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μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium

μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium structure

CAS No:
67719-69-1
Formula:
C13H18AlClTi
Chemical Name:
μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium
Synonyms:
Titanium,μ-chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylene-;Methane,aluminum-titanium complex;μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium;Tebbe reagent;Tebbe's reagent;Reagents,Tebbe
Categories:
Organic Chemistry > Organometallic Compounds

Description

Dark red to purple solution The Tebbe reagent is the organometallic compound with the formula (CH)TiCHClAl(CH). It is used in the methylenation of carbonyl compounds, that is it converts organic compounds containing the RC=O group into the related RC=CH derivative.It is a red solid that is pyrophoric in the air, and thus is typically handled with air-free techniques. It was originally synthesized by Fred Tebbe at DuPont Central Research. Tebbe's reagent contains two tetrahedral metal centers li

μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium Basic Attributes

Molecular Weight：

284.58

Exact Mass：

284.03900

HScode：

29310099

Characteristics

XLogP3：

4.36090

Appearance：

Dark red to purple Solution

Density：

0.927

Flash Point：

34 °F

Water Solubility：

soluble in toluene, benzene, dichloromethane. Insoluble in water.

Storage Conditions：

Refrigerator

Safety Information

Packing level：

Hazard category：

4.3

Transport codes：

UN 2924 3/PG 2

wgk germany：

hazard class code：

11-34-48/20-63-65-67

safety instructions：

26-36/37/39-45-62-16

Marks：

F,C

Precautionary statement(s)：

P210-P261-P280-P301 + P310-P305 + P351 + P338-P310

Hazard Statements：

H225-H304-H314-H336-H361d-H373

μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium Use and Manufacturing

Reagent for the methylenation of carbonyl groups.

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Guide of μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium

Description
Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
Latest News
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μ-Chlorobis(η5-2,4-cyclopentadien-1-yl)(dimethylaluminum)-μ-methylenetitanium

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