Pigment Red 49:1

892.11

892.02400

214-160-6

XA4L9U490C

DTXSID0027359

221.06000

12.19780

DryPowder; WetSolid

310 - 311ºC

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

II; III

6.1

3

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D005, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.|... Ion exchange, lime softening and reverse osmosis are effective to remove barium from drinking water. Conventional coagulation/filtration processes are not effective to remove barium from drinking water. /Barium ion/|Package lots. Place in a separate labeled container for recycling or disposal. Small quantities. Wear nitrile rubber gloves, laboratory coat, and eye protection. Avoid breathing dust. Dissolve the barium salt in the minimum volume of water. For each gram of barium salt, add 15 mL of 10% sodium sulfate solution. Let stand for 1 week. Test for completeness of precipitation by adding a few drops of 10% sodium sulfate solution. If required, add more sodium sulfate solution until no further precipitation occurs. Decant supernatant liquid or filter solid. Treat solid as normal refuse. Wash liquid into drain. /Barium salt/

European Commission, ESIS; IUCLID Dataset, Barium bis [2-[(2-hydroxynaphthyl)azo]naphthalenesulphonate (1103-38-4) (2000 CD-ROM edition) contains information on use, toxicology, and environmental effects of this chemical as supplied to the European Union by industry .[Available from, as of November 17, 2010: http://esis.jrc.ec.europa.eu/]

Not Classified

The only foreseeable danger would be from dust. The effects of this on the workforce can be minimized by the use of local exhaust ventilation and by wearing a suitable respirator if necessary.[European Commission, ESIS; IUCLID Dataset, Barium bis [2-

If material on fire or involved in fire: Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources. /Barium compounds, NOS/|Wear positive pressure self-contained breathing apparatus. /Barium compounds NOS/

Environmental considerations - land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. /SRP: If time permits, pits, ponds, lagoons, soak holes, or holding areas should be sealed with an impermeable flexible membrane liner./ Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents. /Barium/|Environmental considerations - water spill: Use natural barriers or oil spill control booms to limit spill travel. Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom. Remove trapped material with suction hoses. /Barium/|Environmental considerations - air spill: Apply water spray or mist to knock down vapors. /Barium/

If employees' clothing has had any possibility of being contaminated with barium carbonate, barium chloride, barium nitrate ... or liq containing these cmpd, employees should change into uncontaminated clothing before leaving the work premises. ... Clothing contaminated with barium carbonate, barium chloride, barium nitrate ... should be placed in closed containers for storage until it can be discarded or until provision is made for the removal of contaminant from the clothing. If the clothing is to be laundered or otherwise cleaned to remove the contaminant, the person performing the operation should be informed of contaminant's hazardous properties. ... Non-impervious clothing which becomes contaminated with barium carbonate, barium chloride, barium nitrate ... should be removed promptly and not reworn until the contaminant is removed from the clothing. /Soluble barium cmpd/|Skin that becomes contaminated with barium carbonate, barium chloride, or barium nitrate should be promptly washed or showered to remove any contaminant. In the case of barium carbonate, employees should use soap or mild detergent and water for washing purposes. /Soluble barium cmpd/|Eating and smoking should not be permitted in areas where solid barium carbonate, barium chloride, barium nitrate ... or liq containing these cmpd are handled, processed, or stored. Employees who handle barium carbonate, barium chloride, barium nitrate ... or liq containing these cmpd should wash their hands thoroughly before eating, smoking, or using toilet facilities. In the case of barium carbonate, employees should use soap or mild detergent and water for washing purposes. /Soluble barium cmpd/|To keep dust concn below recommended levels, processes should be enclosed &/or exhaust ventilation installed. Adequate washing & other sanitary facilities should be provided ... & rigorous personal hygiene measures should be encouraged. Smoking & consumption of food & beverages in workshops should be prohibited. Floors in workshops should be made of impermeable materials & frequently washed down. /Barium & compounds/|For more Preventive Measures (Complete) data for Barium lithol red (10 total), please visit the HSDB record page.

/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Health: TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. /Barium compound, NOS/|/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. /Barium compound, NOS/|/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Public Safety: CALL Emergency Response Telephone Number ... As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas. /Barium compound, NOS/|/GUIDE 154: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Barium compound, NOS/|For more DOT Emergency Guidelines (Complete) data for Barium lithol red (8 total), please visit the HSDB record page.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.

LD50 Rat (unknown strain) Oral >5,000 mg/kg

NIOSH (NOES Survey 1981-1983) has statistically estimated that 78,115 workers (10,072 of these were female) were potentially exposed to barium lithol red in the US(1).

The impurity beta-naphthol ranged from 13.6 to 1260.0 ppm in 7 samples of Red No. 207.

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Barium and Related Compounds/|Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Do not attempt to neutralize because of exothermic reaction. Cover skin burns with dry sterile dressings after decontamination ... . /Barium and Related Compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious or is in severe respiratory distress. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of 0.9% saline (NS) or lactated Ringer's (LR) /SRP: "To keep open", minimal flow rate/. For hypotension with signs of hypovolemia, administer fluid cautiously Watch for signs of fluid overload. For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Barium and Related Compounds/

Dry color, presscake, and dispersion grades|A typical low cost, water-based ink formula is: water, 62 wt%; barium lithol red, 15 wt%; isolated soya protein, 5 wt%; octyl alcohol (defoamer), 5 wt%; ammonium hydroxide, 2 wt%; microcrystalline wax, 1 wt%. A typical better wet and dry rub resistance, water-based ink formula is: water, 63.5 wt%; carboxylated acrylic resin, 18 wt%; barium lithol red, 15 wt%; ammonium hyroxide, 2 wt%; polyethylene wax, 1 wt%; fatty acid ester or silicone defoamer, 0.5 wt%. The diluents for both are: normal diluent, water; slow-drying diluent, glycol ether or glycol and fast-drying diluent, ethanol

Paint and coating manufacturing|1-Naphthalenesulfonic acid, 2-[2-(2-hydroxy-1-naphthalenyl)diazenyl]-, barium salt (2:1): ACTIVE|When used by customers the substance is bound into the final product.[European Commission, ESIS; IUCLID Dataset, Barium, bis[2-|Insoluble Na, Ba, Ca salts of soluble azo dye. /Lithols/