(-)-(S,S)-1,2-Diphenylethylenediamine
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(-)-(S,S)-1,2-Diphenylethylenediamine
structure -
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CAS No:
29841-69-8
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Formula:
C14H16N2
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Chemical Name:
(-)-(S,S)-1,2-Diphenylethylenediamine
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Synonyms:
1,2-Ethanediamine,1,2-diphenyl-,(1S,2S)-;Ethylenediamine,1,2-diphenyl-,(1S,2S)-(-)-;1,2-Ethanediamine,1,2-diphenyl-,[S-(R*,R*)]-;(1S,2S)-1,2-Diphenyl-1,2-ethanediamine;(-)-Stilbenediamine;(S,S)-1,2-Diphenylethylenediamine;(S,S)-Stilbenediamine;(S,S)-1,2-Diphenyl-1,2-ethanediamine;(1S,2S)-Diphenyl-1,2-diaminoethane;(-)-1,2-Diphenylethylenediamine;(S,S)-(-)-1,2-Diphenylethylenediamine;(1S,2S)-(-)-1,2-Diphenylethylenediamine;(1S,2S)-1,2-Diphenyl-1,2-diaminoethane;(1S,2S)-1,2-Diphenylethylenediamine;(S,S)-1,2-Diamino-1,2-diphenylethane;(1S,2S)-Diphenylethanediamine;(S,S)-1,2-Diphenyl-1,2-diaminoethane;1,2-(S,S)-Diamino-1,2-diphenylethane;(-)-(S,S)-1,2-Diphenylethylenediamine;(1S,2S)-(-)-1,2-Diphenylethylenediamine;((1S,2S)-2-Amino-1,2-diphenylethyl)amine;(S,S)-1,2-Diphenylethylene-1,2-diamine;(1S,2S)-1,2-Diamino-1,2-diphenylethane;(1S,2S)-1,2-Diphenylethan-1,2-diamine
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CAS No:
Characteristics
52
1.4
white to pale yellow crystal
1.1±0.1 g/cm3
82-84 °C
353.9°C at 760 mmHg
199.9±26.0 °C
1.620
Insoluble in water.
2-8°C
3.48E-05mmHg at 25°C
-104 º (c=1.1, MeOH 25 ºC)
Safety Information
8
NONH for all modes of transport
3
36/37/38-34
26-36-45-36/37/39
Xi,C
P261-P305 + P351 + P338
H315-H319-H335
(-)-(S,S)-1,2-Diphenylethylenediamine Use and Manufacturing
Widely used in asymmetric synthesis and optical resolution, such as asymmetric hydroxylation of olefin, asymmetric aldol condensation reaction, asymmetric Diels-Alder reaction, asymmetric allylation of carbonyl group, optically active propadiene Synthesis of alcohols and propynyl alcohols, asymmetric epoxidation of olefins without functional groups and resolution of binaphthol, etc.
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(-)-(S,S)-1,2-Diphenylethylenediamine
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