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Bis(tri-tert-butylphosphine)palladium(0)

Bis(tri-tert-butylphosphine)palladium(0) structure

CAS No:
53199-31-8
Formula:
C24H54P2Pd
Chemical Name:
Bis(tri-tert-butylphosphine)palladium(0)
Synonyms:
BIS(TRI-T-BUTYLPHOSPHINE)PALLADIUM(0);BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM;BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM (0);Bis(tri-t-butylphosphine)palladium,;Bis(tri-tert-butylphosphin)palladium(0);Bis(tri-t-butylphosphine)palladium(0),98%;Bis(tri-t-butyl)phosphino Pd0;Bis(tri-tert-butylphosphine)palladium(0), Pd 20.9%
Categories:
Organic Chemistry > Organometallic Compounds

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Description

Off white crystalline solid

Bis(tri-tert-butylphosphine)palladium(0) Basic Attributes

Molecular Weight：

511.05

Exact Mass：

510.273560

EC Number：

1806241-263-5

DSSTox ID：

DTXSID80370359

HScode：

28439000

Characteristics

PSA：

XLogP3：

9.72760

Appearance：

Off-white to orange-brown Crystals

Melting Point：

>300 °C

Boiling Point：

229.4ºC at 760mmHg

Flash Point：

94.6ºC

Water Solubility：

H2O: insoluble

Storage Conditions：

Freezer

Safety Information

Transport codes：

NONH for all modes of transport

wgk germany：

hazard class code：

36/37/38

safety instructions：

24/25

Marks：

Precautionary statement(s)：

P210, P240, P241, P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P370+P378, P403+P233, P405, P501

Hazard Statements：

H228

GHS Classification：

|Warning|H228 (12.5%): Flammable solid [Danger Flammable solids]|P210, P240, P241, P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P370+P378, P403+P233, P405, and P501|Aggregated GHS information provided by 8 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Bis(tri-tert-butylphosphine)palladium(0) Use and Manufacturing

Catalyst for Suzuki coupling on a multisubstituted sp 3 -carbon (eq. 1) Catalyst for Stille coupling reaction of aryl chlorides 2 (eq. 2) Catalyst for Negishi coupling reaction 3 (eq. 3) Catalyst for Heck coupling to form tetrasubstituted olefins 4 (eq. 4) Catalyst for Buchwald-Hartwig amination of aryl halide 5 (eq. 5) Catalyst for carbonylation of aryl halides with carbamoylsilanes 6 (eq. 6) t -Bu 3 P) 2 catalyst.

Computed Properties

Molecular Weight:511.1
Rotatable Bond Count:6
Exact Mass:510.27356
Monoisotopic Mass:510.27356
Heavy Atom Count:27
Complexity:128
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

Material

Toluene

Tetrahydrofuran

Ethanol

Acetonitrile

Phosphorus trichloride

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Guide of Bis(tri-tert-butylphosphine)palladium(0)

Description
Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
Computed Properties
Material
Recommended Suppliers
Latest News
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Bis(tri-tert-butylphosphine)palladium(0)

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