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Home > Encyclopedia > Copper bromide (CuBr)

Copper bromide (CuBr)

Copper bromide (CuBr) structure

Copper bromide (CuBr) 

structure
  • CAS No:

    7787-70-4

  • Formula:

    BrCu

  • Chemical Name:

    Copper bromide (CuBr)

  • Synonyms:

    Copper bromide (CuBr);Cuprous bromide;Copper monobromide;Copper(1+) bromide;Copper(I) bromide;Copper(1+) bromide tetramer;Copper bromide (Cu4Br4);Cuprous bromide (CuBr);Copper bromide (Cu0.5Br0.5);62431-55-4;2490708-37-5

  • Categories:

    Inorganic Chemistry  >  Inorganic Salts

Description

Cuprous bromide (CuBr) is an inorganic chemical compound that holds a significant place in the field of chemistry due to its unique properties and widespread applications. This monovalent copper halide exists in the form of white, cubic crystals, exhibiting pure chemical characteristics. However, this beautiful white substance is highly sensitive to environmental conditions and will quickly decompose once exposed to light or moist air, revealing its unstable chemical properties. In terms of chemical structure, the molecular structure of CuBr is similar to that of zinc sulfide, forming a paramagnetic solid structure. This structure endows it with unique performance in certain chemical reactions, making it an important reagent in organic synthesis. CuBr can form stable complexes with various acids such as hydrochloric acid and hydrobromic acid, and react with aqueous ammonia to produce corresponding ammine complexes. These characteristics make it highly adjustable in chemical reactions. In terms of physical properties, the density of CuBr is 4.72 g/cm3, its melting point is 504 °C, and its boiling point is as high as 1345 °C, showing its high melting point and relatively high density. This substance dissolves slowly in water but can be fully dissolved in hydrobromic acid, hydrochloric acid, and ammonium hydroxide, while being insoluble in acetone. These characteristics determine its special requirements for experimental operation and storage, which need to be kept in a cool and dry environment, sealed to prevent decomposition caused by contact with air or water. The CAS number of CuBr is 7787-70-4, and its chemical formula clearly indicates its chemical composition. In addition, it has many alternative names, reflecting different names in different research fields and applications. The vapor pressure of CuBr at 1 mm Hg @ 572 °C indicates its stability in high-temperature environments, but it decomposes when exposed to hot water or strong oxidizing agents such as nitric acid. CuBr, a monovalent copper bromide, is an inorganic salt with high reactivity and unique chemical structure, widely used in organic synthesis and chemical research. Its sensitivity to environmental conditions, good solubility, and paramagnetism make it a unique tool for chemical reactions, and a valuable asset for chemists.

Copper bromide (CuBr) Basic Attributes

143.45000

141.84800

232-131-6

DTXSID6052530

White powder or cubic crystals (zinc blende structure)|White tetrahedral crystals|White crystalline solid becoming green in light

2827590000

Characteristics

0

0.84310

Copper (i) bromide appears as white powder or crystal. Turns green to dark blue on exposure to sunlight. Sinks and mixes slowly with water. (USCG, 1999)

4.72 g/cm3 @ Temp: 25 °C

504 °C

1345 °C

1345°C

2.09

Soluble in hydrogen bromide, hydrochloric acid, and ammonium hydroxide. Slightly soluble in water. Insoluble in acetone.

Store in a cool, dry place. Store in a tightly closed container.

1 MM HG @ 572 DEG C

Decomposes in hot water, nitric acid|Heat of fusion: 16.03 cal/g

Safety Information

III

8

UN 3260

3

R36/37/38

S24/25

Xi

Stable, but may be air or light sensitive. Incompatible with alkali metals, strong oxidizing agents.

P261-P305 + P351 + P338

H315-H319-H335

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

MIXTURE /WITH/ POTASSIUM ... PRODUCES WEAK EXPLOSION ON IMPACT ... .

|Danger|H302 (51.58%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P310, P312, P321, P330, P332+P313, P337+P313, P362, P391, P403+P233, P405, and P501|Aggregated GHS information provided by 190 companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Rubber gloves, safety glasses, & lab coat.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

Irritating to skin & eyes. ... Irritation to upper respiratory tract.

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 1 mg/cu m. /Copper (dusts and mists)/

Drug Information

Food and Environmental Agents: Effect on Breast-Feeding: Bromide (photographic laboratory): Potential absorption and bromide transfer into milk. /from Table 7/|Maternal Medication Usually Compatible with Breast-Feeding: Bromide: Rash, weakness, absence of cry with maternal intake of 5.4 g/d. /from Table 6/

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Copper and related compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Start an IV with lactated Ringer's /SRP: "To keep open", minimal flow rate/. Watch for signs of fluid overload. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine, hydrochloride to assist eye irrigation ... . /Copper and related compounds/

Irritating to skin & eyes. ... Irritation to upper respiratory tract.

Copper bromide (CuBr) Use and Manufacturing

Methods of Manufacturing

Prepn: Briggs, J Chem Soc 127: 496 (1925); Keller, Wycoff, Inorg Syn 2: 3 (1946); Wagner, Wagner, J Chem Phys 26: 1597 (1957).|... By reducing copper(II) sulfate soln containing potassium bromide with sulfur dioxide or other standard reducing agents, or with metallic copper.|Prepared pyrometallurgically or by reducing a copper(II) sulfate solution in the presence of sodium bromide, usually with sulfur dioxide or metallic copper.

Uses

Copper(I) bromide is the chemical compound with the formula CuBr. This diamagnetic solid adopts a polymeric structure akin to that for zinc sulfide. The compound is widely used in the synthesis of organic compounds.

Copper bromide (CuBr): ACTIVE

Computed Properties

Molecular Weight:143.45
Exact Mass:141.84793
Monoisotopic Mass:141.84793
Heavy Atom Count:2
Complexity:2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

Price Analysis

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