Isobutyl iodide
-
Isobutyl iodide
structure -
-
CAS No:
513-38-2
-
Formula:
C4H9I
-
Chemical Name:
Isobutyl iodide
-
Synonyms:
Propane,1-iodo-2-methyl-;1-Iodo-2-methylpropane;Isobutyl iodide;2-Methylpropyl iodide;3-Iodo-2-methylpropane;NSC 8421;2-Methyl-1-iodopropane;1-Iodoisobutane;2-Methylpropan-1-yl iodide
- Categories:
-
CAS No:
Description
clear colorless to light orange liquid
Iodomethylpropane appears as a colorless liquid mixture of isomers that discolors in air. Denser than water. Vapors are heavier than air. May be mildly toxic by inhalation. Used as a solvent and to make pharmaceuticals.
Iodomethylpropane appears as a colorless liquid mixture of isomers that discolors in air. Denser than water. Vapors are heavier than air. May be mildly toxic by inhalation. Used as a solvent and to make pharmaceuticals.
Isobutyl iodide Basic Attributes
184.02
184.02
1730927
208-160-5
82IJ6B9708
8421
2391
DTXSID9060154
29033080
Characteristics
0
2.91
Clear colorless to light orange Liquid
1.58693 g/cm3 @ Temp: 30 °C
-93 °C
121.1 °C
55 °F
1.501
H2O: insoluble ;alcohol: miscible(lit.)
Flammables area
20 mm Hg ( 20 °C)
6 (vs air)
Abdominal cavity-rat LD50: 1241 mg/kg; abdominal cavity-mouse LD50: 594 mg/kg
Inflammable in case of open flame, high temperature, oxidant; produces toxic iodide gas in case of heat
Highly flammable. Slightly soluble in water.
Halogenated Organic Compounds
Highly Flammable
IODOMETHYLPROPANES are incompatible with strong oxidizing and reducing agents. Also, incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Safety Information
II
3
UN 2391 3/PG 2
3
11-36/37/38-20-53
16-26-36-9-33
TZ4250000
F,Xi,Xn
The warehouse is ventilated, low temperature, dry and protected from light; stored separately from oxidants
P210-P261-P305 + P351 + P338-P311
H225-H315-H319-H331-H335
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. (ERG, 2016)
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam. Do not use dry chemical extinguishers to control fires involving nitromethane (UN1261) or nitroethane (UN2842). LARGE FIRE: Water spray, fog or alcohol-resistant foam. Do not use straight streams. Move containers from fire area if you can do it without risk. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)
Drug Information
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. (ERG, 2016)
Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. Wash skin with soap and water. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Keep victim calm and warm. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. (ERG, 2016)
Isobutyl iodide Use and Manufacturing
It is derived from the reaction of isobutanol and phosphorus triiodide. First mix red phosphorus and isobutanol, heat on a water bath, slowly add iodine, continue to react for 4 hours after the addition, distill the crude product, and then perform fractional distillation, collect the 119-122 ℃ distillate to obtain the finished product.
Used as organic solvent, also used in organic synthesis
Propane, 1-iodo-2-methyl-: ACTIVE
Computed Properties
Molecular Weight:184.02
XLogP3:2.8
Rotatable Bond Count:1
Exact Mass:183.97490
Monoisotopic Mass:183.97490
Heavy Atom Count:5
Complexity:17.6
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
Recommended Suppliers of Isobutyl iodide
-
CN
5 YRS
Business licensed Certified factoryManufactory Supplier of Chemical Pesticides,Food Additives,Agrochemicals,Active Pharm Ingredients,Flavors and Fragrances,Chemical Catalyst,Chemical Materials,Chem&Pharm Intermediates,Organic Intermediates,Feed AdditiveInquiryCAS No.: 513-38-2Grade: Industrial GradeContent: 99% -
CN
5 YRS
Business licensedTrader Supplier of PVC resin,pvc paste resin,melamineInquiryCAS No.: 513-38-2Grade: Industrial GradeContent: 99% -
CN
4 YRS
Business licensed Certified factoryManufactory Supplier of Flavors & Fragrances,Catalyst & Auxiliary,Intermediates,Dyes & Pigments,Inorganic Chemistry,petro chemicals,Surfactant,Food Additives,Water Treatment Chemicals
Learn More Other Chemicals
-
2,4-DICHLOROBENZYL IODIDE
116529-35-2
-
1H-Imidazo[4,5-b]quinoxalinium, 2-[2-(3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl)ethenyl]-1,3-di-2-propen-1-yl-, iodide (1:1)
23427-51-2
-
Germanium iodide (GeI2)
13573-08-5
-
2-Propyn-1-aminium, N,N,N-trimethyl-, iodide (1:1) Formula
7383-74-6
-
Acridinium, 9-amino-10-methyl-, iodide (1:1) Formula
36141-84-1
-
1-Propanaminium, 2-hydroxy-N,N-dimethyl-N-(1-methylethyl)-3-(1-naphthalenyloxy)-, iodide (1:1) Formula
38726-81-7
-
1-Methyl-4,4′-bipyridinium iodide Structure
38873-01-7
-
Benzenaminium, 4-[[(dimethylamino)carbonyl]oxy]-N,N,N-trimethyl-2-(1-methylethyl)-, iodide (1:1) Structure
63981-53-3
-
What is Ethanaminium, N-ethyl-2-hydroxy-N,N-dimethyl-, iodide (1:1)
1113-04-8
-
What is Naphtho[2,1-f]quinolinium, 1,2,3,4,4a,4b,5,7,8,9,10,10a,10b,11,12,12a-hexadecahydro-1,1,10a,12a-tetramethyl-8-(1-methylpyrrolidinio)-, iodide (1:2), (4aS,4bR,8S,10aR,10bS,12aS)-
54278-85-2