Triisopropyl phosphite
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Triisopropyl phosphite
structure -
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CAS No:
116-17-6
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Formula:
C9H21O3P
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Chemical Name:
Triisopropyl phosphite
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Synonyms:
Phosphorous acid,tris(1-methylethyl) ester;Phosphorous acid,triisopropyl ester;Isopropyl phosphite ((C3H7O)3P);Triisopropyl phosphite;Triisopropoxyphosphine;Isopropyl phosphite;Tri-2-propyl phosphite;NSC 6516;Tris(isopropyl) phosphite
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CAS No:
Triisopropyl phosphite Basic Attributes
208.24
208.24
1701528
204-130-0
RJ7QU4YQUN
6516
DTXSID9044372
Colorless liquid
Characteristics
27.7
1.71
Clear Liquid
0.914 g/cm3 @ Temp: 20 °C
87-88 °C @ Press: 0.5 Torr
154 °F
n20/D 1.411(lit.)
Miscible with most organic solvents; insoluble in water
-20°C
<2 mm Hg ( 20 °C)
Characteristic odor
Hydrolyzes slowly in water|Hydroxy radical reaction rate constant = 1.2X10-10 cu cm/molec-sec at 25 °C (est)
Safety Information
III
3
UN 3278 6.1/PG 3
3
25-38-68
37-46-45-36/37
TH2800000
T,F
Toxic/Flammable/Moisture Sensitive/
High thermal stability
Missing Phrase - N15.00950417
H301-H315
SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.
|Danger|H301 (97.65%): Toxic if swallowed [Danger Acute toxicity, oral]|P264, P270, P280, P301+P310, P302+P352, P321, P330, P332+P313, P362, P405, and P501|Aggregated GHS information provided by 170 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Combustible
/GUIDE 151: SUBSTANCES - TOXIC (NON-COMBUSTIBLE)/ Health: Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. /Organophosphorus compound, poisonous, liquid, NOS; Organophosphorus compound, toxic, liquid, NOS; Organophosphorus compound, poisonous, NOS; Organophosphorus compound, toxic, NOS (Triisopropyl phosphite)/|/GUIDE 151: SUBSTANCES - TOXIC (NON-COMBUSTIBLE)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways. /Organophosphorus compound, poisonous, liquid, NOS; Organophosphorus compound, toxic, liquid, NOS; Organophosphorus compound, poisonous, NOS; Organophosphorus compound, toxic, NOS (Triisopropyl phosphite)/|/GUIDE 151: SUBSTANCES - TOXIC (NON-COMBUSTIBLE)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at lease 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. /Organophosphorus compound, poisonous, liquid, NOS; Organophosphorus compound, toxic, liquid, NOS; Organophosphorus compound, poisonous, NOS; Organophosphorus compound, toxic, NOS (Triisopropyl phosphite)/|/GUIDE 151: SUBSTANCES - TOXIC (NON-COMBUSTIBLE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Organophosphorus compound, poisonous, liquid, NOS; Organophosphorus compound, toxic, liquid, NOS; Organophosphorus compound, poisonous, NOS; Organophosphorus compound, toxic, NOS (Triisopropyl phosphite)/|For more DOT Emergency Guidelines (Complete) data for TRIISOPROPYL PHOSPHITE (8 total), please visit the HSDB record page.
Triisopropyl phosphite Use and Manufacturing
Reaction of phosphorus trichloride and isopropyl alcohol in the presence of a tertiary amine
Referred to as IPPP, it has both flame retardant and plasticizing dual-function additives. It has excellent compatibility with polymer materials such as PVC, which can reduce the viscosity of PVC paste, enhance the paste wettability, and maintain the viscosity of the paste for a long time. Stability, low toxicity, tasteless, low viscosity, antistatic property and good low temperature mechanical properties, it can be used as the main plasticizer of flame retardant PVC products
Intermediates
(1972) PROBABLY GREATER THAN 4.54X10+5 GRAMS|(1975) PROBABLY GREATER THAN 4.54X10+5 GRAMS|Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#4057]
All other basic organic chemical manufacturing|Phosphorous acid, tris(1-methylethyl) ester: ACTIVE|On December 29, 2004, the Department of Commerce Bureau of Industry and Security announced the implementation of the Understandings Reached at the June 2004 Australia Group (AG). Among several items, this rule adds the following four precursor chemicals to the list of chemicals in Export Control Classification Number (ECCN) 1C350.d that may be used as precursors to toxic chemical agents: Tri-isopropyl phosphite; O,O-diethyl phosphorothioate; O,O-diethyl phosphorodithioate; and Sodium hexafluorosilicate.
A flame ionization detector was modified so hydrogen flame could also be used as emission source for flame photometric detector.
Computed Properties
Molecular Weight:208.23
XLogP3:2.5
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:208.12283153
Monoisotopic Mass:208.12283153
Topological Polar Surface Area:27.7
Heavy Atom Count:13
Complexity:102
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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