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619-23-8 3-Nitrobenzyl chloride china supplier hly57

COA

Unit Price:

$1/MT FOB

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CAS No.:

619-23-8

Grade:

industrial Grade

Content:

98%

Port:

qingdao

Brand:

HLY

Packaging:

50kg UNapproved fiber drum

Price valid (until):

2027-02-28

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Suqian City Hengliyuan Import and Export Trade Co., LTD

Company Type:

Trader

Location:

China

Qualification:

Main Products:

Acrylonitrile,Sodium biselenite methylamine solution,Methylamine [anhydrous],Zinc dust,Hydrogen peroxide solution [content >8%],Triisopropyl borate

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Product Description
Seller Information

Description

Company Profile ----------
Suqian City Hengliyuan Import and Export Trade Co., LTD is a trading company. The company has introduced advanced scientific and technological achievements from home and abroad, and has superior products from well-known manufacturers at home and abroad. The basic functions are:
1. Domestic trade of various chemical raw materials;
2. Providing price information services and chemical raw material procurement for industrial enterprises;
3. Cooperating with Chinese state-owned enterprise factories, the price and quality are very advantageous.
At present, the company is relying on the combination of industry and trade and global procurement to steadily improve the company's value-added ability and compound competitiveness. We have always been committed to producing high-quality and low-cost goods, so we have been sincerely recognized by many customers. Our goal is to produce the best products and satisfy every customer with professional services and attitudes. We look forward to cooperating with you and establishing a win-win relationship with you. Please rest assured that we will definitely satisfy you.

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----------packaging and delivery ----------

----------Our Advantages---------
High quality with competitive price
1) Standard:BP/USP/EP/Enterprise standard
2) All Purity≥99%
3) We can provide high quality products with factory price
2. Fast delivery
1) Fast shipment.Various transportation methods for your choice.
2) We have our own agent/remailer/distributor who can help us ship our products very fast , and we have stock in the ir for transferring.
3. Good communication and credit
1) Fast response to customer within 5 hours
2) Good business credit in Europe, US, Japan, Korea, Af r ica and so on.

Items	Specifications

3-Nitrobenzyl ChlorideCAS 619-23-8 Full Export Specification

1. Basic Chemical Identification

IUPAC Name: 1-(chloromethyl)-3-nitrobenzene
Aliases: 3-Nitrobenzyl chloride, m-Nitrobenzyl chloride, α-Chloro-3-nitrotoluene,
CAS No.: 619-23-8
EINECS: 210-584-3
MDL No.: MFCD00007231
Molecular Formula: $\boldsymbol{C_7H_6ClNO_2}$
Molecular Weight: 171.58
SMILES: ClCc1cccc(N+[O-])c1
HS Code: 29049085
UN Number: UN 3261
IMDG Hazard Class: Class 8 Corrosive Solid + Subsidiary 6.1 Toxic, Packing Group II
Signal Word: Danger

2. Physical & Chemical Properties

Appearance: Pale yellow crystalline powder / flaky crystal, pungent irritant halogen-nitro odor; light sensitive, darkens under sunlight
Melting Point: 44–47 ℃
Boiling Point: Decomposes above 250 ℃ (no stable boiling point, releases HCl & nitro fumes)
Density (solid): 1.33 g/cm³
Flash Point: >110 ℃
Solubility: Insoluble in cold water, slowly hydrolyzes to 3-nitrobenzyl alcohol + HCl; freely soluble in ethanol, acetone, toluene, dichloromethane, ethyl acetate, DMF
Stability:
- Hydrolysis sensitive, absorbs atmospheric moisture to release corrosive hydrogen chloride
- Light-sensitive, needs light-proof sealed nitrogen storage
- Incompatible with strong alkalis, amines, oxidants, active metal powders
Core Hazards
- Strong corrosive solid; dust & hydrolysis mist cause irreversible burns to skin, eyes, respiratory tract
- Cumulative toxic via skin absorption, dust inhalation and ingestion; induces methemoglobinemia, liver/kidney damage
- Combustible solid; dust-air mixture forms explosive mixture under high temperature
- High aquatic toxicity with bioaccumulation risk

3. Standard COA Technical Specifications

Industrial Pharmaceutical Grade ≥98.0% (Main Bulk Export Grade)

Test Item	Standard Specification
Purity (GC Area%)	≥98.0 wt%
o/p-Nitrobenzyl chloride isomer total	≤0.80%
Moisture Content	≤0.10%
Melting range	44.0–47.0 ℃
Free HCl acidity	≤0.05%
Ethanol insoluble matter	≤0.02%
Melt color	Pale yellow clear liquid
Heavy Metals (Pb)	≤10 ppm

High-Purity Reagent Grade ≥99.0%

Ultra-low mixed isomer & free acid impurities, for chiral drug synthesis, lab derivatization & chromatographic reference standards

4. Main Industrial Applications

1. Pharmaceutical API Intermediate (Largest Consumption)

High-active benzyl alkylating reagent for β-lactam antibiotics, anti-viral, anti-tumor and cardiovascular drugs; used to introduce m-nitrobenzyl protecting group for carboxyl/hydroxyl in peptide & heterocyclic drug synthesis

2. Chromatography Derivatization Reagent

UV-label derivatization agent for HPLC/GC analysis of carboxylic acids, amino acids, alcohols; the nitro group provides strong UV absorption signal for trace detection

3. Agrochemical Intermediate

Precursor for selective herbicides, bactericides and plant growth regulators; synthesize nitrobenzyl amine salt pesticide active ingredients

4. Dye & Fluorescent Brightener Intermediate

Alkylation feedstock for cationic textile dyes and fluorescent whitening agents; improves dye binding fastness on polyester fiber

5. Laboratory Synthetic Reagent

Standard m-nitrobenzyl halide substrate for nucleophilic substitution, protecting-group chemistry, esterification and coordination chemistry research

5. Export Packaging & Storage Transportation

Standard Packing Options

Industrial bulk: 25kg fiber drum with double PE light-proof moisture-proof inner liner, fully airtight sealed lid
Ton jumbo bag: 1000kg waterproof light-shield woven bag with thick PE inner liner for factory continuous feeding
Lab small packing: 100g / 500g amber sealed plastic bottle with vacuum nitrogen protection

All pallets fixed with anti-slip straps, fully wrapped waterproof light-shield stretch film; transit temperature controlled ≤25 ℃, strictly avoid direct sunlight and high humidity

Storage Mandatory Rules

Warehouse: Cool, dry, dark, ventilated Class8+6.1 dual-hazard chemical warehouse, humidity ＜60%
Fully nitrogen-sealed to block moisture ingress and prevent hydrolysis / oxidative discoloration
Strict segregate from alkalis, amines, oxidants, metal powders, food raw materials and edible goods
Equipped with acid mist / toxic dust alarm and soda ash neutralization emergency pool

Ocean Transport Rules

UN3261 Class8 Corrosive + 6.1 Toxic Solid PG II marine pollutant; mixed loading with food, drinking water and alkaline cargo completely forbidden; prevent rain soaking and package rupture; full set of dangerous goods export documents required for global customs clearance

6. GHS Full Hazard Statements & Mandatory PPE

Hazard Statements

H302: Harmful if swallowed
H311: Toxic in contact with skin (rapid skin absorption risk)
H314: Causes severe irreversible skin and eye burns
H331: Toxic if inhaled (crystal dust severe mucosal irritation)
H373: May cause liver & blood system organ damage via prolonged repeated exposure
H411: Toxic to aquatic life with long-lasting ecological hazards

Mandatory PPE

Dust half-face respirator with P2 high-efficiency particulate + acid vapor dual filter cartridge; full-face positive-pressure SCBA for large-scale feeding & melting operations
Double protection: fully sealed anti-corrosion chemical safety goggles + full anti-dust splash face shield
Double-layer thick nitrile/fluororubber acid-resistant impermeable gloves
Dust-proof impermeable full-body anti-toxic protective overalls + heavy chemical resistant rubber boots
Local negative-pressure closed exhaust fume hood for weighing, feeding and melting operations

Spill & First Aid Emergency Treatment

Spill disposal: Evacuate irrelevant personnel, cover crystalline solid with dry inert sand to suppress dust; collect residues into airtight anti-corrosion steel hazardous barrel for professional incineration; neutralize residual traces with dilute soda ash solution; prohibit direct discharge to sewer or water body
Skin contact: Immediately strip all contaminated clothing, flush skin with massive soap running water continuously ≥30 minutes; hospital observation for corrosive burn & methemoglobinemia risk
Eye contact: Irrigate eyes with steady clean running water non-stop for minimum 30 minutes, urgent ophthalmic rescue mandatory
Inhalation: Move victim to fresh air instantly; supply high-concentration oxygen if throat pain, dizziness, nausea or dyspnea occurs
Ingestion: Do NOT induce vomiting; drink large volume clean water/milk to dilute corrosive toxin, transport to toxic emergency center with SDS document

7. Foreign Trade Selling Advantages

Two grades available: industrial pharma/derivatization bulk grade & high-purity lab reagent grade, strictly controlled low ortho/para nitrobenzyl chloride impurities to guarantee high yield in protection-group synthesis
Light-proof double-layer moisture-proof fiber drum / ton bag packaging, no hydrolysis discoloration or agglomeration during long-distance ocean shipping
Complete Class8+6.1 dual-hazard dangerous goods export document set (COA, English SDS, UN packaging certificate, IMDG maritime declaration, certificate of origin, mixed isomer impurity inspection report)
Flexible supply: small trial fiber drums, ton jumbo bags and full FCL container bulk shipments acceptable
Stable alkylation & UV derivatization performance, widely supplied to global pharmaceutical, chromatographic reagent and agrochemical manufacturers

8. Full Set Export Supporting Documents

Batch Certificate of Analysis (COA)
English SDS Safety Data Sheet (halogen nitro aromatic corrosive solid special version)
Dangerous Goods Packaging Qualification Certificate (UN3261)
IMDG Maritime Dangerous Goods Declaration File
Certificate of Origin
Mixed isomer & heavy metal impurity compliance test report

Certificates

Basic Info

Product Name:

3-Nitrobenzyl chloride

Other Name:

Benzene,1-(chloromethyl)-3-nitro-;Toluene,α-chloro-m-nitro-;1-(Chloromethyl)-3-nitrobenzene;m-Nitrobenzyl chloride;α-Chloro-m-nitrotoluene;3-Nitrobenzyl chloride;m-Nitrobenzyl chloride;NSC 9802

CAS No.:

619-23-8

Molecular Formula:

C7H6ClNO2

InChIKeys:

InChIKey=APGGSERFJKEWFG-UHFFFAOYSA-N

Molecular Weight:

171.58

Exact Mass:

171.58

BRN:

742794

EC Number:

210-586-1

UNII:

OJL133898O

NSC Number:

9802

UN Number:

3261

DSSTox ID:

DTXSID4025743

Color/Form:

PALE YELLOW NEEDLES FROM PETROLEUM ETHER

HScode:

2904909090

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

45.8

XLogP3:

2.85680

Appearance:

Light yellow to light brown Crystalline Solid

Density:

1503

Melting Point:

45-47 °C

Boiling Point:

175-183 °C @ Press: 30-35 Torr

Flash Point:

>230 °F

Refractive Index:

1.5577 (62ºC)

Water Solubility:

H2O: <0.1 g/100 mL at 22 ºC;INSOL IN WATER; SOL IN ALCOHOL, ETHER, BENZENE, ACETIC ACID; VERY SOL IN ETHYL ACETATE, ACETONE

Toxicity:

Reference value: oral-rat LD50: 1809 mg/kg; inhalation-rat LCL0: 280 mg/m3/4 hours

Flammability characteristics:

Combustible in case of fire; burning produces toxic nitrogen oxide fumes

Air and Water Reactions:

Insoluble in water.

Reactive Group:

Halogenated Organic Compounds

Reactivity Profile:

A halogenated aromatic nitro compound. Aromatic nitro compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

See More 3-Nitrobenzyl chloride Properties 

Hazard Identification

Classification of the substance or mixture

Skin corrosion, Sub-category 1B

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H314 Causes severe skin burns and eye damage
Prevention	P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
Response	P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P316 Get emergency medical help immediately. P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage	P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

See More 3-Nitrobenzyl chloride Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
Acrylonitrile,Sodium biselenite methylamine solution,Methylamine [anhydrous],Zinc dust,Hydrogen peroxide solution [content >8%],Triisopropyl borate

Location:
Shop No.15, 1st Floor, Building 12, Hengda Huafu, Sucheng District, Suqian City

Payment Terms:
TT against B/L draft before shipment,100% TT in advance

Average lead Time:
30

Total Annual Revenue:
Less than $1 million

Total Employees:
5-10

Year of Establishment:
2022
Company Overview

Suqian Hengliyuan Import and Export Corporation, Ltd. is a leading enterprise specializing in the international trade of chemical products. Established in Suqian, Jiangsu Province, China, our company has built a strong reputation for excellence and reliability in the chemical industry.

Our Mission

Our mission is to facilitate global trade by providing high-quality chemical products and exceptional service to our clients. We aim to be a bridge between manufacturers and end-users, ensuring the safe and efficient transfer of chemicals across borders.

Products and Services

We offer a comprehensive range of chemical products, including but not limited to:

Industrial Chemicals: Raw materials for various industries such as pharmaceuticals, agriculture, and manufacturing.

Specialty Chemicals: High-performance chemicals used in specific applications, including water treatment, coatings, and adhesives.

Bulk Chemicals: Large-volume chemicals for industrial processes and manufacturing needs.

Quality Assurance

At Suqian Hengliyuan Import and Export Corporation, Ltd., quality is our top priority. We adhere to stringent quality control measures and international standards to ensure that our products meet the highest levels of purity and performance. Our dedicated quality assurance team conducts rigorous inspections and testing to guarantee the integrity and safety of all our chemical products.

Global Network

Leveraging our extensive network of suppliers and partners, we are able to source and deliver a wide array of chemical products to clients worldwide. Our strategic partnerships and logistical expertise enable us to offer competitive pricing, timely delivery, and customized solutions to meet the diverse needs of our clients.

Commitment to Sustainability

We are committed to sustainable business practices and environmental stewardship. Our operations are designed to minimize environmental impact, and we continuously seek ways to improve our processes and reduce our carbon footprint. We work closely with our suppliers and customers to promote the responsible use and disposal of chemicals.

Customer Focus

Our clients are at the heart of everything we do. We pride ourselves on providing personalized service and building long-term relationships based on trust and mutual benefit. Our experienced team of professionals is dedicated to understanding our clients' needs and delivering solutions that exceed their expectations.
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