2-Bromoethyl ethyl ether
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2-Bromoethyl ethyl ether
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CAS No:
592-55-2
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Formula:
C4H9BrO
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Chemical Name:
2-Bromoethyl ethyl ether
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Synonyms:
Ethane,1-bromo-2-ethoxy-;Ether,2-bromoethyl ethyl;1-Bromo-2-ethoxyethane;2-Bromoethyl ethyl ether;2-Ethoxyethyl bromide;1-Ethoxy-2-bromoethane;1-Bromo-2-ethoxyethylene;2-Bromoethoxyethane;5-Bromo-3-oxapentane;1-Bromo-3-oxapentane;NSC 8026
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CAS No:
Description
clear colorless to brown liquid
2-bromoethyl ethyl ether appears as a colorless liquid. Vapors are heavier than air.
2-bromoethyl ethyl ether appears as a colorless liquid. Vapors are heavier than air.
2-Bromoethyl ethyl ether Basic Attributes
153.018
153.02
209-763-6
AK4DQ3EL7A
8026
2340
DTXSID2060464
2909199090
Characteristics
9.23000
1.43
2-bromoethyl ethyl ether appears as a colorless liquid. Vapors are heavier than air.
1.394 g/cm3 @ Temp: 20 °C
-57ºC
127.5 °C
21.1±0.0 °C
1.440
SLIGHTLY SOLUBLE
Highly flammable. Soluble in water and slightly denser than water.
Ethers
Highly Flammable
Ethers, such as 2-BROMOETHYL ETHYL ETHER, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Safety Information
II
3
UN 2340 3/PG 2
3
R10;R36/37/38
S26-S37/39-S16
KN3950000
Xi:Irritant;
P210-P261-P305 + P351 + P338
H225-H315-H319-H335
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. (ERG, 2016)|Flammable - 3rd degree, Reactive - 1st degree
|Danger|H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]|P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 44 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Do not use straight streams. Move containers from fire area if you can do it without risk. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)
Drug Information
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. (ERG, 2016)
Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. Wash skin with soap and water. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Keep victim calm and warm. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. (ERG, 2016)
2-Bromoethyl ethyl ether Use and Manufacturing
Ethane, 1-bromo-2-ethoxy-: ACTIVE
Fire Hazards -> Flammable - 3rd degree, Reactive - 1st degree
Computed Properties
Molecular Weight:153.02
XLogP3:1.2
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:151.98368
Monoisotopic Mass:151.98368
Topological Polar Surface Area:9.2
Heavy Atom Count:6
Complexity:23.5
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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