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Antimony pentafluoride

Antimony pentafluoride structure

Antimony pentafluoride 

structure
  • CAS No:

    7783-70-2

  • Formula:

    F5Sb

  • Chemical Name:

    Antimony pentafluoride

  • Synonyms:

    Antimony fluoride (SbF5);Antimony pentafluoride;Antimony(V) fluoride;Pentafluoroantimony

  • Categories:

    Inorganic Chemistry  >  Inorganic Salts

Description

colourless oily liquid Antimony pentafluoride is a noncombustible, oily, colorless liquid with a pungent odor.


Antimony pentafluoride appears as a colorless, oily liquid. Fumes irritate the eyes and mucous membranes. Toxic. Corrosive to metals and tissue. Extremely dangerous to tissue; its burns may be followed by gangrene. Only shipped in cylinders. Under prolonged exposure to heat cylinders may violently rupture and rocket. Used to make other chemicals as well as a catalyst in the manufacture of other chemicals.|OILY COLOURLESS HYGROSCOPIC LIQUID WITH PUNGENT ODOUR.


Antimony pentafluoride appears as a colorless, oily liquid. Fumes irritate the eyes and mucous membranes. Toxic. Corrosive to metals and tissue. Extremely dangerous to tissue; its burns may be followed by gangrene. Only shipped in cylinders. Under prolonged exposure to heat cylinders may violently rupture and rocket. Used to make other chemicals as well as a catalyst in the manufacture of other chemicals.

Antimony pentafluoride Basic Attributes

216.75

215.895844

232-021-8

0220

1732

Hygroscopic, moderately viscous liquid|Hygroscopic, viscous liquid|Oily, colorless liquid

28261990

Characteristics

0 Ų

2.10100

White to off-white Shiny Flakes or Powder

3.097 g/cm3 @ Temp: 25.8 °C

8.3 °C

141 °C

149.5°C

liquid sulfur dioxide: slightly soluble (lit.)

Store below +30°C.

10 mm Hg ( 25 °C)

2.2 (vs air)

Inhalation-Mouse LC50: 270 mg/m3

Decomposes with water to produce corrosive hydrogen fluoride gas, producing hydrofluoric acid; flammable in case of flammable materials; ventilated at low temperature and dry in the warehouse; dry powder, foam, sand, carbon dioxide, and mist water stored separately from food raw materials are flammable; combustion produces toxic fluoride and antimony Chemical smog

Sharp odor

Very reactive|A good oxidizing and fluorinating agent.|Slowly hydrolyzed in sodium hydroxide solution forming antimony hydroxide ion (Sb(OH)6-). Forms solids with sulfur chloride, carbon disulfide, benzene, toluene, petroleum ether, ether, alcohol, acetone, ethyl acetate.|Antimony pentafluoride ... readily replaces all chlorines with fluorine in an organic compound, and fluorinates double bonds and aromatic rings.|For more Other Experimental Properties (Complete) data for Antimony pentafluoride (7 total), please visit the HSDB record page.

Fumes in air to form small amounts of hydrogen fluoride (reacts with moisture in air). May React with water to give hydrofluoric acid (HF) [Merck 11th ed. 1989]. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Fluoride gas will be created in 1.2 minutes. Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009.

Acids, Strong Non-oxidizing

Water-Reactive

ANTIMONY PENTAFLUORIDE is strongly acidic. Reacts vigorously with bases. When heated to decomposition, it emits highly toxic fumes of fluorides and metallic antimony. Reacts with ammonia to form a diammoniate.

Slowly corrodes glass, copper, lead|When moisture is present, causes severe corrosion of metals (except steel) and glass.

79 Btu/lb = 44 cal/g = 1.8X10+5 J/kg (est)

Safety Information

II

8

UN 2923 8/PG 2

3

23/24/25-34-51/53-20/22

61-45-36/37/39-28-27-26-22

CC5800000

T,O,C,N,Xn

Treasury is ventilated, low temperature and dry; stored separately from organic matter

Corrosive/Oxidising agent

Reacts violently with phosphate

Stable under recommended storage conditions.

P261-P301 + P312 + P330

H302 + H332-H411

SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.|SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.|Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material; Contaminated packaging: Dispose of as unused product.

Incompatible materials: Strong oxidizing agents, strong bases, water, highly toxic fumes, glass.|Violent reaction with phosphates.|Reacts violently with water. Also forms a solid dihydrate, which reacts violently with more water to form a clear solution.|Hydrofluoric acid is formed from reaction with water and moisture, which may react with metals forming hydrogen gas.|For more Hazardous Reactivities and Incompatibilities (Complete) data for Antimony pentafluoride (8 total), please visit the HSDB record page.

Reacts violently with water, to form poisonous hydrogen fluoride fumes. If confined and wet can cause explosion. May cause fire in contact with combustible material. Hazardous polymerization may not occur. (EPA, 1998)|Not combustible but enhances combustion of other substances. Gives off irritating or toxic fumes (or gases) in a fire.|Corrosives, Reactive - 1st degree

|Danger|H302 (42.86%): Harmful if swallowed [Warning Acute toxicity, oral]|P260, P261, P264, P270, P271, P273, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P330, P363, P391, P405, and P501|Aggregated GHS information provided by 105 companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Warning|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P273, P301+P312, P304+P312, P304+P340, P312, P330, P391, and P501|H315: Causes skin irritation [Warning Skin corrosion/irritation]|P260, P264, P270, P280, P302+P352, P305+P351+P338, P307+P311, P321, P332+P313, P337+P313, P362, P405, and P501|H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P201, P202, P260, P264, P270, P271, P280, P281, P284, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P309+P311, P310, P314, P320, P321, P363, P403+P233, P405, and P501

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 1732 datasheet. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to reduce vapors. DO NOT GET WATER INSIDE CONTAINERS. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements or confined areas. SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2016)

For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)|Eye/face protection: Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).|Skin protection: Handle with gloves.|Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.|Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).|For more Personal Protective Equipment (PPE) (Complete) data for Antimony pentafluoride (13 total), please visit the HSDB record page.

Not combustible, but if involved in a fire decomposes to produce fumes of antimony and hydrogen fluoride. Contact with combustible materials may increase the fire hazard.

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.|Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.|Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Use dry chemical, carbon dioxide, or flooding quantities of water as spray on fire involved material.|Approach fire from upwind; avoid hazardous vapors and toxic decomposition products. Do not use water or foam on fire or on adjacent fires; extinguish with dry chemicals or carbon dioxide. Water spray may be used to reduce vapors. ... If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Notify local health or fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors, or shows any signs of deforming), withdraw immediately to a secure position. ... The only respirators recommended for firefighting are self-contained breathing apparatuses that have full face-pieces and are operated in a pressure-demand or other positive-pressure mode.|If material involved in fire: Use dry chemical, dry sand, or carbon dioxide. Do not use water on material itself. If large quantities of combustibles are involved, use water in flooding quantities as spray and fog. Use water spray to knock-down vapors. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.

Closed containers may rupture violently when heated.

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.|Wear special protective clothing and positive pressure self-contained breathing apparatus.|Keep water away from release. Approach release from upwind. Stop or control the leak, if this can be done without undue risk. Control runoff and isolate discharged material for proper disposal.|Evacuate persons not wearing protective equipment from area of spill or leak until cleanup is complete. Remove all ignition sources. Do not touch spilled material; stop leak if you can do so without undue risk. Use water spray to reduce vapors. For large spills, dike far ahead. Absorb spills with noncombustible absorbent material, such as vermiculite, dry sand, earth, etc., and deposit in sealed containers. Ventilate area after cleanup is complete. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters.

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.|Precautions for safe handling: Avoid contact with skin and eyes. Avoid inhalation of vapor or mist.|Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.|Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.|For more Preventive Measures (Complete) data for Antimony pentafluoride (14 total), please visit the HSDB record page.

If ... THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances /(see table below)/ ... to obtain initial isolation and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED, go directly to the appropriate guide /(see guide(s) below)/ and use the evacuation information shown under PUBLIC SAFETY.|Table of Water-Reactive Materials Which Produce Toxic Gases.|/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult GUIDE 140. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.|/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Health: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air may release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.|For more DOT Emergency Guidelines (Complete) data for Antimony pentafluoride (10 total), please visit the HSDB record page.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article. Antimony pentafluoride is included on the dangerous goods list.|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials. Antimony pentafluoride is included on the dangerous goods list.

A very reactive, corrosive liquid to skin, eyes, mucous membranes.

Permissible Exposure Limit: Table Z-1 8-Hour Time Weighted Avg: 0.5 mg/cu m. /Antimony and compounds (as Sb)/

Recommended Exposure Limit: 10 hr Time-Weighted avg 0.5 mg/cu m. /Antimony/

Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Do NOT wash away into sewer. Do NOT absorb in saw-dust or other combustible absorbents. Do NOT let this chemical enter the environment. Then store and dispose of according to local regulations.

Separated from combustible substances, reducing agents and food and feedstuffs. Dry. Well closed. Keep in a well-ventilated room. Do NOT store or transport in containers made from metal or glass. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.

Corrosive. Inhalation may cause severe swelling of the throat. This may result in asphyxia. Inhalation may cause lung oedema, but only after initial corrosive effects on eyes and/or airways have become manifest. Exposure at high levels could cause severe lung damage. Medical observation is indicated.

The substance may have effects on the cardiovascular system and respiratory tract. This may result in impaired functions.

AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!

Use ventilation, local exhaust or breathing protection.

Protective gloves. Protective clothing.

Wear face shield or eye protection in combination with breathing protection.

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Antimony compounds are included on this list. /Antimony Componds/

D003; A waste containing antimonoy pentafluoride may (or may not) be characterized a hazardous waste following testing for the reactivity characteristics as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations.

Releases of CERCLA hazardous substances are subject to the release reporting requirement of CERCLA section 103, codified at 40 CFR part 302, in addition to the requirements of 40 CFR part 355. Antimony pentafluoride is an extremely hazardous substance (EHS) subject to reporting requirements when stored in amounts in excess of its threshold planning quantity (TPQ) of 500 lbs.

D003; A solid waste containing antimony pentafluoride may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.

Toxicity

highly toxic

IDENTIFICATION AND USE: Antimony pentafluoride is a hygroscopic, viscous liquid. It is used in the fluorination of organic compounds. HUMAN STUDIES: It is a corrosive liquid to skin, eyes, mucous membranes. ANIMAL STUDIES: Distribution in rats after chronic poisoning by inhalation of antimony pentafluoride showed high antimony concentration in blood. Levels in liver, kidneys, spleen and pancreas were similar. The antimony was retained for a long time and could be detected in organs under examination one month after experiment discontinued.

Antimony pentafluoride's production and use in the fluorination of organic compounds(1) may result in its release to the environment through various waste streams(SRC).

Drug Information

Distribution in rats after chronic poisoning by inhalation of antimony pentafluoride showed high antimony concentration in blood. Levels in liver, kidneys, spleen and pancreas were similar. The antimony was retained for a long time and could be detected in organs under examination one month after experiment discontinued.

The compound is irritating to eyes, skin, and lungs. Contact with eyes or skin causes severe burns. The compound is extremely toxic with a probable oral lethal dose of 5-50 mg/kg or between 7 drops and one teaspoonful for a 150 pound person (antimony salts). (EPA, 1998)

Warning: Antimony Pentafluoride is highly corrosive to the eyes, skin, and lungs, and is extremely toxic if swallowed. The estimated lethal dose after ingestion is between 7 drops and one teaspoonful for a 150 pound person. Signs and Symptoms of Antimony Pentafluoride Exposure: Acute exposure to antimony pentafluoride may result in severe eye damage, vomiting, and severe burns of mouth and throat. Over- exposure by any route can cause bloody stools, slow pulse rate, low blood pressure, coma, convulsions, and cardiac arrest. Emergency Life-Support Procedures: Acute exposure to antimony pentafluoride may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1. Move victims to fresh air. Emergency personnel should avoid self-exposure to antimony pentafluoride. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4. Rush to a health care facility. Dermal/Eye Exposure: 1. Remove victims from exposure. Emergency personnel should avoid self-exposure to antimony pentafluoride. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3. Remove contaminated clothing as soon as possible. 4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5. Wash exposed skin areas thoroughly with soap and water. 6. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 7. Rush to a health care facility. Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 2. DO NOT induce vomiting or attempt to neutralize. 3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4. Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 ox or 3/4 cup); adults, 250 mL (8 oz or 1 cup). Water or milk should be given only if victims are conscious and alert. 5. Rush to a health care facility. (EPA, 1998)


Fresh air, rest. Half-upright position. Refer immediately for medical attention.


Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer immediately for medical attention. Apply calcium gluconate to the burn areas.


Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Fluorine and related compounds/|Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool. ... . Cover skin burns with dry sterile dressings after decontamination ... . /Fluorine and related compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive pressure ventilation techniques with a bag-valve-mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of D5W. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluids cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Treat seizures with diazepam (Valium) or lorazepam (Ativan) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Fluorine and related compounds/|If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water or milk. Do not induce vomiting. Medical observation is recommended for 24-48 hr after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a corticosteroid spray.

/SIGNS AND SYMPTOMS/ A very reactive, corrosive liquid to skin, eyes, mucous membranes.

antimony pentafluoride

Serious local effects and systemic effects by all routes of exposure.

Burning sensation. Cough. Laboured breathing. Nausea. Shortness of breath. Sore throat.


Redness. Serious skin burns. Pain.


Redness. Pain. Severe deep burns.

Antimony pentafluoride Use and Manufacturing

Methods of Manufacturing

May be prepared by fluorination of antimony trifluoride (SbF3) or by treatment of antimony pentachloride (SbCl5) with hydrogen fluoride (HF). In the latter method the fifth chlorine is removed with difficulty; failure to completely remove the chlorine results in contamination of the distilled SbF5 with Sb(III).|Antimony pentafluoride is prepared by treating antimony pentachloride with excess anhydrous hydrogen fluoride. The antimony pentafluoride is separated from the volatile byproducts by fractional distillation. It can also be prepared by allowing fluorine to react with antimony powder or molten antimony trifluoride.

Uses

In the fluorination of organic Compounds, see the monograph Preparation, Properties and Technology of Fluorine and Organic Fluoro Compounds, C. Slesser, S. R. Schram, Eds. (McGraw-Hill, New York, 1951) 868 pp.

Antimony fluoride (SbF5): ACTIVE|Antimony can be trivalent or pentavalent in compounds. Both exist in antimony(IV) oxide, Sb2O4, and presumably in the deep violet haloantimonates (IV), such as Cs2(SbCl6). The pentavalent compounds, as well as most of the trivalent ones, are hydrolyzed by water to form antimony salts, e.g., SbOCl, and hydrated oxides. The only halides of antimony that have any industrial significance are the chlorides and fluorides. /Antimony compounds/

Fire Hazards -> Corrosives, Reactive - 1st degree

Computed Properties

Molecular Weight:216.752
Hydrogen Bond Acceptor Count:5
Exact Mass:215.89583
Monoisotopic Mass:215.89583
Heavy Atom Count:6
Complexity:37.1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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