Diethylene glycol dibutyl ether
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Diethylene glycol dibutyl ether
structure -
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CAS No:
112-73-2
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Formula:
C12H26O3
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Chemical Name:
Diethylene glycol dibutyl ether
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Synonyms:
Butane,1,1′-[oxybis(2,1-ethanediyloxy)]bis-;Ether,bis(2-butoxyethyl);1,1′-[Oxybis(2,1-ethanediyloxy)]bis[butane];Bis(2-butoxyethyl) ether;2,2′-Dibutoxyethyl ether;Dibutyl Carbitol;5,8,11-Trioxapentadecane;Diethylene glycol dibutyl ether;2-Butoxyethyl ether;2-(2-Butoxyethoxy)-1-butoxyethane;Butex;DBDG;Hisolve BDB;Butyl diglyme;1-[2-(2-Butoxyethoxy)ethoxy]butane;201468-65-7
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CAS No:
Description
clear colorless to yellowish liquidColorless liquid. Floats on water.
Diethylene glycol dibutyl ether is a colorless liquid. Floats on water. (USCG, 1999)|Liquid
Diethylene glycol dibutyl ether is a colorless liquid. Floats on water. (USCG, 1999)
Diethylene glycol dibutyl ether Basic Attributes
218.33304
218.33
204-001-9
F8P3DHG73Z
DTXSID8025046
29091900
Characteristics
27.7
2.39
Diethylene glycol dibutyl ether is a colorless liquid. Floats on water. (USCG, 1999)
0.8847 g/cm3 @ Temp: 16 °C
-60 °C
256 °C
245° F (NTP, 1992)
n 20/D 1.423(lit.)
H2O: 3g/l
<0.01 mm Hg ( 20 °C)
greater than 1 (NTP, 1992) (Relative to Air)
LD50 orally in Rabbit: 3900 mg/kg LD50 dermal Rabbit 3555 mg/kg
Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. Insoluble in water.
Ethers
Peroxidizable Compound
DIETHYLENE GLYCOL DIBUTYL ETHER may react violently with strong oxidizing agents. Incompatible with nitric acid. May form salts with strong acids and addition complexes with Lewis acids. In other reactions, which typically involve the breaking of the carbon-oxygen bond, relatively inert.
590 °F (NTP, 1992)
Safety Information
I; II; III
NONH for all modes of transport
1
23-24/25
KN0350000
P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, P501
H226
Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back. (USCG, 1999)
Not Classified
Fire Extinguishing Agents: Water spray, dry chemical, alcohol foam. (USCG, 1999)
SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. (USCG, 1999)
Drug Information
May be harmful by inhalation, ingestion and skin absorption. Causes eye and skin irritation. Material is irritating to mucous membrane and upper respiratory tract. (USCG, 1999)
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Diethylene glycol dibutyl ether Use and Manufacturing
Butyl diglyme is used to extract gold from hydrochloric acid solutions containing other metals. Treatment of the diglyme extract with hydrogen or oxalic acid precipitates the ionic gold as gold powder.
Processing aids, not otherwise listed
Solvent
All other basic organic chemical manufacturing|Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-: ACTIVE|S - indicates a substance that is identified in a final Significant New Use Rule.
Computed Properties
Molecular Weight:218.33
XLogP3:1.9
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:12
Exact Mass:218.18819469
Monoisotopic Mass:218.18819469
Topological Polar Surface Area:27.7
Heavy Atom Count:15
Complexity:95
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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