve A;Norpar 5S;NSC 72415;E 0121;M 004;Exxsol Pentane 80;Guchen MG 132;MG 132;8031-35-4;2063998-93-4

CAS No.:

109-66-0

Molecular Formula:

C5H12

InChIKeys:

InChIKey=OFBQJSOFQDEBGM-UHFFFAOYSA-N

Molecular Weight:

72.14880

Exact Mass:

72.15

EC Number:

923-583-1

UNII:

4FEX897A91

ICSC Number:

0534

NSC Number:

72415

UN Number:

1265

DSSTox ID:

DTXSID2025846|DTXSID5029001

Color/Form:

Colorless liquid [Note: A gas above 97 degrees F. May be utilized as a fuel].

HScode:

2930909019

Categories:

Hydrocarbons and Derivatives

Characteristics

PSA:

XLogP3:

2.19650

Appearance:

N-pentane appears as a clear colorless liquid with a petroleum-like odor. Flash point 57°F. Boiling point 97°F. Less dense than water and insoluble in water. Hence floats on water. Vapors are heavier than air.

Density:

0.62638 g/cm³ @ Temp: 20 °C

Melting Point:

-129.7 °C

Boiling Point:

36.1 °C

Flash Point:

-49ºC

Refractive Index:

1.358

Water Solubility:

ethanol: soluble (lit.)

Storage Conditions:

2-8ºC

Vapor Pressure:

527mmHg at 25°C

Vapor Density:

2.48

Toxicity:

LC (in air) in mice: 377 mg/l (Fühner)

Flammability characteristics:

Class IA Flammable Liquid: Fl.P. below 73°F and BP below 100°F.

Explosive limit:

vol% in air: 1.5.8

Odor:

Pleasant

OH:

3.94e-12 cm3/molecule*sec

Henrys Law Constant:

1.25 atm-m3/mole|Henry's Law constant = 1.25 atm-cu m/mole at 25 °C

Experimental Properties:

Specific gravity: 0.64529 at 0 °C/4 °C; 0.62638 at 20 °C/4 °C; 0.6163 at 30 °C/4 °C|Heat of combustion: 3509.0 kJ/mol (liquid)|2.35 mg/cu m equals approx 1 ppm /from table/|Heat of fusion: 8.40 KJ/mol|For more Other Experimental Properties (Complete) data for n-Pentane (10 total), please visit the HSDB record page.

Air and Water Reactions:

Highly flammable. Insoluble in water.

Reactive Group:

Hydrocarbons, Aliphatic Saturated

Reactivity Alerts:

Highly Flammable

Reactivity Profile:

N-PENTANE is incompatible with strong oxidizers. It is also incompatible with strong acids, alkalis, and oxygen. Mixtures with chlorine gas have produced explosions. It will attack some forms of plastics, rubber, and coatings. (NTP, 1992).

Autoignition Temperature:

500 °F (USCG, 1999)|500 °F (260 °C)|260 °C

Heat of Combustion:

3272 kJ/mol (gas); 3245 kJ/mol (liquid)

Ionization Potential:

10.34 eV

Flammable Limits:

Lower flammable limit: 1.5% by volume; Upper flammable limit: 7.8% by volume.|Class IA Flammable Liquid: Fl.P. below 73°F and BP below 100°F.

Physical Dangers:

The vapour is heavier than air and may travel along the ground; distant ignition possible. The vapour is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen.

Corrosivity:

Will attack some forms of plastics, rubber, and coatings.

Heat of Vaporization:

26.43 kJ/mol at 25 °C

Critical Temperature & Pressure:

Critical temperature: 469.7 K; critical pressure: 3.37 MPa ; critical volume: 310 cu cm/mole

See More n-Pentane Properties 

Hazard Identification

Classification of the substance or mixture

Flammable liquids, Category 2

Aspiration hazard, Category 1

Specific target organ toxicity â single exposure, Category 3

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H225 Highly flammable liquid and vapour H304 May be fatal if swallowed and enters airways H336 May cause drowsiness or dizziness H411 Toxic to aquatic life with long lasting effects
Prevention	P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment.
Response	P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower]. P370+P378 In case of fire: Use ... to extinguish. P301+P316 IF SWALLOWED: Get emergency medical help immediately. P331 Do NOT induce vomiting. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P319 Get medical help if you feel unwell. P391 Collect spillage.
Storage	P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames, NO sparks and NO smoking. NO contact with strong oxidizing agents. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Fireproof. Separated from strong oxidants. Cool. Well closed. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.Storage temp: ambient. Venting: open (flame arrester) or pressure-vacuum.

See More n-Pentane Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

A reliable supplier is like insurance.

We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

Website: orientchem.cc
Email: scarlett@orientchem.cc
WhatsApp: +86 17753254221

Inquiry History

3 Inquiries

Country	Product	Purchase Quantity	Date Posted
Malaysia	N-PENTANE	1 20' Fcl	Jan 3, 2024
Serbia	N Pentane	200 MT	Jun 17, 2026
Saudi Arabia	N-Pentane	10 MT	Jul 17, 2024

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Pentane109-66-0

Product Description

Seller Information

Inquiry History

Classification of the substance or mixture

GHS label elements, including precautionary statements

Other hazards which do not result in classification

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

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