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ortho-chlorophenol

Name: ortho-chlorophenol
Brand: OORENT
SKU: pr2606171868
Price: 33 USD
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CAS No.:

108-43-0

Grade:

Pharmaceutical Grade

Content:

99.5%

Port:

上海

Brand:

OORENT

Packaging:

Vial/Bottle/Bag/Carton

Price valid (until):

2027-12-02

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Qingdao Orient Chemical Co.,LTD

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Trader

Location:

China

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Product Description
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Description

Product Detail

3-Chlorophenol Basic information

Product Name:	3-Chlorophenol
Synonyms:	3-chloro-1-hydroxybenzene;3-chloro-pheno;3-Hydroxychlorobenzene;m-chlorophenicacid;3-Chloro-1-benzenol;3-Cl-phenol;3-Chlorophenol,99%;3-Chlorophenol Standard
CAS:	108-43-0
MF:	C6H5ClO
MW:	128.56
EINECS:	203-582-6
Product Categories:	Pyridines;Chlorine Compounds;Phenols;Alpha sort;C;CAlphabetic;Organics;Phenol&Thiophenol&Mercaptan;Phenoles and thiophenoles;CH;Pesticides&Metabolites;Organic Building Blocks;Oxygen Compounds
Mol File:	108-43-0.mol

3-Chlorophenol Chemical Properties

Melting point	31-34 °C (lit.)
Boiling point	214 °C (lit.)
density	1.218 g/mL at 25 °C (lit.)
vapor pressure	1 hPa (44 °C)
refractive index	n20/D 1.563(lit.)
Fp	>230 °F
storage temp.	Store below +30°C.
solubility	Soluble in ethanol and ether.
pka	8.85(at 25℃)
form	Liquid After Melting
color	Clear yellow to brownish
Odor	distinct phenol-like odor
PH	3.5 (27.7g/l, H2O, 20℃)
Water Solubility	27.7 g/L (20 ºC)
Merck	14,2154
BRN	1634401
Henry's Law Constant	7.2×10⁰ mol/(m³Pa) at 25℃, Chao et al. (2017)
Stability:	Stable. Combustible. Incompatible with acid chlorides, oxidizing agents, acid anhydrides. Discolours in air.
InChI	1S/C6H5ClO/c7-5-2-1-3-6(8)4-5/h1-4,8H
InChIKey	HORNXRXVQWOLPJ-UHFFFAOYSA-N
SMILES	Oc1cccc(Cl)c1
CAS DataBase Reference	108-43-0(CAS DataBase Reference)
NIST Chemistry Reference	Phenol, 3-chloro-(108-43-0)
EPA Substance Registry System	m-Chlorophenol (108-43-0)

Safety Information

Hazard Codes	Xn,N
Risk Statements	20/21/22-51/53
Safety Statements	28-61-28A
RIDADR	UN 2020 6.1/PG 3
WGK Germany	2
RTECS	SK2450000
F	9
Autoignition Temperature	>600 °C
TSCA	TSCA listed
HazardClass	6.1
PackingGroup	III
HS Code	29081000
Storage Class	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Aquatic Chronic 2 Eye Dam. 1 Skin Irrit. 2
Hazardous Substances Data	108-43-0(Hazardous Substances Data)
Toxicity	LD50 orally in rats: 0.57 g/kg (Deichmann)

MSDS Information

Provider	Language
3-Chlorophenol	English
SigmaAldrich	English
ACROS	English
ALFA	English

3-Chlorophenol Usage And Synthesis

Chemical Properties	White to light yellow crystal.
Chemical Properties	All isomers have a characteristic odor.
Uses	3-Chlorophenol is a halophenol with antifungal activity. 3-Chlorophenol is commonly used as a building block in the preparation of variety of biologically active compounds. Studies suggest that 3-Chlo rophenol can be used in the regeneration of vegetal activated carbons.
Uses	3-Chlorophenol is widely used in the pharmaceutical, dyes and organic synthesis industry. It is an important intermediate in the synthesis of chemicals.
Uses	3-Chlorophenol is generally used in building various polycyclic aromatic systems. It is also employed in palladium-catalyzed coupling reactions to synthesize aryl intermediates in synthetic organic chemistry.
Definition	ChEBI: 3-chlorophenol is a monochlorophenol carrying the chloro substituent at position 3.
General Description	White crystals with an odor of phenol. Sinks in and slowly dissolves in water.
Air & Water Reactions	Discolors on exposure to air. Water soluble
Reactivity Profile	3-Chlorophenol is incompatible with acid chlorides, acid anhydrides and oxidizing agents .
Hazard	Toxic by skin absorption, inhalation, or ingestion.
Fire Hazard	3-Chlorophenol is probably combustible.
Safety Profile	Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental tumorigenic data by skin contact. Mutation data reported. Flammable or combustible liquid. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROPHENOLS.
Potential Exposure	Monochlorophenols are used in the manufacture of fungicides, slimicides, bactericides, pesticides, herbicides, disinfectants, wood and glue preservatives; in the production of phenolic resins; in the extraction of certain minerals from coal; as a denaturant for ethanol; as an antiseptic; as a disinfectant, and others.
Shipping	UN 2020 (solid); UN2021 (liquid) Chlorophenols, solid and liquid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Purification Methods	It could not be obtained solid by crystallisation from pet ether. It is best purified by distillation under reduced pressure. [Beilstein 6 IV 810.]
Incompatibilities	May form explosive mixture with air. Contact with oxidizing agents can cause fire and explosion hazard. Heat produces hydrogen chloride and chlorine. Corrosive to aluminum, copper and other chemically active metals.
Waste Disposal	Incinerate in admixture with flammable solvent in furnace equipped with afterburner and scrubber.

3-Chlorophenol Preparation Products And Raw materials

Raw materials	Sodium nitrite-->Sodium hypochlorite-->Sulfuryl chloride-->4-Chloroaniline-->3-Chloroaniline-->2-Chlorophenol
Preparation Products	4-Chloro-2-hydroxybenzaldehyde-->2-CHLORO-6-HYDROXYBENZALDEHYDE-->3-CHLOROPHENOXYACETYL CHLORIDE-->2,4,6-tribromo 3-chlorophenol-->2,4-dibromo-5-chlorophenol-->3-CHLORO-2-IODOPHENOL-->3-Chlorophenoxyacetic acid-->(+)-Cloprostenol-->3-CHLORO-4-IODOPHENOL-->2-BROMO-3-CHLOROPHENOL

Shop Fluorobenzene462-06-6C6H5F-Detailed Image 2

ECHEMI Editorial Reference

White to light yellow crystal. All isomers have a characteristic odor.White crystals with an odor of phenol. Sinks in and slowly dissolves in water.

Basic Info

Product Name:

3-Chlorophenol

Other Name:

Phenol,3-chloro-;Phenol,m-chloro-;3-Chlorophenol;m-Chlorophenol;3-Hydroxychlorobenzene;m-Chlorophenic acid;NSC 59700

CAS No.:

108-43-0

Molecular Formula:

C6H5ClO

InChIKeys:

InChIKey=HORNXRXVQWOLPJ-UHFFFAOYSA-N

Molecular Weight:

128.56

Exact Mass:

128.56

EC Number:

203-582-6

UNII:

Z2Z7M2FTAD

ICSC Number:

0150

NSC Number:

59700

UN Number:

2020

DSSTox ID:

DTXSID4024800|DTXSID3094129

Color/Form:

Needles|White crystals

HScode:

29081000

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

20.23000

XLogP3:

2.40

Appearance:

M-chlorophenol appears as white crystals with an odor of phenol. Sinks in and slowly dissolves in water. (NTP, 1992)

Density:

1.268 g/cm³ @ Temp: 25 °C

Melting Point:

32.6 °C

Boiling Point:

214 °C @ Press: 760 Torr

Flash Point:

>230 °F

Refractive Index:

n 20/D 1.563(lit.)

Water Solubility:

soluble in ethanol and ether.

Storage Conditions:

Store in tightly closed containers in a cool, well ventilated area. Metal containers involving the transfer of this chemical should be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers to precess containers. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition such as smoking and

Vapor Pressure:

1 hPa (44 °C)

Toxicity:

LD50 orally in rats: 0.57 g/kg (Deichmann)

Odor:

Odor similar to phenol

Taste:

Strong medicinal taste

PKA:

9.12None

Henrys Law Constant:

3.45e-07 atm-m3/mole|Henry's Law constant = 3.45X10-7 atm cu-m/mole at 25 °C

Dissociation Constants:

9.12|pKa = 9.12 at 25 °C

Experimental Properties:

Dipole moment in benzene: 2.10 D|Medicinal, empyrumatic odor /Chlorophenols/|Taste threshold: Detection in water 1.00 ppm /Chlorophenol/|Heat of fusion = 105.789 kJ/kg at 33 °C|Hydroxyl radical reaction rate constant = 2.36X10-11 cu-cm/molec-sec at 25 °C (est)

Air and Water Reactions:

Discolors on exposure to air. Water soluble

Reactive Group:

Phenols and Cresols

Reactivity Profile:

M-CHLOROPHENOL is incompatible with acid chlorides, acid anhydrides and oxidizing agents (NTP, 1992).

Heat of Combustion:

2760.0 kJ/mole at 77 °F solid /25 °C/

Heat of Vaporization:

45.86 kJ/mole at 214 °C

Critical Temperature & Pressure:

Critical temperature = 53.20 bar; Critical pressure = 729.00 K

See More 3-Chlorophenol Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Acute toxicity - Category 4, Dermal

Acute toxicity - Category 4, Inhalation

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Warning
Hazard statement(s)	H302 Harmful if swallowed H312 Harmful in contact with skin H332 Harmful if inhaled H411 Toxic to aquatic life with long lasting effects
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment.
Response	P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P317 Get medical help. P321 Specific treatment (see ... on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P391 Collect spillage.
Storage	none
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Separated from strong oxidants and food and feedstuffs. Well closed.Store in tightly closed containers in a cool, well ventilated area. Metal containers involving the transfer of this chemical should be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers to precess containers. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition such as smoking and open flames, are prohibited where this chemical is used, handled, or stored in a manner that could create a potential fire or explosion hazard. Monochlorophenols

See More 3-Chlorophenol Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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