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Acetylene

Acetylene structure

Acetylene 

structure

Description

Acetylene (100% purity) is odorless but commercial purity has a distinctive garlic-like odor. It is very soluble in alcohol and almost miscible with ethane. Acetylene is a flammable gas and kept under pressure in gas cylinders. Under certain conditions, acetylene can react with copper, silver, and mercury to form acetylides, compounds that can act as ignition sources. Brasses contain a form acetylides, compounds that can act as ignition sources. Brasses containing less than 65% copper in the al


Acetylene (systematic name: ethyne) is the chemical compound with the formula C2H2. It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure form and thus is usually handled as a solution. Pure acetylene is odorless, but commercial grades usually have a marked odor due to impurities.

Acetylene Basic Attributes

26.04

26.04

200-816-9

2901292000

Characteristics

0

0.37

Acetylene appears as a colorless gas with a faint garlic-like odor. Easily ignited and burns with a sooty flame. Gas is lighter than air. Flame may flash back to the source of a leak very easily. Under prolonged exposure to fire or heat the containers may rupture violently and rocket.

0.6208 g/cm3 @ Temp: -82 °C

-80.8 °C

-84.0 °C @ Press: 760 Torr

-18°C

1.316

H2O: 0.106 g/100 mL

Acetylene should be kept stored in a cool, dry place in a tightly sealed container, and should only be used in a well-ventilated area. Cylinders should be separated from oxygen and other oxidizers by a minimum of 20 ft or by a barrier of non-combustible material at least 5 ft high, having a fi re resistance rating of at least 30 min. Storage in excess of 2500 cu ft is prohibited in buildings with other occupancies. Cylinders should be stored upright with a valve protection cap in place and fi r

3.04 X 104 mmHg (~40 atmospheres) at 16.8 °C

0.91

Inhalation-Mammal LCL0: 50000 PPM/ 5 minutes

Open flame, flammable when heated; burning produces irritating smoke

Explosive limits , vol% in air: 2.5-100

Not unpleasant odor unless impure (due to phosphine)

Safety Information

2.1

UN 1001

5-6-12

9-16-33

AO9600000

F+

The warehouse is ventilated, low temperature and dry; lightly loaded and unloaded; stored separately from oxygen, air and chlorine gas cylinders

Open flame mixed with air, explosive when heated; explosive when exposed to copper, mercury, silver, chlorine, fluorine

Acetylene at 170 deg C is somewhat stabilized by presence of acetic acid

P210, P377, P381, P403

H220

UN 1001

Toxicity

practically nontoxic

Acetylene Use and Manufacturing

Illuminant, oxyacetylene welding, cutting, and soldering metals, signalling; pptg metals, particularly Cu; manufacture of acetaldehyde, acetic acid; fuel for motor boats.

Computed Properties

Molecular Weight:26.04
XLogP3:0.4
Exact Mass:26.0156500638
Monoisotopic Mass:26.0156500638
Heavy Atom Count:2
Complexity:8
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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