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Home > Encyclopedia > 2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3)

2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3)

2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3) structure

2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3) 

structure
  • CAS No:

    2429-73-4

  • Formula:

    C32H24N6O11S3.3Na

  • Chemical Name:

    2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3)

  • Synonyms:

    2,7-Naphthalenedisulfonic acid,5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-,sodium salt (1:3);C.I. Direct Blue 2,trisodium salt;Direct Diazo Black S;C.I. Direct Blue 2;2,7-Naphthalenedisulfonic acid,5-amino-3-[[4′-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo][1,1′-biphenyl]-4-yl]azo]-4-hydroxy-,trisodium salt;C.I. 22590;Airedale Black BHD;Aizen Direct Black BH;Altazine Black BH;Amanil Developed Black BHSW;Atul Developed Black BT;Azine Diazo Black BHK;Azocard Blue BH;Azomine Black BH;Belamine Diazo Black BH;Bencidal Navy Blue BH;Benzanil Black BH;Benzo Black Blue BH;Benzo Black Blue FBH;Blue BH;Brasilazol Black BH;Calcoloid Diazo Black BHL;Calcomine Diazo Black BHD;Calcomine Diazo Black BTCW;Chloramine Black BH;Chlorazol Black BH;Chlorazol Leather Black BH;Chrome Leather Black BH;Chrome Leather Black CR;Chrome Leather Black DS;Chrome Leather Dark Blue BHM;Cutamin Dark Blue CB;Diacotton Black BH;Diamine Black BH;Diamine Black BHM;Diaminogene Velour Black B;Dianil Dark Blue H;Diaphtamine Black BH;Diazine Black H;Diazine Black BHC;Diazine Black HDW;Diazine Black HNJ;Diazo Black BH;Diazo Black BHN-CF;Diazo Black BHSW;Diazo Black BHSWK;Diazo Black CR;Diazo Direct Black N;Diazo Fast Black BH;Diazo Fast Black MBH;Diazol Black BH;Diazo Navy Blue BH;Diazophenyl Black BH;Diphenyl Blue Black GHS;Diphenyl Blue Black MBH;52350-22-8

Description

Direct blue 2 is a dark blue-black powder. (NTP, 1992)


Direct blue 2 is a dark blue-black powder. (NTP, 1992)

2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3) Basic Attributes

830.70700

830.01200

219-384-8

EE5HVP9RA8

DTXSID6025191

Characteristics

338.68000

10.18350

Direct blue 2 is a dark blue-black powder. (NTP, 1992)

1.791

10 to 50 mg/mL at 64° F (NTP, 1992)

Azo dyes can be explosive when suspended in air at specific concentrations. Water soluble.

Azo, Diazo, Azido, Hydrazine, and Azide Compounds

Explosive

DIRECT BLUE 2 is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Safety Information

QJ6158000

Flash point data for this chemical are not available, but it is probably combustible. (NTP, 1992)

|Warning|H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]|P264, P280, P305+P351+P338, and P337+P313|The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.|Danger|H350: May cause cancer [Danger Carcinogenicity]|P201, P202, P281, P308+P313, P405, and P501

Fires involving this compound should be controlled with a dry chemical, carbon dioxide or halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4′-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1′-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3) Use and Manufacturing

Methods of Manufacturing

DIAZOTIZATION & COUPLING OF BENZIDINE WITH 8-AMINO-1-NAPHTHOL-3,6-DISULFONIC ACID, THEN COUPLING WITH 7-AMINO-1-NAPHTHOL-3-SULFONIC ACID

Uses

DYE FOR CELLULOSE FIBERS, LEATHER AND PAPER

Production

(1977) PROBABLY GREATER THAN 4.54X10+6 GRAMS|(1978) 9.92X10+7 GRAMS

ESSENTIALLY 100% AS A DYE

2,7-Naphthalenedisulfonic acid, 5-amino-3-[2-[4'-[2-(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)diazenyl][1,1'-biphenyl]-4-yl]diazenyl]-4-hydroxy-, sodium salt (1:3): ACTIVE|S - indicates a substance that is identified in a final Significant New Use Rule.|SOL DYE TAKEN UP DIRECTLY BY FIBERS, PRESUMABLY DUE TO SELECTIVE ADSORPTION. USUALLY APPLIED TO COTTON OR UNION GOODS (COTTON-WOOL MIXT). DYEING ASSISTANTS SUCH AS SODIUM CHLORIDE OR SODIUM SULFATE ARE USED TO OBTAIN HIGHER CONCN OF DYE ON FIBERS. /DIRECT DYE/

Computed Properties

Molecular Weight:830.7
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:17
Rotatable Bond Count:5
Exact Mass:830.01235187
Monoisotopic Mass:830.01235187
Topological Polar Surface Area:339
Heavy Atom Count:55
Complexity:1590
Covalently-Bonded Unit Count:4
Compound Is Canonicalized:Yes

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