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Nonadecane

Nonadecane structure

Nonadecane 

structure
  • CAS No:

    629-92-5

  • Formula:

    C19H40

  • Chemical Name:

    Nonadecane

  • Synonyms:

    Nonadecane;n-Nonadecane;NSC 77136

  • Categories:

    Cosmetic Ingredient  >  Perfuming

Description

white crystalline solid


Wax. (NTP, 1992)|Solid


Wax. (NTP, 1992)|Nonadecane is a straight-chain alkane with 19 carbon atoms. It has been found as a component of essential oils isolated from Artemisia armeniaca. It has a role as a plant metabolite and a volatile oil component.

Nonadecane Basic Attributes

268.52

268.52

1742892

211-116-8

NMY21D3Y5T

77136

1325

DTXSID9047170

Waxy solid|Leaflets|White solidified mass or fragments

29011000

Characteristics

0

9.67 (est)

white semisolid

0.7780 g/cm3

32.1 °C

329.9 °C

335 °F

1.4410

soluble in Chloroform, Hexane.

Store below +30°C.

1 mm Hg ( 133.2 °C)

9.27 (vs air)

0.6-6.5%(V)

Fuel-like

Henry's Law constant = 68 atm-cu m/mol at 25 °C (est)

Hydroxyl radical reaction rate constant = 2.38X10-11 cu cm/molecule-sec at 25 °C (est)

Insoluble in water.

Hydrocarbons, Aliphatic Saturated

Saturated aliphatic hydrocarbons, such as N-NONADECANE, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water.

446 °F (NTP, 1992)

Safety Information

NONH for all modes of transport

3

66-65-34-11

22-24/25-45-36/37/39-26-16

211-116-8

Xn,C,F

Stable. Incompatible with strong oxidizing agents.

P301+P310, P331, P405, P501

H304

SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.|Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging: Dispose of as unused product.

Incompatible materials: Strong oxidizing agents.

Excerpt from ERG Guide 133 [Flammable Solids]: Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare-burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished. (ERG, 2016)

|Danger|H304 (100%): May be fatal if swallowed and enters airways [Danger Aspiration hazard]|P301+P310, P331, P405, and P501|Aggregated GHS information provided by 157 companies from 4 notifications to the ECHA C&L Inventory.

Excerpt from ERG Guide 133 [Flammable Solids]: As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

SMALL SPILLS AND LEAKAGE: You should dampen the solid spill material with acetone, then transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the adsorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a strong soap and water solution. Do not reenter the contaminate area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. RECOMMENDED GLOVE MATERIALS: Permeation data indicate that butyl rubber gloves may provide protection to contact with this compound. Butyl rubber over latex gloves is recommended. However, if this chemical makes direct contact with your gloves, or if a tear, hole or puncture develops, remove them at once. (NTP, 1992)|Eye/face protection: Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).|Handle with gloves.|Body Protection: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.|Respiratory protection: Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.|Advice for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.

ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Avoid dust formation. Avoid breathing vapors, mist or gas. Environmental precautions: Do not let product enter drains. Methods and materials for containment and cleaning up: Sweep up and shovel. Keep in suitable, closed containers for disposal.

ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Avoid dust formation. Avoid breathing vapors, mist or gas. Environmental precautions: Do not let product enter drains.|Precautions for safe handling: Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection.|Appropriate engineering controls: General industrial hygiene practice.|Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.|SRP: The scientific literature for the use of contact lenses by industrial workers is inconsistent. The benefits or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

/Higher alkanes/ may cause eye and skin irritation.

Nonadecane was identified in the extract of some plastic materials from Concon, Chile(1); it was not detected in the surface extract of new plastic bags but was detected in the surface extract of roadside litter and landfill trash at concentrations of 12.2 and 9.2 ug/g, respectively; it was detected in the particulate matter of open burn smoke from new plastic bags, roadside litter, and landfill trash, at concentrations of 6.8, 6.5, and 13.5 ng/mg, respectively; nonadecane was not detected in the surface extract nor the open burn smoke of new plastic bags from the United States(1). Average concentrations of nonadecane emitted as a result of Chinese cooking styles were reported as 72, 75, 69, and 39 ng/mg, for Cantonese style, Sichuan style, Dongbei style, and Hunan style cooking, respectively(2).

SEDIMENTS: Nonadecane was detected in sediment samples from 14 sites along from the Shinano River in Japan, from Nov 2005 to April 2006, at concentrations ranging from less than 0.1 to 32 ng/g(2).|SOIL: During winter 2002 soil and sand samples, from six locations in the Riyadh metropolitan area of Saudi Arabia, were examined for extractable organic matter; nonadecane was detected at relative concentrations between 0.03 to 6.06% (of total extractable organic matter) at five of six locations(1).

URBAN/SUBURBAN:A mean ambient air concentration of 96.3 ng/cu m was reported for nonadecane from monitoring data measured on September 9, 1993 at Central Los Angeles, Azusa, and Claremont(1). In 2002, nonadecane was detected in the gas-phase and the particulate-phase of urban and industrial air samples from Prato, Italy, at average concentrations of approximately 30 and 0.09 ng/cu m, respectively(2). During late fall and winter seasons nonadecane was monitored in the particulate matter of ambient atmospheres in urban areas of Corvallis OR, Guangzhou China, Beijing China, and Taiyuan China, with reported concentrations of not detected, 11.7, 40.5, and 30.1 ng/cu m, respectively(3).|SOURCE DOMINATED: Nonadecane was detected in the gas phase of tailpipe emissions from catalyst equipped gasoline powered motor vehicles at a concentration of 2.0 ug/km; and in the gas and particle phase of tailpipe emissions from non-catalyst equipped gasoline powered motor vehicles at concentrations of 92 and 75 ug/km, respectively; it was also detected in the gasoline at 4.7 ug/g(1).

Toxicity

IDENTIFICATION AND USE: Nonadecane is a solid n-alkane containing 19 carbon atoms (C19). Solid n-alkanes (paraffin waxes) are used in a variety of applications: as feeds for cracking them to gasoline blendstock materials, oxidation, and chlorination reactions. HUMAN EXPOSURE AND TOXICITY: There are no data available. ANIMAL STUDIES: A homologous series of n-alkanes ranging from n-C12-n-C31 was found in all samples of bovine tissues. ECOTOXICITY STUDIES: Volatile organic compounds (heptadecadiene, n-nonadecane, n-tricosane, and octadecene represent 62% of the fraction) released from A. dealbata flowers strongly inhibited germination and seedling growth of selected species, and mainly on its own seedlings.

/PLANTS/ Acacia dealbata is a widespread invader in Mediterranean type ecosystems, and traits promoting its invasiveness are currently under investigation. Due to the dense atmosphere below its canopy, /it was/ hypothesized that volatile organic compounds (VOCs) released from flowers, leaves, litter, or a mixture of treatments exert inhibitory effects on the natives Trifolium subterraneum, Lolium multiflorum, Medicago sativa, and also on its own seeds. ...VOCs from flowers significantly reduced germination in L. multiflorum and A. dealbata; moreover, root length, stem length, above-ground and below-ground biomass were also reduced in all species studied. Volatile organic compounds from flowers and the mixture also increased significantly malondialdehyde content in T. subterraneum and L. multiflorum. The effects of VOCs on antioxidant enzymatic activities were species dependent. Flowers enhanced peroxidase but decreased superoxide dismutase activity in T. subterraneum. In contrast, VOCs released from leaves increased the activity of superoxide dismutase in L. multiflorum. GC/MS analyses revealed 27 VOCs in the volatile fraction from flowers, 12 of which were exclusive to this fraction. Within them, heptadecadiene, n-nonadecane, n-tricosane, and octadecene represent 62% of the fraction. ...Evidence /was presented/ that the VOCs released from A. dealbata flowers strongly inhibited germination and seedling growth of selected species, and mainly on its own seedlings. As far as we know, this is the first evidence of phytotoxicity induced by VOCs in invasive species belonging to the Acacia genus.

Nonadecane is detected in various plants used in food and medicinal applications(1).

Alkanes such as nonadecane may be components in petroleum products(1) and may be released to the environment through the processing and combustion of petroleum products(SRC). Nonadecane's production and use in organic synthesis(2) may result in its release to the environment through various waste streams(SRC).

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 3.2X10+5(SRC), determined from a structure estimation method(2), indicates that nonadecane is expected to be immobile in soil(SRC). Volatilization of nonadecane from moist soil surfaces is expected to be an important fate process(SRC) given an estimated Henry's Law constant of 68 atm-cu m/mole(SRC), using a fragment constant estimation method(3). However, adsorption to soil is expected to attenuate volatilization(SRC). Nonadecane is not expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 4.9X10-5 mm Hg at 25 °C(4). Nonadecane achieved 6 to 27% biodegradation after 28 days in sediment and marine-water inoculums(5), indicating that biodegradation is an important environmental fate process under certain conditions in soil(SRC).|AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 3.2X10+5(SRC), determined from a structure estimation method(2), indicates that nonadecane is expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(3) based upon an estimated Henry's Law constant of 68 atm-cu m/mole(SRC), developed using a fragment constant estimation method(4). Using this Henry's Law constant and an estimation method(3), volatilization half-lives for a model river and model lake are 1.7 hours and 6.5 days, respectively(SRC). However, adsorption to suspended solids and sediment is expected to attenuate volatilization(SRC). The estimated volatilization half-life from a model pond is greater than 2 years if adsorption is considered(5). According to a classification scheme(6), an estimated BCF of 165(SRC), from an estimated log Kow of 9.67(2) and a regression-derived equation(2), suggests the potential for bioconcentration in aquatic organisms is high(SRC). Nonadecane has a calculated half-life of 2.8 days in unacclimated pond-water(7), indicating that biodegradation is an important environmental fate process under certain conditions in water(SRC).|ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), nonadecane, which has a vapor pressure of 4.9X10-5 mm Hg at 25 °C(2), will exist in both the vapor and particulate phases in the ambient atmosphere. Vapor-phase nonadecane is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 16 hours(SRC), calculated from its rate constant of 23.8X10-12 cu cm/molecule-sec at 25 °C(SRC) that was derived using a structure estimation method(3). Particulate-phase nonadecane may be removed from the air by wet and dry deposition(SRC). Nonadecane does not contain chromophores that absorb at wavelengths >290 nm(4) and, therefore, is not expected to be susceptible to direct photolysis by sunlight(SRC).

The rate constant for the vapor-phase reaction of nonadecane with photochemically-produced hydroxyl radicals has been estimated as 23.8X10-12 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1). This corresponds to an atmospheric half-life of about 16 hours at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1). Nonadecane is not expected to undergo hydrolysis in the environment due to the lack of functional groups that hydrolyze under environmental conditions(3). Nonadecane does not contain chromophores that absorb at wavelengths >290 nm(3) and, therefore, is not expected to be susceptible to direct photolysis by sunlight(SRC).

An estimated BCF of 165 was calculated in fish for nonadecane(SRC), using an estimated log Kow of 9.67(1). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is high(SRC).

The Koc of nonadecane is estimated as 3.2X10+5(SRC), using an estimated log Kow of 9.67(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that nonadecane is expected to be immobile in soil.

The Henry's Law constant for nonadecane is estimated as 68 atm-cu m/mole(SRC) using a fragment constant estimation method(1). This Henry's Law constant indicates that nonadecane is expected to volatilize rapidly from water surfaces(2). Based on this Henry's Law constant, the volatilization half-life from a model river (1 m deep, flowing 1 m/sec, wind velocity of 3 m/sec)(3) is estimated as 1.6 hours(SRC). The volatilization half-life from a model lake (1 m deep, flowing 0.05 m/sec, wind velocity of 0.5 m/sec)(3) is estimated as 6.5 days(SRC). However, adsorption to suspended solids and sediment is expected to attenuate volatilization(SRC). The estimated volatilization half-life from a model pond is greater than 2 years if adsorption is considered(4). Nonadecane is not expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 4.9X10-5 mm Hg(5).

DRINKING WATER: Nonadecane was identified but not quantified in tap water samples from 2 sites in Tsukuba, Japan, June 1983(1).|SURFACE WATER: Nonadecane was identified but not quantified in the waters of Besos and Llogregat Rivers, in the coasts of Barcelona and Vilanova-Sitges, and in La Pineda beach, Spain(1). Nonadecane concentrations in suspended particulate matter ranged from 0.1 to 0.29 ug/L in eight stations located in the Guanabara Bay Basin, Rio de Janeiro, Brazil, sampled from September 2011 to August 2012(2).|RAIN/SNOW/FOG: Nonadecane was detected in 6 out of 10 snow samples collected in March 1999 from rural and urban areas in Russia and Finland at concentrations ranging from 0.04 to 1.98 ug/kg(1).

Nonadecane was identified as a volatile component in the edible extract of Korean Chamchwi (Aster scaber Thunb)(1). Nonadecane was detected in the extract of 8 Australian yellow box honey samples, and 8 Australian blue gum honey samples at average concentrations of 0.2 mg/kg(2). Nonadecane was detected in holm-oak, oak, and forest Spanish honeydew honeys in Autumn 2005 at average concentrations of 248.7, 207.9, and 80.7 ug/kg(3).

According to the 2012 TSCA Inventory Update Reporting data, there are 0 reporting facilities for nonadecane(1).|Occupational exposure to nonadecane may occur through inhalation and dermal contact with this compound at workplaces where nonadecane is produced or used. Monitoring data indicate that the general population may be exposed to nonadecane via inhalation of ambient air, ingestion of food and dermal contact with water contaminated by combustion effluents(SRC). The greatest potential for dermal and inhalation exposure is expected during use of petroleum products containing nonadecane(1).

Drug Information

Liver, heart, kidneys, muscle and adipose (perirenal and s.c.) /bovine/ tissues were collected from 6 animals for analysis of their hydrocarbon composition. Qualitative and quantitative determinations were carried out by gas chromatography and combined gas chromatography-mass spectrometry. Although differing in the proportions, a homologous series of n-alkanes ranging from n-C12-n-C31 was found in all samples. The isoprenoid hydrocarbons phytane and phytene (phyt-1-ene and phyt-2-ene) were also identified. (These findings have relevance to the health of humans consuming hydrocarbon-contaminated meats.) /n-Alkanes/

18.00 Days

Excerpt from ERG Guide 133 [Flammable Solids]: Fire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution. (ERG, 2016)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Aliphatic hydrocarbons and related compounds/|/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . Treat frostbite with rapid rewarming techniques ... ./Aliphatic hydrocarbons and related compounds/|/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam (Valium) or lorazepam (Ativan) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Aliphatic hydrocarbons and related compounds/|Emergency and supportive measures. 1. General. Provide basic supportive care for all symptomatic patients. Maintain an open airway and assist ventilation if necessary. Administer supplemental oxygen. Monitor arterial blood gases or oximetry, chest radiographs, and ECG and admit symptomatic patients to an intensive care setting. Use epinephrine and other beta-adrenergic medications with caution in patients with significant hydrocarbon intoxication because arrhythmias may be induced. 2. Pulmonary aspiration. Patients who remain completely asymptomatic after 4-6 hours of observation may be discharged. In contrast, if the patient is coughing on arrival, aspiration probably has occurred. Administer supplemental oxygen and treat bronchospasm and hypoxia if they occur. Do not use steroids or prophylactic antibiotics. 3. Ingestion. In the vast majority of accidental childhood ingestions, less than 5-10 mL is actually swallowed and systemic toxicity is rare. Treatment is primarily supportive. Injection. For injections into the fingertip or hand, especially those involving a high-pressure paint gun, consult with a plastic or hand surgeon immediately, as prompt wide exposure, irrigation, and debridement are often required. /Hydrocarbons/|For more Antidote and Emergency Treatment (Complete) data for n-Nonadecane (7 total), please visit the HSDB record page.

nonadecane

Nonadecane Use and Manufacturing

Methods of Manufacturing

The liquefaction of coal provides the greatest variety of saturated hydrocarbons. The Fischer-Tropsch synthesis produces alkanes from syngas (CO + H2) in the range C1 to C30 or higher depending on the process variant: depending on the catalyst employed, the synthesis yields predominantly liquid hydrocarbons in the gasoline range, along with gases from C1 to C4 when iron-based catalysts are used, while cobalt-based catalysts produce longer chain hydrocarbons in the diesel and wax range that often undergo, depending of the desired product slate, further processing, especially for gasoline generation. While iron-based Fischer-Tropsch catalysts generate complex mixtures that also include branched and olefinic hydrocarbons, cobalt-based catalysts produce streams that are rich in n-alkanes and are therefore suitable raw materials for detergents and for wax products. /Saturated Hydrocarbons/|Suitable sources for n-alkanes with more than six carbon atoms are the appropriate petroleum distillate fractions, from which the n-paraffins can be isolated in high isomeric purity (= 95% linearity) by selective separation techniques, especially fractional distillation. /Higher n-Alkanes/

Uses

Nonadecane is a long chain saturated aliphatic hydrocarbon. Nonadecane is found in tar from coal and other forssil organic matter. Nonadecane is used as a fragrance agent in cosmetics and perfumes.

Nonadecane: ACTIVE|Gas-phase dehydrogenation of n-alkanes over noble-metal catalysts yield the corresponding n-alkenes at low conversion rates (ca. 10%) with predominantly internal double bonds. The corresponding alkenes can be isolated in high purity by selective molecular-sieve processes. /Higher n-Alkanes/

The chloroform-extractable lipid fraction of dissolved organic matter in seawater was analyzed by gravimetry, liquid chromatography, gas chromatography (GC), and gas chromatography-mass spectrometry (GC-MS). Gravimetric concentrations of dissolved lipids in the Gulf of Mexico were in the range of 60-160 mg/L in near-surface waters and 61-116 ug/L in near bottom waters and accounted for approximately 4% of the dissolved organic C. Over a 12-hr sampling period and a 5-day sampling period extensive variability in dissolved lipid quantity and quality were observed. The major percentage of extractable weight was collected in the polar liquid chromatographic fraction (55-95%). Gas chromatographic concentrations of the aliphatic fractions were in the range of 0.014-0.187 ug/L. Concentrations derived from gas chromatography were consistently lower than gravimetrically-derived concentrations. A number of compounds were tentatively identified by a combination of GC, GC-MS, and authentic standards. The major components of the analyzable dissolved lipids were n-alkanes (C16-C32), pristane, phytane, methyl, ethyl and propyl esters of fatty acids. Minor components included olefins and cycloalkanes, aromatics, short-chained acids, and possibly a lactone and an alcohol. All concentrations and compounds were indicative of a fairly pristine environment. The n-alkane distribution appears to be the result of marine and terrestrial inputs superimposed on a chronic low-level background of oil pollution. The fatty acid esters and other fragment molecules may be the result of the degradation of humic substances. A number of potential indicators of source were isolated. /n-Alkanes/

Fatty Acyls [FA] -> Hydrocarbons [FA11]

Computed Properties

Molecular Weight:268.5
XLogP3:9.9
Rotatable Bond Count:16
Exact Mass:268.313001276
Monoisotopic Mass:268.313001276
Heavy Atom Count:19
Complexity:123
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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