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Pyrophosphoric acid

Pyrophosphoric acid structure

Pyrophosphoric acid 

structure
  • CAS No:

    2466-09-3

  • Formula:

    H4O7P2

  • Chemical Name:

    Pyrophosphoric acid

  • Synonyms:

    Diphosphoric acid;Pyrophosphoric acid;Diphosphoric acid (H4P2O7);133883-41-7;1531584-96-9

  • Categories:

    Inorganic Chemistry  >  Inorganic Acid

Description

White to very pale yellow glassy solid


Solid


Diphosphoric acid is an acyclic phosphorus acid anhydride obtained by condensation of two molecules of phosphoric acid. It has a role as an Escherichia coli metabolite. It is a phosphorus oxoacid and an acyclic phosphorus acid anhydride. It is a conjugate acid of a diphosphate(1-).

Pyrophosphoric acid Basic Attributes

177.98

177.98

219-574-0

4E862E7GRQ

289196

DTXSID4075035

2809201900

Characteristics

143.91000

-3.42

Solid

2.4±0.1 g/cm3

61 °C

1.560

709g/100mL H2O (23°C); soluble alcohol, ether [MER06]

145.58 Ų [M+Na]+ [CCS Type: DT, Method: stepped-field]|144.7 Ų [M+Na]+

Safety Information

III

8

UN 3260 8/PG 2

3

22-34

26-36/37/39-45

JL6672500

C

P260, P264, P270, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P405, P501

H302

|Danger|H302 (46.91%): Harmful if swallowed [Warning Acute toxicity, oral]|P260, P264, P270, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P405, and P501|Aggregated GHS information provided by 114 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P260, P261, P264, P271, P280, P301+P330+P331, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P363, P405, and P501

Drug Information

diphosphoric acid

Pyrophosphoric acid Use and Manufacturing

Methods of Manufacturing

The production of pyrophosphorus includes a method of dehydrating and concentrating 85% of commercially available phosphoric acid, dissolving phosphorus pentoxide in 85% of phosphoric acid, and a method of reacting phosphoryl chloride with 85% of phosphoric acid. The 85% phosphoric acid concentration method avoids local overheating of commercially available 85% phosphoric acid and heats it to about 180°C under reduced pressure for dehydration (100g 85% phosphoric acid has a weight loss of about 25-30g) to produce pyrophosphoric acid. Method of dissolving P2O5 in 85% phosphoric acid Under vigorous stirring, add P2O5 to the phosphoric acid in a calculated amount (100g85% phosphoric acid plus 95-100g P2O5) little by little, and dissolve it while heating until it becomes transparent. Add water to the generated pyrophosphoric acid to adjust the P2O5 content to about 76% to 79%. The pyrophosphoric acid is naturally placed (to keep moisture-proof) to form crystals, and it takes two to three days to form crystals under ice cooling to produce pyrophosphoric acid. Method of seeding liquid pyrophosphate. This is a method for mass production of high-purity crystalline pyrophosphate (type I or type II). The commercially available polyphosphoric acid (also called 116% phosphoric acid) containing 84% P2O5 is diluted with water Make liquid pyrophosphoric acid (P2O579.76%), add an appropriate amount (10%-50% by weight) of type I or type II pyrophosphoric acid seed crystals, in a dry nitrogen stream to prevent moisture, stir at 30-50℃, After an induction period of 60 to 180 min, crystalline pyrophosphate can be prepared with a purity of >95%.

Uses

Used as a catalyst, metal refining, organic peroxide stabilizer. Used to adjust the Ph value of the electroplating solution in the copper electroplating process, and also used in other electroplating. Used as a catalyst and hiding agent, etc. Water retention agent, quality improver, pH adjuster, metal chelating agent.

Computed Properties

Molecular Weight:177.98
XLogP3:-3.2
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:2
Exact Mass:177.94322646
Monoisotopic Mass:177.94322646
Topological Polar Surface Area:124
Heavy Atom Count:9
Complexity:147
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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