2,2′-Benzidinedisulfonic acid
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2,2′-Benzidinedisulfonic acid
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CAS No:
117-61-3
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Formula:
C12H12N2O6S2
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Chemical Name:
2,2′-Benzidinedisulfonic acid
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Synonyms:
[1,1′-Biphenyl]-2,2′-disulfonic acid,4,4′-diamino-;2,2′-Biphenyldisulfonic acid,4,4′-diamino-;4,4′-Diamino[1,1′-biphenyl]-2,2′-disulfonic acid;2,2′-Disulfobenzidine;2,2′-Benzidinedisulfonic acid;6,6′-Bimetanilic acid;4,4′-Diaminobiphenyl-2,2′-disulfonic acid;4,4′-Diaminodiphenyl-2,2′-disulfonic acid;2,2′-Disulfo-4,4′-diaminobiphenyl;NSC 3763;4,4′-Diaminobiphenyl-2,2′-bis(sulfonic acid);4,4′-Benzidine-2,2′-disulfonic acid;4,4′-Diamino-[1,1′-biphenyl]-2,2′-disulfonic acid;1351935-87-9
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CAS No:
Description
CBI
Leaflets or prisms or light purple powder. (NTP, 1992)
Leaflets or prisms or light purple powder. (NTP, 1992)
2,2′-Benzidinedisulfonic acid Basic Attributes
344.36
344.36
204-200-0
ALF643N2EQ
3763
DTXSID3024572
2921590090
Characteristics
178
-0.3
Dark purple Powder
1.7±0.1 g/cm3
168 °C @ Solvent: Water
1.703
H2O: <0.1 g/100 mL at 20 ºC
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammable; burning produces toxic nitrogen oxides and sulfur oxide fumes
Insoluble in water.
Sulfonates, Phosphonates, and Thiophosphonates, Organic
Safety Information
20/21/22-37/38-36-36/37/38
22-26-36-60-37
DV5230000
Xi
Ventilated, low temperature and dry
Stable under normal temperatures and pressures.
P201, P202, P264, P280, P281, P302+P352, P305+P351+P338, P308+P313, P321, P332+P313, P337+P313, P362, P405, P501
H315
Flash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)
|Warning|H315 (13.04%): Causes skin irritation [Warning Skin corrosion/irritation]|P201, P202, P264, P280, P281, P302+P352, P305+P351+P338, P308+P313, P321, P332+P313, P337+P313, P362, P405, and P501|Aggregated GHS information provided by 57 companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material under ambient temperatures. (NTP, 1992)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Drug Information
SYMPTOMS: Symptoms of exposure to this compound include eye irritation. ACUTE/CHRONIC HAZARDS: This chemical is an eye irritant. When heated to decomposition it emits very toxic fumes of sulfur oxides and nitrogen oxides. (NTP, 1992)
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
2,2′-Benzidinedisulfonic acid Use and Manufacturing
For organic synthesis
Printing ink manufacturing|[1,1'-Biphenyl]-2,2'-disulfonic acid, 4,4'-diamino-: ACTIVE
Computed Properties
Molecular Weight:344.4
XLogP3:-0.3
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:3
Exact Mass:344.01367845
Monoisotopic Mass:344.01367845
Topological Polar Surface Area:178
Heavy Atom Count:22
Complexity:540
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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