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N-Methylaniline | Pharmaceutical Grade | 99.99% Purity | 10mg 20mg 30mg Vials | Lyophilized Powder | CAS 100-61-8 buy - image4

N-Methylaniline | Pharmaceutical Grade | 99.99% Purity | 10mg 20mg 30mg Vials | Lyophilized Powder | CAS 100-61-8

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CAS No.:

100-61-8

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Pharmaceutical Grade

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99.99%

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Description

N-Methylaniline Basic information

Product Name:	N-Methylaniline
Synonyms:	MONOMETHYLANILINE;N-METHYLANILINE;N-METHYLAMINOBENZENE;N-MONOMETHYLANILINE;(Methylamino)benzene;Benzenamine, N-methyl-;Benzenenamine, N-methyl-;methylaniline(non-specificname)
CAS:	100-61-8
MF:	C7H9N
MW:	107.15
EINECS:	202-870-9
Product Categories:	Amines;Building Blocks;C7;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Intermediates of Dyes and Pigments;Anilines, Aromatic Amines and Nitro Compounds;Organics;Fine Intermediate;100-61-8
Mol File:	100-61-8.mol

N-Methylaniline Chemical Properties

Melting point	-57 °C (lit.)
Boiling point	196 °C (lit.)
density	0.989 g/mL at 25 °C (lit.)
vapor pressure	0.5 hPa (20 °C)
refractive index	n20/D 1.571(lit.)
Fp	174 °F
storage temp.	Store below +30°C.
solubility	water: slightly soluble30g/L
form	Liquid
pka	4.84(at 25℃)
color	Clear yellow to brown
Odor	Moderate aniline-type.
PH	7.6 (1g/l, H2O, 20℃)
Water Solubility	30 g/L
Sensitive	Air Sensitive
Merck	14,6019
BRN	741982
Henry's Law Constant	(x 10^-5 atmm³/mol): 1.19 at 25 °C (approximate - calculated from water solubility and vapor pressure)
Dielectric constant	6.0（22℃）
Exposure limits	ACGIH:TLV-TWA 0.5 ppm (2.2 mg/m3) OSHA:PEL-TWA 2 ppm (9 mg/m3) NIOSH:REL-TWA 0.5 ppm
Stability:	Incompatible with strong oxidizing agents. Discolours upon exposure to air.
InChI	1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3
InChIKey	AFBPFSWMIHJQDM-UHFFFAOYSA-N
SMILES	CNc1ccccc1
LogP	1.66 at 20℃
CAS DataBase Reference	100-61-8(CAS DataBase Reference)
NIST Chemistry Reference	Aniline, N-methyl-(100-61-8)
EPA Substance Registry System	N-Methylaniline (100-61-8)

Safety Information

Hazard Codes	T,N
Risk Statements	23/24/25-33-50/53
Safety Statements	28-36/37-45-60-61-28A
RIDADR	UN 2294
OEB	B
OEL	TWA: 0.5 ppm (2 mg/m3) [skin]
WGK Germany	3
RTECS	BY4550000
F	8
Autoignition Temperature	500 °C
TSCA	TSCA listed
HazardClass	6.1
PackingGroup	III
HS Code	29214200
Storage Class	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral Aquatic Acute 1 Aquatic Chronic 1 Eye Irrit. 2 STOT RE 2 Oral
Hazardous Substances Data	100-61-8(Hazardous Substances Data)
Toxicity	LD in rabbits (g/kg): 0.28 orally; in rabbits, cats (mg/kg): 24, 24 i.v. (Treon)
IDLH	100 ppm

MSDS Information

Provider	Language
Monomethylaniline	English
ACROS	English
SigmaAldrich	English
ALFA	English

N-Methylaniline Usage And Synthesis

Description	N-Methylaniline is a yellow to light brown oily liquid with a weak, ammonia-like odor. Turns reddishbrown if left standing. The odor threshold is 1.7 ppm. Molecular weight= 107.17; Specific gravity (H2O:1)= 0.99;Boiling point=195.6℃; Freezing/Melting point=57.2℃; Vapor pressure= 0.3 mmHg at 20℃; Flash point=79.4℃. Hazard Identification (based on NFPA-704 M Rating System): Health 2, Flammability 2, Reactivity 0. Practically insoluble in water.
Chemical Properties	N-Methylaniline is a yellow to light brown oily liquid with a weak, ammonia-like odor. soluble in ethanol, ether, chloroform, slightly soluble in water. Turns reddishbrown if left standing.
Physical properties	Colorless to yellow to pale brown liquid with a faint, ammonia-like odor. Odor threshold concentration is 1.7 ppm (quoted, Amoore and Hautala, 1983).
Uses	N-Methylaniline is used as a solvent and in organic synthesis. It is used in the production of cationic brilliant red FG, cationic pink B, reactive yellow brown KGR, etc. in the dye industry. N-methylaniline is an intermediate in the synthesis of the insecticide buprofezin and the herbicide mefenacet.
Uses	N-methylaniline was used as raw material, and metal-organic skeleton material CAU-10pydc was used as catalyst to catalyze the reaction of CO₂ with n-methylaniline to produce N-methyl-N-phenylformamide in mild conditions and green solvent acetonitrile^[1]. Poly (N-methylaniline) (PNMA) was prepared by the electrooxidation of N-methylaniline in acidic aqueous solution. PNMA prepared in acidic aqueous solution with different organic solvents and anions had different conductivity. Such as the experimental group added acetonitrile, N, N-dimethylformamide and dimethylsulfoxide, and the experimental group which adding dimethylsulfoxide had the strongest conductivity^[2]. References: [1] Zhiqiang Wang, Chenghua Deng, Xiao Liu, Wenmin Wang, Highly efficient conversion of CO2 into N-formamides catalyzed by a noble-metal-free aluminum-based MOF under mild conditions, 2023, 52, 11163-11167. [2] Jun YANO , Hiroko YOSHIKAWA , Tomomi MUKAI , Sumio YAMASAKI , Akira KITANI, Effect of Anions and Added Organic Solvents of Polymerizing Solutions on the Conductivity of Poly (N-methylaniline), 2006, 74, 42-48.
Preparation	N-methylaniline was synthesized by the reaction of aniline with dimethyl sulfate. Dimethyl sulfate was added dropwise to the mixed solution of aniline and water below 10°C, stirred for 1 h, and then added dropwise with 30% sodium hydroxide solution. The upper layer is the organic phase, and the lower layer is extracted with benzene. After the benzene is recovered from the extract, the obtained oil Chemicalbook-like substance is combined with the organic phase to obtain a mixture of aniline, N-methylaniline and N,N-dimethylaniline. The mixture was treated with sulfuric acid, and the aniline formed sulfate crystals which were filtered off. N,N-dimethylaniline can be converted to N-methylaniline by the following reaction.
Application	N-Methylaniline (NMA) was used in the preparation of self-assembled poly(N-methylaniline)-lignosulfonate (PNMA-LS) composite spheres with reactive silver-ion adsorbability. NMA was also used in electrodeposition of poly(N-methylaniline) (PNMA) coatings on a steel disc electrode using potentiodynamic, potentiostatic and galvanostatic techniques.
Definition	ChEBI: N-methylaniline is a methylaniline that is aniline carrying a methyl substituent at the nitrogen atom. It is a phenylalkylamine, a secondary amine and a methylaniline. It derives from an aniline.
Synthesis Reference(s)	Chemical and Pharmaceutical Bulletin, 14, p. 1007, 1966 DOI: 10.1248/cpb.14.1007 Journal of the American Chemical Society, 107, p. 493, 1985 DOI: 10.1021/ja00288a037 Synthetic Communications, 13, p. 601, 1983 DOI: 10.1080/00397918308059535
General Description	Chemical oxidation of N-methylaniline with dichromate (oxidant) has been studied by Raman spectroscopy.
Hazard	Toxic by ingestion, inhalation, and skin absorption. Methemoglobinemia and central nervous system impairment.
Health Hazard	Recommended Personal Protective Equipment: Approved respirator; rubber gloves; splash proof goggles; Symptoms Following Exposure: Inhalation causes dizziness and headache. Ingestion causes bluish discoloration (cyanosis) of lips, ear lobes, and fingernail beds. Liquid irritates eyes. Absorption through skin produces same symptoms as for ingestion; General Treatment for Exposure: INHALATION: remove victim to fresh air and call a physician at once; administer oxygen until physician arrives. INGESTION: give large amount of water; get medical attention at once. EYES or SKIN: flush with plenty of water for at least 15 min.; if cyanosis is present, shower with soap and warm water, with special attention to scalp and finger nails; remove any contaminated clothing; Toxicity by Inhalation (Threshold Limit Value): Data not available; Short-Term Inhalation Limits: Data not available; Toxicity by Ingestion: Data not available; Late Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Data not available; Liquid or Solid Irritant Characteristics: Data not available; Odor Threshold: Data not available.
Chemical Reactivity	Reactivity with Water No reaction; Reactivity with Common Materials: May attack some forms of plastic; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Safety Profile	Poison by ingestion and intravenous routes. Moderately toxic by subcutaneous route. When heated to decomposition it emits toxic fumes of NOx.
Potential Exposure	The material is used as an intermediate in organic synthesis, as a solvent and as an acid acceptor
First aid	If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 2448 h after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a corticosteroid spray. Note to physician: Treat for methemoglobinemia. Spectrophotometry may be required for precise determination of levels of methemoglobin in urine.
Carcinogenicity	N-methyl aniline (1.95 g/kg of food) given together with sodium nitrite (1.0 g/l of drinking water) to Swiss mice resulted in a 17% incidence of lung adenomas and a 14% incidence of malignant lymphomas; there were no carcinogenic effects in animals treated with Nmethyl aniline alone, suggesting that in vivo nitrosation is necessary for forming carcinogenic nitrosamines. In bacterial mutagenicity assays N-methyl aniline was negative with or without metabolic activation.
Environmental fate	Soil. Reacts slowly with humic acids or humates forming quinoidal structures (Parris, 1980).
storage	Color Code—Blue: Health Hazard/Poison: Store in a secure poison location. Prior to working with this chemical you should be trained on its proper handling and storage. Methylaniline must be stored to avoid contact with strong acids (such as hydrochloric, sulfuric, and nitric), since violent reactions occur. Store in tightly closed containers in a cool, well-ventilated area away from heat. Sources of ignition, such as smoking and open flames, are prohibited where methylaniline is used, handled, or stored in a manner that could create a potential fire or explosion hazard.
Shipping	UN2294 N-Methylaniline, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Purification Methods	Dry it with KOH pellets and fractionally distil it under vacuum. Acetylate, and the acetyl derivative is recrystallised to constant melting point (m 101-102o), then hydrolysed with aqueous HCl and distilled from zinc dust under reduced pressure. [Hammond & Parks J Am Chem Soc 77 340 1955, Beilstein 12 IV 241.]
Incompatibilities	Reacts violently with strong acids, acid chlorides, acid anhydrides, strong oxidizers. Attacks some plasti℃.
Waste Disposal	Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal device.

N-Methylaniline Preparation Products And Raw materials

Raw materials

Methanol-->Dimethyl sulfate-->Phosphorus trichloride-->Aniline-->Water-->N,N-Dimethylaniline-->Dimethyl ether

Preparation Products

Vanillin-->2,6-Dimethylaniline-->5-Azaindole-->Crystal Violet-->Buprofezin-->4-Dimethylaminobenzaldehyde-->1H-PYRROLO[2,3-B]PYRIDINE, 2-METHYL--->Michler's ketone-->Benzothiazole-->REACTIVE BLUE 4-->2-Amino-4,6-dimethoxypyrimidine-->Basic Blue 54-->o-Acetoacetaniside-->Hexamethyldisiloxane-->Mefenacet-->N-METHYL-N-PHENYL-2-PIPERAZIN-1-YLACETAMIDE-->Methyl Orange-->N-2,4-DIMETHYLPHENYL-N'-METHYLFORMAMIDINE-->Methylene Blue-->Malachite Green-->5-Fluorocytosine-->Lidocaine-->4-(TRIMETHYL-UREIDO)-BENZENESULFONYL CHLORIDE-->ASTRAZON PINK FG-->N-(2-Hydroxyethyl)-N-methylaniline-->N-METHYL-N-PHENYLCARBAMOYL CHLORIDE-->Acid Yellow 127-->4-(Dimethylamino)benzophenone-->1-Methyl-1-phenylhydrazine-->ASTRAZON BRILLIANT RED 4G-->RIBITYL-3,4-XYLIDINE*-->2-Chloro-N-(2,6-dimethylphenyl)acetamide-->N-Chloromethyl-N-phenylaminoformyl chloride-->4-(DIMETHYLAMINO)PHENYL THIOCYANATE-->N-METHYL-N-BENZYLANILINE-->1,2-DIPHENYLVINYLENE CARBONATE

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Certificates

Basic Info

Product Name:

N-Methylaniline

Other Name:

Benzenamine,N-methyl-;Aniline,N-methyl-;N-Methylbenzenamine;Anilinomethane;N-Methylaniline;Methylaniline;(Methylamino)benzene;N-Methylphenylamine;N-Monomethylaniline;N-Phenylmethylamine;N-Phenyl-N-methylamine;N-Methyl-N-phenylamine;Methyl(phenyl)amine;NSC 3502

CAS No.:

100-61-8

Molecular Formula:

C7H9N

InChIKeys:

InChIKey=AFBPFSWMIHJQDM-UHFFFAOYSA-N

Molecular Weight:

107.15

Exact Mass:

107.15

EC Number:

202-870-9

UNII:

TH45GK410O

ICSC Number:

0921

NSC Number:

3502

UN Number:

2294

DSSTox ID:

DTXSID9021841

Color/Form:

COLORLESS OR SLIGHTLY YELLOW LIQ|Yellow to light brown liquid.

HScode:

29214200

Categories:

Blood Glucose Regulators

Characteristics

PSA:

XLogP3:

1.7

Appearance:

N-methylaniline appears as a colorless to brown viscous liquid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Density:

0.989 g/cm³ @ Temp: 20 °C

Melting Point:

-57 °C

Boiling Point:

196.25 °C

Flash Point:

174 °F

Refractive Index:

n 20/D 1.571(lit.)

Water Solubility:

water: slightly soluble 30g/L

Storage Conditions:

IN GENERAL, MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS...SHOULD BE STORED IN A COOL, WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, & SHOULD BE PERIODICALLY INSPECTED... INCOMPATIBLE MATERIALS SHOULD BE ISOLATED FROM EACH OTHER.

Vapor Pressure:

0.5 hPa (20 °C)

Vapor Density:

3.9

Toxicity:

LD in rabbits (g/kg): 0.28 orally; in rabbits, cats (mg/kg): 24, 24 i.v. (Treon)

Flammability characteristics:

Class IIIA Combustible Liquid: Fl.P. at or above 140°F and below 200°F.

Odor:

Weak, ammonia-like odor.

Henrys Law Constant:

8.88e-06 atm-m3/mole

Dissociation Constants:

pKa = 4.848 @ 25 °C

Experimental Properties:

Standard Heat of fusion @ 25 °C: 7.7 kcal/mol /liquid/; 20.4 kcal/mol /gas/|Dielectric constant: 6.06 @ 25 °C|Becomes brown on exposure to air.

Air and Water Reactions:

Becomes brown on exposure to air (NTP, 1992). Slightly soluble in water.

Reactive Group:

Amines, Aromatic

Reactivity Profile:

N-METHYLANILINE is an aryl an amine. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.

Heat of Combustion:

-973.5 kcal/mol @ 25 °C /Liquid/

Ionization Potential:

7.32 eV

Flammable Limits:

Class IIIA Combustible Liquid: Fl.P. at or above 140°F and below 200°F.

Heat of Vaporization:

12.7 kcal/mol @ 25 °C

Critical Temperature & Pressure:

Critical temperature = 428 °C; Critical pressure = 51.3 atm

See More N-Methylaniline Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 3, Oral

Acute toxicity - Category 3, Dermal

Acute toxicity - Category 3, Inhalation

Specific target organ toxicity â repeated exposure, Category 2

Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H301 Toxic if swallowed H311 Toxic in contact with skin H331 Toxic if inhaled H373 May cause damage to organs through prolonged or repeated exposure H410 Very toxic to aquatic life with long lasting effects
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment.
Response	P301+P316 IF SWALLOWED: Get emergency medical help immediately. P321 Specific treatment (see ... on this label). P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P316 Get emergency medical help immediately. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P319 Get medical help if you feel unwell. P391 Collect spillage.
Storage	P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames. Above 79.5Â°C use a closed system and ventilation. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Separated from strong oxidants, strong acids and food and feedstuffs. Keep in a well-ventilated room. Store in an area without drain or sewer access.IN GENERAL, MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS...SHOULD BE STORED IN A COOL, WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, & SHOULD BE PERIODICALLY INSPECTED... INCOMPATIBLE MATERIALS SHOULD BE ISOLATED FROM EACH OTHER.

See More N-Methylaniline Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
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Website: orientchem.cc
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Inquiry History

41 Inquiries

Country	Product	Purchase Quantity	Date Posted
Pakistan	N-METHYLANILINE) CAS NO: 100-61-8	5000 MT	Apr 8, 2024
Jordan	N-Methylaniline CAS NO. 100-61-8	100 MT	Sep 28, 2023
India	N-Methylaniline	100 MT	Mar 6, 2025
Jordan	N-Methylanline	100 TON	Jan 25, 2024
Turkey	N-Methylaniline	2 20' Fcl	Jan 25, 2024
Georgia	N-Methylaniline	5 MT	Mar 31, 2026
Georgia	N-Methylaniline (NMA)	5 MT	Mar 27, 2026
Colombia	N-Methyl Aniline (NMA)	5000	Jul 2, 2025
India	N-methylaniline	1.00 KG	Nov 12, 2025
Pakistan	NMA Octane Booster	300 MT	Oct 9, 2025
Pakistan	n-methyl aniline 99%	1 20' Fcl	Aug 18, 2025
Uzbekistan	Monomethylaniline	65000 KG	Apr 22, 2024
Latvia	NMA98%	2000 MT	Feb 13, 2024
United Arab Emirates	NMA Gasoline Octane Booster supplier	1000 MT	Oct 23, 2023
Singapore	N-Methylaniline	1000 MT	Jul 14, 2026
Singapore	N-methylanine	1 KG	Jul 14, 2026
India	N-methyl aniline	1000.00 KG	Apr 28, 2026
Georgia	N-Methylaniline	1 MT	Mar 19, 2026
United Arab Emirates	N-methylaniline	1 KG	Feb 12, 2026
Bahrain	N-Methyl Aniline	1.00 20' Fcl	Dec 5, 2025

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N-Methylaniline | Pharmaceutical Grade | 99.99% Purity | 10mg 20mg 30mg Vials | Lyophilized Powder | CAS 100-61-8

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Seller Information

Inquiry History

Classification of the substance or mixture

GHS label elements, including precautionary statements

Other hazards which do not result in classification

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

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