3-Fluorotoluene

110.13

110.13

1903631

206-524-8

F72W445DQ0

8860

2388

DTXSID2059855

29036990

0

2.73

3-fluorotoluene appears as a colorless liquid with an aromatic odor. Boiling point 239°C. Flash point 63°F. Density 0.991 g / cm3 --- may float or sink in water. (USCG, 1999)

0.9972 g/cm³ @ Temp: 13.4 °C

-87 °C

115 °C

49 °F

1.477

H2O: immiscible

Store below +30°C.

42.39 mm Hg (USCG, 1999)

Highly flammable.

Aryl Halides

Highly Flammable

3-FLUOROTOLUENE may be incompatible with strong oxidizing and reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Generates toxic fluoride fumes when burned.

II

3

UN 2388 3/PG 2

2

11-36/37/38

16-26-36-37/39

XT2578000

F,Xi

Flammable/Irritant

P210-P261-P305 + P351 + P338

H225-H315-H319-H335

Special Hazards of Combustion Products: May contain toxic fluoride fumes. Behavior in Fire: May produce toxic and irritating fluoride fumes. (USCG, 1999)

Fire Extinguishing Agents: Small fires: dry chemical, CO 2 , water spray or foam; large fires: water spray, fog or foam. (USCG, 1999)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)

Wear self-contained positive pressure breathing apparatus and full protective clothing. (USCG, 1999)

Inhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed. (USCG, 1999)

INHALATION: Move to fresh air. If not breathing, give artificial respiration. if breathing is difficult, give oxygen. EYES OR SKIN: Flush with running water for at least 15 min.; hold eyelids open if necessary. Remove and isolate contaminated clothing and shoes at the site. INGESTION: If victim is conscious, have victim drink water or milk. DO NOT INDUCE VOMITING. If victim is UNCONSCIOUS OR HAVING CONVULSIONS, do nothing except keep victim warm. (USCG, 1999)

Benzene, 1-fluoro-3-methyl-: ACTIVE