NIOBIUM
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NIOBIUM
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CAS No:
7440-03-1
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Formula:
Nb
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Chemical Name:
NIOBIUM
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Synonyms:
COLUMBIAN METAL;COLUMBIUM;NIOBIUM PLASMA EMISSION SPECTROSCOPY STANDARD;NIOBIUM PLASMA EMISSION STANDARD;NIOBIUM, PLASMA STANDARD SOLUTION;NIOBIUM ICP STANDARD;NIOBIUM METAL;NIOBIUM SINGLE ELEMENT PLASMA STANDARD
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CAS No:
Description
Niobium was discovered by Charles Hatchett in 1801 and isolated by Christian Blomstrand of Sweden in 1964. Its name was given after the Greek mythological ?gure Niobe, the daughter of Tantalos; tantalum always was associated with niobium. For many years, the terms “niobium” and “columbium”wereusedinterchangeably;however,thename “niobium” was of?cially adopted by International Union of Pure and Applied Chemistry (IUPAC) in 1950. Niobium is not a very rare element; its crustal abundance is 24ppm,
DryPowder; DryPowder, PelletsLargeCrystals, OtherSolid; OtherSolid; PelletsLargeCrystals
Niobium atom is a vanadium group element atom.|Niobium has been used in trials studying the treatment of Obesity and Overweight.|A metal element atomic number 41, atomic weight 92.906, symbol Nb.
The element was discovered in 1801 by British chemist Charles Hatchett during analysis of a black mineral sample from the British Museum, originally sent in 1753 from Connecticut. He named the element columbium, after the country of its origin, Columbia (United States). In 1844, Rose announced the discovery of a new element which he named as niobium, in honor of Niobe, the daughter of Tantalus, the mythological Goddess of Tears. Later, it was established that Hatchett’s columbium and Roses’ niobium were the same element. Both names remained in use for more than one hundred years. In 1949 at the Fifteenth International Union of Chemistry Congress held at Amsterdam, the name niobium was officially adopted as the international name.Niobium was prepared in the metallic state for the first time by Blomstrand in 1866, later by Moissan, and still later, by Goldschmidt. While Blomstrand reduced niobium chloride with hydrogen to form niobium, Moissan and Goldschmidt reduced the oxide with carbon (in an electrical furnace) and aluminum powder, respectively.Niobium occurs naturally in several minerals, mostly associated with tantalum and many rare earth elements. The metal is never found in free elemental form. It occurs mostly as hydroxide, silicate, or borate or as its oxy salt, niobate, which is mostly associated with isomorphous tantalate. The principal niobium minerals are pyrochlore, loparite, and koppite all of which contain titanium together with calcium and other metals, such as cerium. They are complex hydroxide minerals and their composition may vary with place. Another type of niobium mineral is the niobates-tantalates mixed ores of Nb2O6—Ta2O6 or of compositions (Nb,Ta)2O6. Such ores usually contain iron and sometimes manganese which partially replaces iron. A typical example is an isomorphous admixture of Fe(NbO3)2—Fe(TaO2)2. Many impurity metals, such as tungsten, titanium, and tin are also found in these ores.The abundance of niobium in the earth’s crust is estimated to be in the range 20 mg/kg and its average concentration in sea water is 0.01 mg/L. The metal also is found in the solar system including the lunar surface. Radionucleides niobium-94 and -95 occur in the fission products of uranium- 235.
shiny grey metallic solid
NIOBIUM Basic Attributes
92.91
92.90640
231-113-5
05175J654G
TSCA listed
DTXSID4052479
Silver-gray
8112993090
Characteristics
0
Niobium is a soft grayish-silvery metal that resembles fresh-cut steel. It is usually found inminerals with other related metals. It neither tarnishes nor oxidizes in air at room temperaturebecause of a thin coating of niobium oxide. It does readily oxidize at high temperatures(above 200°C), particularly with oxygen and halogens (group 17). When alloyed with tin andaluminum, niobium has the property of superconductivity at 9.25 Kelvin degrees.Its melting point is 2,468°C, its boiling point is 4,742°C, and its density is 8.57 g/cm3.
0.00000
Silver-gray wire
8.57 g/mL at 25 °C (lit.)
2468 °C (lit.)
4742 °C (lit.)
Insoluble in water.
-20°C
LD50 intraperitoneal in mouse: > 10gm/kg
3 (20°C in H2O)
-20°C
Safety Information
II
8
UN 1383 4.2/PG 1
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F,Xi,C
17-36-26-6-45-36/37/39-27
QT9900000
F,Xi,C
Stable. Incompatible with strong bases, strong oxidizing agents, halogens, oxygen.
P222-P231-P422
Niobium is not considered reactive at normal room temperatures. However, it is toxic in itsphysical forms as dust, powder, shavings, and vapors, and it is carcinogenic if inhaled or ingested.
UN 1383 4.2/PG 1
|Danger|H228 (81%): Flammable solid [Danger Flammable solids]|P210, P222, P240, P241, P280, P302+P334, P370+P378, and P422|Aggregated GHS information provided by 484 companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Toxicity
ACGIH: TWA 0.5 ppm(2.5 mg/m3); Ceiling 2 ppm (Skin)OSHA: TWA 3 ppmNIOSH: IDLH 30 ppm(250 mg/m3); TWA 3 ppm(2.5 mg/m3); Ceiling 6 ppm(5 mg/m3)
NIOBIUM Use and Manufacturing
In ferrous metallurgy:Ferroniobium (produced by silicon reduction of columbite) is used to alloy stainless steels and metals for welding rods.In niobium base alloys for high temperatures and nuclear reactions.Niobium has some use as a getter in electronic vacuum tubes.
AS A COMPONENT OF STEEL SLABS
Arts, crafts, and hobby materials
Niobium is a very important metal in both ferrous and nonferrous metallurgy. As an additive to alloys or when alloyed with other metals niobium imparts high mechanical strength, high electrical conductivity, and ductility to alloys. It enhances corrosion resistance of most alloys. The metal and several of its alloys exhibit superconductivity. Nobium is used as an additive in the manufacture of most high strength, low alloy carbon steels and microalloyed steels that are used in the construction of oil and gas pipelines, bridges, buildings, concrete bars, and automobiles.Nobium also is added to nickel- and cobalt-based superalloys and is a component of zirconium, titanium and tungsten alloys.Other applications of niobium are in electronic and propulsion devices, in electrodes; in catalysis; and in vacuum tubes and high-pressure sodium vapor lamps.
1,000,000 - 10,000,000 lb
There are several processes for extracting and refining niobium from its ores. The process of choice depends on nature of the ore and end use intended for the metal. Some common steps in these recovery processes involve ore preconcentration, breaking or opening the ore, obtaining pure niobium compounds, reduction of niobium compounds to niobium metal, purification or refining metal and fabrication. If niobium is extracted from a niobium-tantalum ore, the most important step is separation of niobium from tantalum, both of which are chemically very similar.Ferroniobium can be produced from the ore pyrochlore in batch process by thermal reduction in a refractory-lined steel or preferably an electric furnace reactor. Aluminum powder is used as a reducing agent.Ore-opening is a key step in the recovery of niobium, and separation of niobium from tantalum and impurity metals is the most important step in its extraction from the ore. It may be achieved by several methods that include solvent extraction, ion exchange, fractional crystallization, fractional sublimation, and other techniques.High purity grade metal may be produced by reduction of niobium pentaoxide, Nb2O5 or pentachloride, NbCl5 at elevated temperatures ranging from 1400 to 2000°C and often under vacuum using various reducing agents, such as carbon, hydrogen, sodium and other substances:Nb2O5 + 7C → 2NbC + 5CONb2O5 + 5NbC → 7Nb + 5CO2NbCl5 + 5H2 → 2Nb + 10HClNbCl5 + 5Na → Nb + 5NaCl
Theextractingandreningprocessesforniobiumfromore are extremely complex and consist of a series of operations, starting from upgrading the ores by concentration. Disruption of the niobium-containing matrix is then performed by an ore-opening procedure with hot HF or fusion with alkali uxes. The next steps include pure niobium compound preparation and reduction to metallic niobium, followed by rening, consolidation, and fabrication of the metal. Niobium is so closely associated with tantalum that they must be separated by fractional crystallization or by solvent extraction before purication.
Computer and electronic product manufacturing|Niobium: ACTIVE
Computed Properties
Molecular Weight:92.90637
Exact Mass:92.90637
Monoisotopic Mass:92.90637
Heavy Atom Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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Niobium oxide (NbO)
12034-57-0
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Lead niobium oxide (PbNb2O6)
12034-88-7
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Niobium potassium oxide (NbKO3)
12030-85-2
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Niobium strontium oxide (Nb2SrO6) Formula
12034-89-8
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Cadmium niobium oxide (Cd2Nb2O7) Formula
12187-14-3
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Manganese niobium oxide (MnNb2O6) Formula
12032-69-8
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Niobium chloride oxide (NbCl3O), (T-4)- Structure
13597-20-1
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Niobium hydroxide Structure
12710-38-2
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What is Niobium potassium oxide
54413-02-4
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What is Barium niobium sodium oxide (Ba2Nb5NaO15)
12323-03-4