(+)-Lupanine
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(+)-Lupanine
structure -
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CAS No:
550-90-3
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Formula:
C15H24N2O
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Chemical Name:
(+)-Lupanine
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Synonyms:
7,14-Methano-2H,11H-dipyrido[1,2-a:1′,2′-e][1,5]diazocin-11-one,dodecahydro-,(7S,7aR,14S,14aS)-;Lupanine;7,14-Methano-2H,11H-dipyrido[1,2-a:1′,2′-e][1,5]diazocin-11-one,dodecahydro-,[7S-(7α,7aα,14α,14aβ)]-;Lupanine,d-;(7S,7aR,14S,14aS)-Dodecahydro-7,14-methano-2H,11H-dipyrido[1,2-a:1′,2′-e][1,5]diazocin-11-one;Lupanin;2-Oxosparteine;(+)-Lupanine;7,14-Methano-4H,6H-dipyrido[1,2-a:1′,2′-e][1,5]diazocin-4-one,dodecahydro-,[7S-(7α,7aβ,14α,14aα)]-;d-Lupanine;(+)-2-Oxosparteine;D-(+)-Lupanine;D-Lupanine;1617-54-5;15043-15-9
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CAS No:
Description
ChEBI: The delta-lactam obtained by formal oxidation at the 2-position of sparteine. The major alkaloid from the seeds of Lupinus exaltatus, L. mexicanus and L. rotundiflorus, it is among the most important of the tetracyc ic quinolizidine alkaloids.
Lupanine is the delta-lactam obtained by formal oxidation at the 2-position of sparteine. The major alkaloid from the seeds of Lupinus exaltatus, L. mexicanus and L. rotundiflorus, it is among the most important of the tetracyclic quinolizidine alkaloids. It is a quinolizidine alkaloid, a tertiary amine and a delta-lactam. It is a conjugate base of a lupanine(1+). It derives from a hydride of a sparteine.
Characteristics
23.55000
13.33
0.9±0.1 g/cm3
99 °C
186-188 °C @ Press: 1 Torr
221.8±13.1 °C
1.498
D25 +84° (c = 4.8 in alc)
Computed Properties
Molecular Weight:248.36
XLogP3:1.6
Hydrogen Bond Acceptor Count:2
Exact Mass:248.188863393
Monoisotopic Mass:248.188863393
Topological Polar Surface Area:23.6
Heavy Atom Count:18
Complexity:356
Defined Atom Stereocenter Count:4
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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