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Home > Encyclopedia > Ethyl 1-methyl-3-piperidinecarboxylate

Ethyl 1-methyl-3-piperidinecarboxylate

Ethyl 1-methyl-3-piperidinecarboxylate structure

Ethyl 1-methyl-3-piperidinecarboxylate 

structure
  • CAS No:

    5166-67-6

  • Formula:

    C9H17NO2

  • Chemical Name:

    Ethyl 1-methyl-3-piperidinecarboxylate

  • Synonyms:

    3-Piperidinecarboxylic acid,1-methyl-,ethyl ester;Nipecotic acid,1-methyl-,ethyl ester;Ethyl 1-methyl-3-piperidinecarboxylate;Ethyl 1-methylnipecotate;Ethyl N-methylnipecotate;NSC 64739

  • Categories:

    Pharmaceutical Intermediates  >  Bulk Drug Intermediates

Description

Clear colorless to pale yellow liquid

Ethyl 1-methyl-3-piperidinecarboxylate Basic Attributes

171.24

171.24

225-951-0

64739

29333990

Characteristics

29.5

1

Clear colorless to pale yellow liquid

0.981 g/cm3 @ Temp: 20 °C

105-107 °C @ Press: 2.5 Torr

155 °F

1.459

Safety Information

NONH for all modes of transport

3

36/37/38

26-36/37/39-37/39

Xi

Irritant

P261-P305 + P351 + P338

H315-H319-H335

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 39 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Ethyl 1-methyl-3-piperidinecarboxylate Use and Manufacturing

General procedure: An autoclave was filled with catalyst (1 molpercent based on the molar amount of amine), flushed with argon and topped up with a solution of amine (0.1 mol) and orthocarboxylic acid ester (0.11-0.3mol) in 10 ml of methanol (or ethanol) and 0.5 ml of a 0.2 M solution of anhydrous ptoluenesulphonic acid in methanol (or ethanol). The mixture was heated to 120°C and hydrogen was injected to 40 bar and then the mixture was stirred at a constant pressure until hydrogen absorption could no longer be detected (0.2 - 6 h). After being filtered off from the catalyst, the filtrate was distilled.

Computed Properties

Molecular Weight:171.24
XLogP3:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:171.125928785
Monoisotopic Mass:171.125928785
Topological Polar Surface Area:29.5
Heavy Atom Count:12
Complexity:159
Undefined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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