1-(BROMOMETHYL)-4-(METHYLSULFONYL)BENZENE
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1-(BROMOMETHYL)-4-(METHYLSULFONYL)BENZENE
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CAS No:
53606-06-7
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Formula:
C8H9BrO2S
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Chemical Name:
1-(BROMOMETHYL)-4-(METHYLSULFONYL)BENZENE
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Synonyms:
1-(Bromomethyl)-4-(methylsulfonyl)benzene [tech.];4-Methylsulphonylbenzyl broMide, tech. 2.5GR;4-(Methanesulfonyl)benzyl bromide;1-(broMoMethyl)-4-Methanesulfonylbenzene;1-(Bromomethyl)-4-(methylsulphonyl)benzene, 4-(Bromomethyl)phenyl methyl sulphone;4-(Methanesulfonyl)benzyl bromide1-(Bromomethyl)-4-(methylsulfonyl)benzene;1-(Chloromethyl)-4-(methylsulfonyl)benzene;1-(BROMOMETHYL)-4-(METHYLSULFONYL)BENZENE
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CAS No:
Safety Information
III
8
UN3261
3
36/37/38-36-22-34
37/39-26-45-36/37/39
Xi,Xn
P234, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P390, P404, P405, P501
H290
|Danger|H290 (20%): May be corrosive to metals [Warning Corrosive to Metals]|P234, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P390, P404, P405, and P501|Aggregated GHS information provided by 5 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
1-(BROMOMETHYL)-4-(METHYLSULFONYL)BENZENE Use and Manufacturing
To a stirring solution of (4-(methylsulfonyl)phenyl)methanol (2.00 g, 10.7 mmol) and triethylamine (2.24 mL, 1 6. 1 mmol) in acetone (25 mL) at 0 °C was added methanesulfonyl chloride (1.00 mL, 12.9 mmol) drop-wise. The resulting mixture was stirred at this temperature for 30 mins. The reaction mixture was filtered, and to the filtrate was added lithium bromide (4.66 g, 53.7 mmol) at 0 Example 211; l-(bromomethyl)-4-(methylsulfonyl)benzene; A stirred mixture of l-methanesulfonyl-4-methyl-benzene (1.30 g, 7.5 mmol), n- bromosuccinimide (1.30 g, 7.10 mmol), and benzoyl peroxide (70 mg, 0.30 mmol) in CCl
Computed Properties
Molecular Weight:249.13
XLogP3:1.7
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:247.95066
Monoisotopic Mass:247.95066
Topological Polar Surface Area:42.5
Heavy Atom Count:12
Complexity:222
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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1-(BROMOMETHYL)-4-(METHYLSULFONYL)BENZENE
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