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Zinc carbonate

Zinc carbonate structure

Zinc carbonate 

structure
  • CAS No:

    3486-35-9

  • Formula:

    CH2O3.Zn

  • Chemical Name:

    Zinc carbonate

  • Synonyms:

    Carbonic acid,zinc salt (1:1);Zinc carbonate;C.I. 77950;Zinc carbonate (ZnCO3);Zinc carbonate (1:1);Zinc monocarbonate;Zinc Oxide Transparent;Bayoxide Z Transparent;Transparent Zinc White;2222270-46-2

  • Categories:

    Cosmetic Ingredient  >  Opacifying

Description

White, crystalline powder. Evolves carbon dioxide at 300C. Soluble in acids, alkalies, and ammonium salt solutions; insoluble in water. Smithsonite is zinc carbonate, ZnCO3, a hexagonal mineral with a rhombohedral cleavage. It is a brittle mineral; hardness, 4–4.5; specific gravity, 4.3–4.5; luster, vitreous to dull; color, usually white, but may be colored yellowish or brownish or perhaps blue or green due to impurities. It is translucent to opaque.


Zinc carbonate appears as a white crystalline solid or powder that is insoluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Used in pharmaceuticals, to make other zinc compounds, as a feed additive.|DryPowder; OtherSolid


Zinc carbonate appears as a white crystalline solid or powder that is insoluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Used in pharmaceuticals, to make other zinc compounds, as a feed additive.

Zinc carbonate Basic Attributes

566.97700

559.64200

222-477-6

K8290PTQ4F

9157

DTXSID5049817

WHITE RHOMBIC CRYSTALS|WHITE, CRYSTALLINE POWDER|RHOMBOHEDRAL STRUCTURE

2836999000

Characteristics

214.51000

-5.52010

Zinc carbonate appears as a white crystalline solid or powder that is insoluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Used in pharmaceuticals, to make other zinc compounds, as a feed additive.

4.4 g/cm3

Loses CO 2 at 572° F = 300° F = 573.2° F (USCG, 1999)

333.6ºC at 760 mmHg

169.8ºC

INDEX OF REFRACTION: 1.818, 1.618

Insol in alcohol

Store in a cool, dry place. Keep containers tightly closed.

Odorless

EVOLVES CARBON DIOXIDE AT 300 °C|Sinks in water

Insoluble in water.

Carbonate Salts

ZINC CARBONATE reacts with acids to generate carbon dioxide and a zinc-containing solution. Dissolves in bases and in solutions of ammonium salts.

Not flammable (USCG, 1999)

Safety Information

9.2

9157

1

S24/25

Stable. Incompatible with acids.

P273, P391, P501

H400

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Trace minerals added to animal feeds as nutritional dietary supplements are generally recognized as safe when added at levels consistent with good feeding practice. Zinc carbonate is included on this list.

Zinc and Health. Current Bibliographies in Medicine 98-3. Public Services Division/National Library of Medicine. 3619 citations, January, 1990-June, 1998. Available from: http://www.nlm.nih.gov/archive/20040831/pubs/cbm/zinc.html as of November 2, 1998.|USEPA; Ambient Water Quality Criteria Doc: Zinc (1980) EPA 400/5-80-079|USEPA; Ambient Water Quality Criteria Doc: Zinc (1987) EPA 400/5-87-003|Arvidson, B. A Review of Axonal Transport of Metals. Toxicology 88: 1-14 (19994) Recent findings regarding axonal transport of metals, including zinc.|For more Special Reports (Complete) data for ZINC CARBONATE (6 total), please visit the HSDB record page.

Behavior in Fire: Could decompose to liberate CO 2 (USCG, 1999)

|Warning|H400 (85.33%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]|P273, P391, and P501|Aggregated GHS information provided by 262 companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 1000 lb or 454 kg. The toll free number of the NRC is (800) 424-8802; In the Washington D.C. metropolitan area (202) 426-2675. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).

Toxicity

The effects of Eimeria acervulina infection (duodenal coccidiosis) on cadmium toxicity and zinc status in the young chick /were evaluated/. Additions of cadmium (45 mg/kg) were made to diets that contained either 0 or 52 mg/kg supplemental zinc (from zinc carbonate). Growth and efficiency of feed utilization were reduced by dietary cadmium addition while concurrent coccidial infection reduced these parameters further. Addition of cadmium also increased cadmium content of liver and kidney and depressed hemoglobin, hematocrit, and plasma zinc content. Coccidial infection exacerbated tissue cadmium deposition and depressed hematological parameters further. Although dietary zinc addition ameliorated some of the adverse effects of cadmium toxicity, cadium administration tended to enhance tissue zinc deposition.

OCCURS AS THE MINERALS SMITHSONITE AND ZINCSPAR.

Drug Information

MEDICATION (VET): ASTRINGENT, ANTISEPTIC, PROTECTIVE (TOPICAL). ALSO USED IN RATIONS TO PREVENT ZINC DEFICIENCY DISEASES.|MEDICATION (VET): Zinc carbonate is used as a dietary supplement for farm animals.|Astringent, topical antiseptic.

The effects of different amounts of dietary zinc on the zinc absorption rate and on zinc, calcium and magnesium concn in tissues of MOPC104E tumor bearing Balb/c female mice were determined. Three groups of 7 mice each (each mouse inoculated with approx 1.25 million MOPC104E cells) were given one of three experimental diets containing adequate amounts of zinc (40 ug zinc/g), a zinc deficient diet (1.0 ug zinc/g), or a zinc excess diet (1 mg zinc/g). A group of 7 nontumor bearing mice was fed laboratory mice chow as a control. The zinc deficient diet contained 37.5 ug zinc/g. For the zinc adequate diet, 71.0 mg zinc carbonate/kg diet was added to the zinc deficient diet. For the zinc excess diet 1917.9 mg zinc carbonate/kg diet was added. After 14 days on the special diets, mice were given an intragastric dose of a 200 ul solution containing 0.37 MBq (65)zinc (specific activity: 37 MBq/mg). (65)Zn was determined in various organs by gamma counting. Another set of 28 mice were placed in the same experimental conditions as described above. After anesthesia with nembutal injection, each organ was analyzed for concn of zinc, calcium, and magnesium by atomic absorption spectrophotometry. The zinc absorption rate was inversely related to the amounts of zinc in the diet and was lower than that of nontumor bearing control mice fed a laboratory mice chow. Zinc concn of tumor bearing mice were also low compared with control mice but tumor zinc concn, regardless of the concn of zinc in the diets, were higher than those of normal tissues of the host other than the pancreas.

CADMIUM IS A MINOR CONSTITUENT OF SMITHSONITE.

INHALATION OF DUST OR FUMES: Dry throat, cough and chest discomfort. Fever and sweating. SKIN: Astringent. INGESTION: May cause nausea and vomiting. (USCG, 1999)

Call a physican. INGESTION: Dilute with water or milk and remove by gastric lavage. To relieve irritation administer demulcents. (USCG, 1999)

zinc carbonate

Zinc carbonate Use and Manufacturing

Methods of Manufacturing

GRINDING THE MINERAL SMITHSONITE; ACTION OF SODIUM BICARBONATE ON SOLN OF A ZINC SALT.

Uses

As fire-proofing filler for rubber & plastic compositions exposed to flame temperature, in cosmetics & lotions, manufacture zinc salts, as feed additive, topical antiseptic.


Process regulators


Adhesives and sealants

Production

25,000 - 100,000 lb

Adhesive manufacturing|Carbonic acid, zinc salt (1:1): ACTIVE

Cosmetics -> Opacifying

Computed Properties

Molecular Weight:125.4
Hydrogen Bond Acceptor Count:3
Exact Mass:123.913886
Monoisotopic Mass:123.913886
Topological Polar Surface Area:63.2
Heavy Atom Count:5
Complexity:18.8
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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