4,7-Diphenyl-1,10-phenanthroline
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4,7-Diphenyl-1,10-phenanthroline
structure -
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CAS No:
1662-01-7
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Formula:
C24H16N2
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Chemical Name:
4,7-Diphenyl-1,10-phenanthroline
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Synonyms:
1,10-Phenanthroline,4,7-diphenyl-;4,7-Diphenyl-1,10-phenanthroline;Bathophenanthroline;4,7-Diphenyl-1,10-diazaphenanthrene;1,10-Bathophenanthroline;4,7-Diphenyl-o-phenanthroline;NSC 637659;BPhen;DPA;4′,7-Diphenyl-1,10-phenanthroline;100756-39-6
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CAS No:
Description
white to faintly yellow crystalline powderChEBI: A member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7.
4,7-diphenyl-1,10-phenanthroline is a member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7. It has a role as a chelator. It is a member of phenanthrolines and a member of benzenes.
4,7-Diphenyl-1,10-phenanthroline Basic Attributes
332.4
332.40
261048
216-767-1
4A2B091F0G
637659
DTXSID7061857
29339990
Characteristics
25.8
5.7
White to yellow to pinkish Crystalline Powder, Crystals or Crystalline Mass
1.2047 (rough estimate)
215-216 °C
459.52°C (rough estimate)
242.1±21.4 °C
1.7620 (estimate)
Soluble in organic solvents. Slightly soluble in acidic aqueous solutions. Insoluble in neutral or alkaline solutions.
Store at +15°C to +25°C.
2.63E-11mmHg at 25°C
Safety Information
NONH for all modes of transport
3
20/21/22-36/37/38
22-24/25-36-26
SF8427000
Xn
Stable. Incompatible with strong oxidizing agents.
|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 4 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Drug Information
Chemical agents that uncouple oxidation from phosphorylation in the metabolic cycle so that ATP synthesis does not occur. Included here are those IONOPHORES that disrupt electron transfer by short-circuiting the proton gradient across mitochondrial membranes. (See all compounds classified as Uncoupling Agents.)|Substances used for the detection, identification, analysis, etc. of chemical, biological, or pathologic processes or conditions. Indicators are substances that change in physical appearance, e.g., color, at or approaching the endpoint of a chemical titration, e.g., on the passage between acidity and alkalinity. Reagents are substances used for the detection or determination of another substance by chemical or microscopical means, especially analysis. Types of reagents are precipitants, solvents, oxidizers, reducers, fluxes, and colorimetric reagents. (From Grant and Hackh's Chemical Dictionary, 5th ed, p301, p499) (See all compounds classified as Indicators and Reagents.)
bathophenanthroline
4,7-Diphenyl-1,10-phenanthroline Use and Manufacturing
BPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.
The phenanthroline unit is small, rigid, and planar, with extended π-electrons and short hopping lengths that facilitate electron mobility. The electron mobility of BPhen is about 5 × 10-4 cm2 V-1 s-1, which is about two orders of magnitude higher than that of Alq3.
When doped with lithium, BPhen:Li is an excellent electron-transport material, and is often used
1,10-Phenanthroline, 4,7-diphenyl-: ACTIVE
Computed Properties
Molecular Weight:332.4
XLogP3:5.7
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:332.131348519
Monoisotopic Mass:332.131348519
Topological Polar Surface Area:25.8
Heavy Atom Count:26
Complexity:409
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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4,7-Diphenyl-1,10-phenanthroline
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