3,3'-Bis(N-carbazolyl)-1,1'-biphenyl
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3,3'-Bis(N-carbazolyl)-1,1'-biphenyl
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CAS No:
342638-54-4
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Formula:
C36H24N2
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Chemical Name:
3,3'-Bis(N-carbazolyl)-1,1'-biphenyl
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Synonyms:
MCBP;3,3-Di(9H-carbazol-9-yl)biphenyl.;MCBP, 3,3'-bis(carbazol-9-yl)biphenyl;3,3'-Bis(N-carbazolyl)-1,1'-biphenyl;9,9'-Biphenyl-3,3'-diylbis-9H-carbazole;3,3'-Di(9H-carbazol-9-yl)-1,1'-biphenyl;3,3'-Di(9H-carbazol-9-yl)-1,1'-biphenyl;3,3'-Bis(carbazol-9-yl)biphenyl
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CAS No:
Characteristics
9.9
9.7
1.19±0.1 g/cm3
270℃ (chloroformligroine )
732.3±60.0°C at 760 mmHg
396.7±32.9 °C
1.697
Safety Information
P280, P305+P351+P338, P310
H318
|Danger|H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]|P280, P305+P351+P338, and P310|Aggregated GHS information provided by 39 companies from 2 notifications to the ECHA C&L Inventory.
3,3'-Bis(N-carbazolyl)-1,1'-biphenyl Use and Manufacturing
Potassium tertbutoxide (1.12 g, 10 mmol) and carbazole (1.67 g, 10 mmol) were added to appropriate dihalobiphenyl 1 (1 mmol) in dry toluene (20 mL). The mixture was heated in a glass autoclave under argon at 130—140 C for 48 h.The resulting suspension was diluted with water to remove inorganic impurities. The organic layer was separated, concentrated to dryness, and chromatographed on silica gel using a 0—10percent acetone solution in hexane. 4, 4'-Bis(9Hcarbozol-9-yl)-1, 1'biphenyl (2a), the yield was 0.43 g (90percent), m.p. >250 C. Found (percent): C, 89.08; H, 4.84.C36H24N2. Calculated (percent): C, 89.23; H, 4.99. 1H NMR (DMSOd6), : 8.28 (m, 4 H); 8.09 (m, 4 H); 7.80 (m, 4 H);7.47—7.50 (m, 8 H); 7.26—7.28 (m, 4 H). ESIMS, m/z (Irel (percent)):485.20 [M + H]+ (100).General procedure: Potassium tertbutoxide (1.12 g, 10 mmol) and carbazole (1.67 g, 10 mmol) were added to appropriate dihalobiphenyl 1 (1 mmol) in dry toluene (20 mL). The mixture was heated in a glass autoclave under argon at 130—140 C for 48 h.The resulting suspension was diluted with water to remove inorganic impurities. The organic layer was separated, concentrated to dryness, and chromatographed on silica gel using a 0—10percent acetone solution in hexane.
Computed Properties
Molecular Weight:484.6
XLogP3:9.7
Rotatable Bond Count:3
Exact Mass:484.193948774
Monoisotopic Mass:484.193948774
Topological Polar Surface Area:9.9
Heavy Atom Count:38
Complexity:699
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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3,3'-Bis(N-carbazolyl)-1,1'-biphenyl
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