Potassium bromate
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Potassium bromate
structure -
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CAS No:
7758-01-2
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Formula:
BrHO3.K
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Chemical Name:
Potassium bromate
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Synonyms:
Bromic acid,potassium salt (1:1);Bromic acid,potassium salt;Potassium bromate
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CAS No:
Characteristics
57.2
0.48920
White Powder/Solid
3.34 g/cm3
350 °C
Decomposes at 698° F (NTP, 1992)
H2O: 70 g/L (20 ºC)
Store below +30°C.
Oral-Rat LD50: 321 mg/kg; intravenous injection-mouse LDL0: 289 mg/kg
High thermal decomposition of oxygen; flammable in contact with sulfuric acid; burning produces toxic bromide and potassium oxide fumes
It forms very flammable mixtures with combustible materials and this mixture may be explosive if the combustible material is very finely divided. Prolonged exposure to fire or heat by the material can result in an explosion.
Odorless
Tasteless
The pH of a 1:20 aqueous solution is between 5 and 9
Safety Information
II
5.1
UN 1484 5.1/PG 2
3
45-9-25-22
53-45
EF8725000
O,T
The warehouse is ventilated, low temperature and dry; lightly loaded and unloaded; stored separately from organic materials, reducing agents, sulfur, phosphorus and flammable materials, food raw materials
Mixed with reducing agent, sulfur, phosphorus, etc., heated, impacted, friction can be explosive
Stability Strong oxidizer - contact with combustible materials may cause fire. Incompatible with combustible material, organics, reducing agents, aluminium, finely powdered metals.
P201, P202, P210, P220, P221, P264, P270, P280, P281, P283, P301+P310, P306+P360, P308+P313, P321, P330, P370+P378, P371+P380+P375, P405, P501
H271
Potassium bromate Use and Manufacturing
Electrolysis method dissolves potassium bromide synthesized from bromine and potassium hydroxide with distilled water to prepare an electrolyte. The first batch of crude product is produced after electrolysis for 24h, and then the crude product is taken every 12h. The crude product is washed with water to remove potassium bromide and then dissolved in distilled water. A small amount of potassium hydroxide was added to adjust the pH value to 8, the temperature was kept for 0.5 h, and then filtered, the clear filtrate was cooled to room temperature in a crystallizer, and crystallized, separated, and dried to obtain potassium bromate product. The anode Br-+6OH-→BrO3-+3H2O+6e cathode 6H++6e→3H2↑KBr+3H2O→KBrO3+3H2↑chlorine oxidation method After the lime milk reacts with bromine, chlorine gas is introduced to perform chlorine oxidation reaction to pH When the value reaches 6-7, the reaction is terminated. After removing the residue, the filtrate was evaporated. Add barium chloride solution to produce barium bromate precipitate. Suspend the filtered precipitate with water, maintain a certain temperature and add potassium carbonate for metathesis reaction. Crude potassium bromate is washed with a small amount of distilled water for many times, then filtered, evaporated, cooled and crystallized, separated and dried. , Crushed to produce edible potassium bromate products. Its 6Ca(OH)2+6Br2→Ca(BrO3)3+5CaBr2+6H2OCaBr2+6Cl2+6Ca(OH)2→Ca(BrO3)2+CaCl2+6H2OCa(BrO3)2+BaCl2→Ba(BrO3)2↓+ CaCl2Ba(BrO3)2+K2CO3→2KBrO3+BaCO3↓
Bread- and flour-improving agent; in analytical chemistry.
Computed Properties
Molecular Weight:167.00
Hydrogen Bond Acceptor Count:3
Exact Mass:165.86679
Monoisotopic Mass:165.86679
Topological Polar Surface Area:57.2
Heavy Atom Count:5
Complexity:49.8
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes
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