Acid Blue 7
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Acid Blue 7
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CAS No:
3486-30-4
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Formula:
C37H36N2O6S2.Na
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Chemical Name:
Acid Blue 7
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Synonyms:
Benzenemethanaminium,N-[4-[(2,4-disulfophenyl)[4-[ethyl(phenylmethyl)amino]phenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-ethyl-,inner salt,sodium salt (1:1);Alphazurine A;C.I. Acid Blue 7,sodium salt;Benzenemethanaminium,N-[4-[(2,4-disulfophenyl)[4-[ethyl(phenylmethyl)amino]phenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-ethyl-,hydroxide,inner salt,sodium salt;C.I. Acid Blue 7;Benzenemethanaminium,N-[4-[(2,4-disulfophenyl)[4-[ethyl(phenylmethyl)amino]phenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-ethyl-,inner salt,sodium salt;C.I. 42080;Acid Turquoise Blue A;Aizen Brilliant Acid Blue AFH;D and C Blue No. 3;Brilliant Acid Blue AS;Brilliant Acid Blue N Extra;Bucacid Patent Blue AF;Calcocid Blue AX;Carmine Blue AF;Disulphine Blue AN;Disulphine Lake Blue AN;Erio Glaucine X;Erio Glaucine XS;Ext D and C Blue No. 3;Fenazo Blue XG;Hidacid Blue A;Hidacid Blue AF;Kiton Blue A;Lake Blue AFX;Merantine Blue AF;Patent Blue A;Patent Blue AF;Pontacyl Brilliant Blue A;Shimazaki Patent Blue AFX;Tertracid Carmine Blue A;Vulcol Blue BZ;Xylene Blue AS;Acid Sky Blue 0;Acid Sky Blue O;Acid Blue O;Kayacyl Pure Blue FGA;Sandolan Turquoise E-AS;Acid Turquois Blue A;Acid Blue 7;C-WR Blue 11;Acid Brilliant Blue AF;Acid Patent Blue AS;Acid Turquoise Blue 2G;Sandolan Turquoise E-AS 100;Colocid Patent Blue AS;Acid Turquoise Blue B;Dinacid Patent Blue AS;Vicoacid Blue 7;Ratna Acid Blue AS;86280-78-6
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CAS No:
Characteristics
137.41000
8.28440
Dark purple Crystalline Powder
290 °C (dec.)(lit.)
Peritoneal-mouse LD50: 437 mg/kg
Combustible; Decomposes by heating to release toxic nitrogen oxide, sodium oxide and sulfur oxide fumes
Safety Information
NONH for all modes of transport
3
S24/25
DA4427950
Warehouse ventilated, low temperature and dry
Stable. Incompatible with strong oxidizing agents.
P201, P202, P261, P264, P271, P273, P280, P281, P302+P352, P304+P340, P305+P351+P338, P308+P313, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
H315
Not Classified
Acid Blue 7 Use and Manufacturing
Using 2, 4-disulfonic acid benzaldehyde and N-ethyl-N-benzylaniline as raw materials, the two are first condensed, and the product is obtained by oxidation. The finished product is obtained by salting out and drying. Dissolve 54kg of 2, 4-disulfonic acid benzaldehyde (100%) in 81kg of sulfuric acid (100%). When heated to 45-50℃, add 91.8kg of N-ethyl-N-benzylaniline (100%) , The temperature is raised to 100-103 ℃, the condensation reaction is maintained for 72 hours, filtered, the filter cake is purified with sulfuric acid and hydrochloric acid, the purified condensation product is melted with sodium carbonate alkali, and 2.475-2.625kg potassium dichromate (100%) is added. 1.29kg sulfuric acid, 5.4kg acetic acid, 3.6kg oxalic acid, oxidized at 100℃ for 1h, salted out, filtered and dried to obtain the finished product. There is a manganese dioxide oxidation process abroad. The operation is as follows: add 1mol/L sodium hydroxide solution 40mL to the suspension formed by 12.5g leuco body and 400mL water, then add 400mL water, heat up to 85-95℃, add 2.1g A suspension of manganese dioxide and 20 g of water was added with a mixture of 4 g of acetic acid and 5.25 g of 8% phosphoric acid while stirring, stirred at 85-95°C for 15 min, and filtered. The filtrate was salted out with 6%-7% sodium chloride, filtered, and dried at 100-105°C to obtain 15g of product (Pol.126654).
Acid Turquoise Blue 2G can be used for dyeing wool, silk, nylon and direct printing of wool and silk fabrics. It has good level dyeing properties, beautiful color, but poor fastness, and the light fastness is only Grade 2. It can be combined with acid bright yellow 2G to dye bright fruit green and emerald green, and it can also be combined with dyes such as navy blue and red to increase the vividness of dyeing. It can also be used to color leather, paper, cosmetics, soap, biological products, and make lake pigments.
Benzenemethanaminium, N-[4-[(2,4-disulfophenyl)[4-[ethyl(phenylmethyl)amino]phenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-ethyl-, inner salt, sodium salt (1:1): ACTIVE
Cosmetics -> Cosmetic colorant
Computed Properties
Molecular Weight:690.8
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:9
Exact Mass:690.18342347
Monoisotopic Mass:690.18342347
Topological Polar Surface Area:137
Heavy Atom Count:48
Complexity:1280
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes
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