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Diethylenetriamine 111-40-0

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Unit Price: Get Latest Price
CAS No.:

111-40-0

Grade:

Industrail Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2025-12-26

Company Type:
Trader
Location:
China
Qualification:
Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

  • Product Description

  • Seller Information

  • Inquiry History

  • Description
    Diethylenetriamine Basic information
    Product Name: Diethylenetriamine
    Synonyms: (Aminoethyl)ethanediamine;1,2-Ethanediamine,N-(2-aminoethyl)-;1,4,7-Triazaheptane;1,5-Diamino-3-azapentane;2,2’-diamino-diethylamin;2,2’-iminobis(ethanamine);2,2’-iminobis-ethylamin;2,2’-iminobis-ethylenediamine,n-(2-aminoethyl)-ethylamin
    CAS: 111-40-0
    MF: C4H13N3
    MW: 103.17
    EINECS: 203-865-4
    Product Categories: Organics;organic amine;1
    Mol File: 111-40-0.mol
    Shop Diethylenetriamine 111-40-0-Detailed Image 1

    Diethylenetriamine Chemical Properties
    Melting point  -40 °C
    Boiling point  206 °C
    density  0.955 g/mL at 25 °C(lit.)
    vapor density  3.6 (vs air)
    vapor pressure  0.08 mm Hg ( 20 °C)
    refractive index  n20/D 1.484(lit.)
    Fp  90 °C
    storage temp.  Store below +30°C.
    solubility  Chloroform (Soluble), Methanol (Slightly)
    pka pK1:4.42(+3);pK2:9.21(+2);pK3:10.02(+1) (25°C)
    form  Liquid
    color  Clear
    Odor Strong ammoniacal; mildly ammoniacal.
    PH >12 (100g/l, H2O, 20℃)
    explosive limit 1-10%(V)
    Water Solubility  miscible
    Sensitive  Air Sensitive
    BRN  605314
    Exposure limits ACGIH: TWA 1 ppm (Skin)
    NIOSH: TWA 1 ppm(4 mg/m3)
    Stability: Stable, but absorbs carbon dioxide from the air. Incompatible with strong oxidizing agents, copper and its alloys.
    InChIKey RPNUMPOLZDHAAY-UHFFFAOYSA-N
    LogP -1.58 at 20℃
    CAS DataBase Reference 111-40-0(CAS DataBase Reference)
    NIST Chemistry Reference 1,2-Ethanediamine, N-(2-aminoethyl)-(111-40-0)
    EPA Substance Registry System Diethylenetriamine (111-40-0)

    Safety Information
    Hazard Codes  C,T+
    Risk Statements  21/22-34-43-37-26
    Safety Statements  26-36/37/39-45-28
    RIDADR  UN 2079 8/PG 2
    OEB B
    OEL TWA: 1 ppm (4 mg/m3) [skin]
    WGK Germany  2
    RTECS  IE1225000
    Autoignition Temperature 676 °F
    TSCA  Yes
    HazardClass  8
    PackingGroup  II
    HS Code  29212900
    Hazardous Substances Data 111-40-0(Hazardous Substances Data)
    Toxicity LD50 orally in Rabbit: 1540 mg/kg


    Diethylenetriamine Usage And Synthesis
    Description Diethylenetriamine is a hardener in epoxy resins of the Bisphenol A type. It has been reported as a sensitizer in ultrasonic baths for cleaning jewels, in synthetic lubricants and in carbonless copy paper.
    Chemical Properties Diethylenetriamine is a corrosive yellow liquid and a solvent. It has a strong ammonia odor and is prone to absorbing moisture. It can dissolve in water, acetone, benzene, ether, methanol, but is not soluble in n-heptane.
    Uses Diethylenetriamine is a solvent for sulfur, acidic gas, resin and dye intermediates for organic synthesis; saponification agent for acidic materials; fuel component; hardener for epoxy resins.
    Definition ChEBI: Diethylenetriamine is a triamine and a polyazaalkane.
    Production Methods Diethylenetriamine is produced by the reaction of ethylene dichloride with ammonia. Diethylenetriamine is used in biological studies, for polyamines inhibition to carbonic anhydrases by anchoring to the zinc-coordinated water molecule.
    Synthesis Reference(s) Journal of the American Chemical Society, 105, p. 5002, 1983 DOI: 10.1021/ja00353a025
    General Description A yellow liquid with an ammonia-like odor. Less dense than water. Corrosive to metals and tissue. Vapors heavier than air. Burns, although possibly difficult to igntie. Toxic oxides of nitrogen produced during combustion. Used as a solvent for plastics and dyes and in chemical synthesis.
    Air & Water Reactions Soluble in water.
    Reactivity Profile Diethylenetriamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
    Health Hazard Prolonged breathing of vapors may cause asthma. Liquid burns skin and eyes. A skin rash can form.
    Health Hazard Brief contact with concentrated diethylenetriamine can produce severe local injury to the eyes and skin resembling the effect from strong base. Human subjects are susceptible to sensitization responses either as dermatitis or an asthma-like response. A time-weighted average of 1 p.p.m. is recommenced for diethylenetriamine (ACGIH 1986).
    Fire Hazard Special Hazards of Combustion Products: Irritating vapors are generated when heated.
    Flammability and Explosibility Non flammable
    Industrial uses Diethylenetriamine is used as an intermediate in the production of reactive polyamide resins, and in the production of aminoamides and imidazolines from fatty acids. It is also used in the production of paper wet strength resins and piperazine. Diethylenetriamine serves as a solvent for sulfur, acid gases, resins and dyes (HSDB 1989).
    Contact allergens Diethylenetriamine is a hardener in epoxy resins of the Bisphenol A type. It has been reported to be a sensitizer when used in an ultrasonic bath for cleaning jewels, in synthetic lubricants, or in carbonless copy paper.
    Safety Profile Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion. Corrosive. A severe skin and eye irritant. High concentration of vapors causes irritation of respiratory tract, nausea, and vomiting. Repeated exposures can cause asthma and sensitization of skin. Combus uble when exposed to heat or flame; can react with oxidizing materials. Mxture with nitromethane is a shock-sensitive explosive. Ignites on contact with cellulose nitrate of high surface area. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
    Potential Exposure PrimaryIrritant. This material is used in textile finishes, fungicides,corrosion inhibitors, adhesives, asphalt additives, as a solvent for sulfur, acid gases, resins, and dyes.
    First aid If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water ormilk. Do not induce vomiting.
    Carcinogenicity DETA has a strong ammonia-like odor, but it does not provide adequate warning of hazardous concentrations.
    The 2003 ACGIH threshold limit valuetime- weighted average (TLV-TWA) for diethylene triamine is 1ppm (4.2mg/m3) with a notation for skin absorption.
    Metabolism Diethylenetriamine is readily absorbed through the gastrointestinal tract and 96% of the administered dose is excreted within 48 h (USEPA 1983a). Roughly equal amounts are excreted in the feces and urine with at least 4 metabolites being detected (but not identified) in the latter. Only a small proportion (<2%) was recovered as expired carbon dioxide. Any residual remaining in the animal was found primarily in kidney, liver, bladder and large intestine.

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    ——  Q&A  ——

    Q1:Do you provide sample?

    A: Yes, we can provide free sample, you only need pay the shipping cost.

    Q2: What is the lead time?

    A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

    Q3: How can I buy? What is the payment method?

    A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer, 

    Q4:What if there are quality issues?

    A:We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.



    Certificates

    Basic Info
    Product Name:

    Diethylenetriamine

    Other Name:

    1,2-Ethanediamine,N1-(2-aminoethyl)-;Diethylenetriamine;1,2-Ethanediamine,N-(2-aminoethyl)-;N1-(2-Aminoethyl)-1,2-ethanediamine;3-Azapentane-1,5-diamine;Bis(β-aminoethyl)amine;2,2′-Diaminodiethylamine;Bis(2-aminoethyl)amine;N,N-Bis(2-aminoethyl)amine;1,4,7-Triazaheptane;1,5-Diamino-3-azapentane;N-(2-Aminoethyl)-1,2-ethanediamine;ChS-P 1;N-(2-Aminoethyl)ethylenediamine;2,2′-Iminobis(ethanamine);2-(2-Aminoethylamino)ethylamine;DEH 20;H 9506;Ancamine DETA;Epon 3223;Epicure T;DETA;NSC 446;NCI 138881;Epicure 3223;JER Cure T;JER-T;Epicure 3290;P 11 (crosslinking agent);P 11;3-Azapentanediyl-1,5-diamine;D 93856;ChS-P 11;FS-B 412;Epikure 3223;N1-(2-Aminoethyl)ethane-1,2-diamine;Amosil 4H;D 1551;Aradur HY 950BR;8076-55-9;26915-78-6;53303-76-7;54018-92-7;59135-90-9;73989-30-7;94700-17-1;98824-35-2;203009-17-0;419553-44-9;859039-00-2;1078151-43-5;1380230-30-7;1801663-13-7

    CAS No.:

    111-40-0

    Molecular Formula:

    C4H13N3

    InChIKeys:

    InChIKey=RPNUMPOLZDHAAY-UHFFFAOYSA-N

    Molecular Weight:

    103.17

    Exact Mass:

    103.17

    BRN:

    605314

    EC Number:

    203-865-4

    UNII:

    03K6SX4V2J

    ICSC Number:

    0620

    NSC Number:

    446

    UN Number:

    2079

    DSSTox ID:

    DTXSID2025050

    Color/Form:

    YELLOW LIQUID|Colorless liquid|Colorless to yellow liquid ... [Note: Hygroscopic (i.e., absorbs moisture from the air)].

    HScode:

    29212900

    Characteristics
    PSA:

    64.1

    XLogP3:

    -1.3

    Appearance:

    Clear Liquid

    Density:

    0.9586 g/cm3 @ Temp: 20 °C

    Melting Point:

    -39 °C

    Boiling Point:

    207 °C @ Press: 760 Torr

    Flash Point:

    90 °C

    Refractive Index:

    n 20/D 1.484(lit.)

    Water Solubility:

    Miscible

    Storage Conditions:

    Store below +30°C.

    Vapor Pressure:

    0.08 mm Hg ( 20 °C)

    Vapor Density:

    3.6 (vs air)

    Toxicity:

    Oral-Rat LD50: 74 mg/kg; Abdominal cavity-mouse LD50: 71  mg/kg

    Flammability characteristics:

    Combustible in case of open flame, high temperature and strong oxidant; burning emits irritating smoke

    Explosive limit:

    1-10%(V)

    Odor:

    AMMONIACAL ODOR

    PH:

    STRONGLY ALKALINE

    Dissociation Constants:

    Kb = 7.07X10-5|pKa = 10.45 @ 20 °C

    Experimental Properties:

    CORROSIVE TO COPPER & ITS ALLOYS|1 MG/L EQIV TO 237 PPM; 1 PPM EQUIV TO 4.22 MG/U M|HYGROSCOPIC; WT/GAL= 7.9 LB @ 20 °C|Heat of vaporization: 487.7 J/g @ 40 kPa|For more Other Experimental Properties (Complete) data for DIETHYLENETRIAMINE (7 total), please visit the HSDB record page.

    Air and Water Reactions:

    Soluble in water.

    Reactive Group:

    Amines, Phosphines, and Pyridines

    Reactivity Profile:

    DIETHYLENETRIAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

    Autoignition Temperature:

    676 °F (USCG, 1999)|398.9 °C|358 °C

    Flammable Limits:

    Flammable Limits In Air: 1%-10% (calculated)|Class IIIB Combustible Liquid: Fl.P. at or above 200°F.

    Physical Dangers:

    The vapour is heavier than air.

    Heat of Vaporization:

    456.4 J/g @ 0.1 MPa

    Hazard Identification

    Classification of the substance or mixture

    Acute toxicity - Category 4, Oral

    Acute toxicity - Category 4, Dermal

    Skin corrosion, Sub-category 1B

    Skin sensitization, Category 1

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H302 Harmful if swallowed

    H312 Harmful in contact with skin

    H314 Causes severe skin burns and eye damage

    H317 May cause an allergic skin reaction

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P270 Do not eat, drink or smoke when using this product.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P260 Do not breathe dust/fume/gas/mist/vapours/spray.

    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

    P272 Contaminated work clothing should not be allowed out of the workplace.

    Response

    P301+P317 IF SWALLOWED: Get medical help.

    P330 Rinse mouth.

    P302+P352 IF ON SKIN: Wash with plenty of water/...

    P317 Get medical help.

    P321 Specific treatment (see ... on this label).

    P362+P364 Take off contaminated clothing and wash it before reuse.

    P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

    P363 Wash contaminated clothing before reuse.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P316 Get emergency medical help immediately.

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P333+P317 If skin irritation or rash occurs: Get medical help.

    Storage

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    NO open flames. Above 97°C use a closed system, ventilation and explosion-proof electrical equipment. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Separated from strong oxidants, acids, organic nitro compounds and food and feedstuffs. Keep in a well-ventilated room.Protect containers against physical damage. Store in cool, dark, well-ventilated place away from sources of ignition.

  • Seller Information
    Business Type:

    Trader

    Main Products:

    pharmaceutical intermediates,peptides,electronic chemicals

    Location:

    Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

    Payment Terms:

    100% TT in advance

    Average lead Time:

    10

    Total Annual Revenue:

    $10 million-$25 million

    Total Employees:

    51-100

    Year of Establishment:

    2024

    A reliable supplier is like insurance.

    We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals,food additives, and other fine chemical products.
    Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

    Website: orientchem.cc
    Email: scarlett@orientchem.cc
    WhatsApp: +86 17753254221

  • Inquiry History
    22 Inquiries
    Country Product Purchase Quantity Date Posted
    Turkey

    DIETHYLENE TRIAMINE (DETA) 99%

    1 20' Fcl Dec 25, 2023
    Turkey

    diethylenetriamine (DETA) %99

    1 20' Fcl Dec 25, 2023
    Russia

    Diethylenetriamine

    1 MT Jun 5, 2026
    Saudi Arabia

    DETA

    1 20' Fcl Nov 12, 2025
    India

    DIETHYLENETRIAMINE

    1.00 20' Fcl Mar 31, 2025
    India

    Diethylenetriamine

    1.00 20' Fcl Feb 27, 2024
    India

    Diethylenetriamine (DETA)

    50 MT Apr 28, 2026
    India

    Diethylenetriamine (DETA)

    18.00 MT Mar 10, 2026
    Egypt

    DETA

    1 40' Fcl Dec 10, 2025
    India

    Diethylenetriamine (DETA)

    1.00 20' Fcl Jun 4, 2025
    India

    Diethylenetriamine (DETA)

    5.00 TON Mar 4, 2025
    India

    Diethylenetriamine

    1.00 20' Fcl Aug 19, 2024
    India

    Diethylenetriamine

    12.00 20' Fcl Mar 27, 2024
    South Korea

    Diethylenetriamine

    1.00 20' Fcl Dec 12, 2023
    Micronesia

    Diethylenetriamine

    15  Jan 16, 2024
    Egypt

    Diethylenetriamine

    1.00 20' Fcl Dec 10, 2025
    South Africa

    Diethylenetriamine

    1.00 20' Fcl Nov 19, 2025
    India

    Diethylenetriamine

    1.00 20' Fcl Nov 14, 2025
    India

    Diethylenetriamine

    1.00 20' Fcl Feb 9, 2025
    Vietnam

    Diethylenetriamine

    1 MT Jun 17, 2024
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