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4-Bromoanisole104-92-7

Name: 4-Bromoanisole104-92-7
Brand: OORENT
SKU: pr2606181141
Price: 33 USD
Availability: InStock

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Unit Price:

$33-34/MT FOB

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CAS No.:

104-92-7

Grade:

Pharmaceutical Grade

Content:

99.5%

Port:

上海

Brand:

OORENT

Packaging:

Vial/Bottle/Bag/Carton

Sample Available:

Yes

Price valid (until):

2027-06-14

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Qingdao Orient Chemical Co.,LTD

Company Type:

Trader

Location:

China

Payment Terms:

100% TT in advance

Average Lead Time:

10 days

Qualification:

Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

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Product Details
Seller Information
Inquiry History

Description

Product Detail

4-Bromoanisole Basic information

Product Name:	4-Bromoanisole
Synonyms:	p-methoxyphenylbromide;2-Bromoanisole,98%;4-Bromomethoxybenzene;4-Methoxy-1-bromobenzene;4-Methoxybromobenzene;4-Methoxyphenyl bromide;4-methoxyphenylbromide;Anisole, p-bromo-
CAS:	104-92-7
MF:	C7H7BrO
MW:	187.03
EINECS:	203-252-1
Product Categories:	Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds;Aromatic Ethers;AnisoleSeries;Anisole;alkyl bromide
Mol File:	104-92-7.mol

4-Bromoanisole Chemical Properties

Melting point	9-10 °C (lit.)
Boiling point	223 °C (lit.)
density	1.494 g/mL at 25 °C (lit.)
refractive index	n20/D 1.564(lit.)
Fp	202 °F
storage temp.	Store below +30°C.
solubility	Chloroform (Sparingly), Ethyl Acetate (Slightly)
form	Liquid
color	Clear colorless to slightly yellow
Water Solubility	immiscible
Merck	14,1428
BRN	1237590
Henry's Law Constant	1.1×10^-2 mol/(m³Pa) at 25℃, Pfeifer et al. (2001)
Dielectric constant	7.4000000000000004
Stability:	Stable. Combustible. Incompatible with strong oxidizing agents.
InChI	1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
InChIKey	QJPJQTDYNZXKQF-UHFFFAOYSA-N
SMILES	COc1ccc(Br)cc1
CAS DataBase Reference	104-92-7(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-bromo-4-methoxy-(104-92-7)
EPA Substance Registry System	Benzene, 1-bromo-4-methoxy- (104-92-7)

Safety Information

Hazard Codes	Xn
Safety Statements	23-24/25
WGK Germany	2
RTECS	BZ8501000
F	8
TSCA	TSCA listed
HS Code	29093038
Storage Class	10 - Combustible liquids
Hazard Classifications	Acute Tox. 4 Oral Skin Irrit. 2
Toxicity	LD50 orl-mus: 2200 mg/kg GISAAA 44(12),19,79

MSDS Information

Provider	Language
4-Bromoanisole	English
ACROS	English
SigmaAldrich	English
ALFA	English

4-Bromoanisole Usage And Synthesis

Chemical Properties	4-Bromoanisole is a colourless to pale yellow oily liquid with a pleasant smell similar to that of anise seed. Insoluble in water, soluble in ethanol, ether and chloroform. It is one of three isomers of bromoanisole, the others being 3-bromoanisole and 2-bromoanisole. It is the precursor to many 4-anisyl derivatives.
Uses	4-Bromoanisole finds application as an intermediate in synthetic chemistry. It is used in the preparation of aryl 1,3-diketones and ethyl 4-methoxycinnamate. It is a used as a brominating reagent. Further, it is used in Suzuki coupling reaction with phenylboronic acid as well as in Heck reaction.
Preparation	4-Bromoanisole is obtained by reacting p-bromophenol with dimethyl sulfate.
Definition	ChEBI: 4-bromoanisole is a monomethoxybenzene carrying a bromo substituent at position 4. It is a monomethoxybenzene and an organobromine compound.
Biological Functions	4-Bromoanisole is compound sometimes used in RNA extraction which serves to further eliminate DNA contamination. It interacts with genomic DNA(gDNA) and through a separation phase, it will be located in the organic layer instead of the aqueous layer (upper layer) containing the RNA extract.
Synthesis Reference(s)	Tetrahedron Letters, 35, p. 7429, 1994 DOI: 10.1016/0040-4039(94)85333-9 Synthesis, p. 868, 1986 DOI: 10.1055/s-1986-31813
General Description	4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.
Safety Profile	Moderately toxic by ingestion andintraperitoneal routes. When heated to decomposition itemits toxic vapors of Br^-.
Purification Methods	Crystallise the anisole by repeated partial freezing, then distil it under reduced pressure. [Beilstein 6 III 741, 6 IV 1044.]

4-Bromoanisole Preparation Products And Raw materials

ECHEMI Editorial Reference

colourless liquidChEBI: A monomethoxybenzene carrying a bromo substituent at position 4.
4-bromoanisole is a monomethoxybenzene carrying a bromo substituent at position 4. It is a monomethoxybenzene and an organobromine compound.

Basic Info

Product Name:

4-Bromoanisole

Other Name:

Benzene,1-bromo-4-methoxy-;Anisole,p-bromo-;1-Bromo-4-methoxybenzene;p-Bromoanisole;4-Bromoanisole;p-Bromanisole;p-Bromophenyl methyl ether;4-Methoxy-1-bromobenzene;p-Methoxyphenyl bromide;p-Methoxybromobenzene;4-Methoxybromobenzene;4-Anisyl bromide;4-Methoxyphenyl bromide;p-Anisyl bromide;4-Bromomethoxybenzene;p-Bromomethoxybenzene;4-Bromo-1-methoxybenzene;1-Methoxy-4-bromobenzene;NSC 8042;4-Bromoanisol

CAS No.:

104-92-7

Molecular Formula:

C7H7BrO

InChIKeys:

InChIKey=QJPJQTDYNZXKQF-UHFFFAOYSA-N

Molecular Weight:

187.036

Exact Mass:

187.03

EC Number:

203-252-1

UNII:

U430F901J9

NSC Number:

8042

DSSTox ID:

DTXSID2059308

HScode:

29093038

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

9.2

XLogP3:

3.16

Density:

1.494 g/mL at 25 °C(lit.)

Melting Point:

13.5 °C

Boiling Point:

215 °C

Flash Point:

202 °F

Refractive Index:

n 20/D 1.564(lit.)

Water Solubility:

immiscible

Vapor Pressure:

0.20 mmHg

Toxicity:

LD50 orl-mus: 2200 mg/kg GISAAA 44(12),19,79

See More 4-Bromoanisole Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Skin irritation, Category 2

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Warning
Hazard statement(s)	H302 Harmful if swallowed H315 Causes skin irritation
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
Response	P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P317 If skin irritation occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse.
Storage	none
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

See More 4-Bromoanisole Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10 days

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
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Website: orientchem.cc
Email: scarlett@orientchem.cc
WhatsApp: +86 17753254221

Inquiry History

3 Inquiries

Country	Product	Purchase Quantity	Date Posted
India	4-Bromoanisole (1-Bromo-4-methoxybenzene)	250 KG	Jan 21, 2026
India	Para Bromo Anisole	1.00 MT	Oct 23, 2023
Brazil	4-Bromoanisole	30 MT	Nov 15, 2024

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4-Bromoanisole104-92-7

Product Details

Seller Information

Inquiry History

Classification of the substance or mixture

GHS label elements, including precautionary statements

Other hazards which do not result in classification

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

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