Sucrose

342.3

342.30

90825

200-334-9

C151H8M554

1507

DTXSID2021288

Monoclinic sphenoidal crystals, crystalline masses, blocks, or powder|Hard, white ... crystals, lumps, or powder ...

17019910

190

-3.7

White Liquid

1.5805 g/cm³ @ Temp: 17 °C

185.5 °C

Decomposes

375.4±31.5 °C

1.656

H2O: 1970 g/L (15 ºC)

Store at RT.

0 mmHg (approx)

LD50 orally in Rabbit: 29700 mg/kg

Noncombustible Solid, but fine airborne dust may explode.

67 º (c=26, in water 25 ºC)

Characteristic caramel

Sweet

Soln are neutral to litmus

12.6None

12.6|pKa= 12.62

174 Ų [M+Na]+ [CCS Type: DT, Method: single field calibrated with Agilent tune mix (Agilent)]|173.93 Ų [M+Na]+ [CCS Type: DT, Method: stepped-field]|168.47 Ų [M-H]- [CCS Type: DT, Method: stepped-field]|170 Ų [M+Na]+ [CCS Type: TW, Method: calibrated with polyalanine]|175.4 Ų [M+K]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|173.9 Ų [M+Na]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|168.2 Ų [M-H]- [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|168.2 Ų [M-H]-

Decomp @ 160-186 °C; does not reduce Fehling's soln, form osazone, or show mutarotation; hydrolyzed to glucose and fructose by dil acids and by invertase, a yeast enzyme; upon hydrolysis optical rotation falls and is negative when hydrolysis is complete.|Surface tension of aqueous solution (0.1-0.6 mol/l) = 71-75 mN/m|Enthalpy of formation = 86 cal/mol-deg K

Water soluble. Sugar dust explosion is possibility.

Alcohols and Polyols

SUCROSE is a reducing agent. Can react explosively with oxidizing agents such as chlorates and perchlorates. Is hydrolyzed by dilute acids and by invertase (a yeast enzyme) (NTP, 1992). Chars rapidly and exothermically when mixed with concentrated sulfuric acid.

-1.35X10+6 cal/mol

Noncombustible Solid, but fine airborne dust may explode.

Dust explosion possible if in powder or granular form, mixed with air.

NONH for all modes of transport

2

36/37/38

24/25-37/39-26

WN6500000

Xi

Separated from strong oxidants.

Stable. Combustible. Incompatible with strong oxidizing agents. Hydrolyzed by dilute acids and by invertase.

P260, P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P312, P304+P340, P311, P312, P314, P321, P322, P330, P332+P313, P361, P362, P363, P391, P403+P233, P405, P501

H302

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Oxidizers, sulfuric acid, nitric acid.

Substance added directly to human food affirmed as generally recognized as safe (GRAS).

INFORMATICS INC; SCIENTIFIC LITERATURE REVIEWS ON GENERALLY RECOGNIZED AS SAFE (GRAS) FOOD INGREDIENTS: SUCROSE; US NTIS PB REPORT PB-228 548, 202 PP. (1973). LITERATURE REVIEW OF SUCROSE AND ITS USE IN FOOD PRODUCTS.

Special Hazards of Combustion Products: Irritating fumes may form in fires. Behavior in Fire: Melts and chars (USCG, 1999)|Combustible. Finely dispersed particles form explosive mixtures in air.

Not Classified

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material under ambient temperatures. (NTP, 1992)

Skin: No recommendation is made specifying the need for personal protective equipment for the body. Eyes: No recommendation is made specifying the need for eye protection. Wash skin: No recommendation is made specifying the need for washing the substance from the skin (either immediately or at the end of the work shift). Remove: No recommendation is made specifying the need for removing clothing that becomes wet or contaminated. Change: No recommendation is made specifying the need for the worker to change clothing after the work shift. (NIOSH, 2016)|/NIOSH approved respirator/ and goggles or face shield.|(See protection codes)

Water

Irritating fumes may form in fires.

Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 15 mg/cu m. /Total dust/|Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 5 mg/cu m. /Respirable fraction/

Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 10 mg/cu m (total).|Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m (resp).

Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.

Separated from strong oxidants.

May cause mechanical irritation.

The substance may have effects on the teeth. This may result in dental caries. Repeated or prolonged contact with skin may cause dermatitis.

NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust.

Use local exhaust or breathing protection.

Protective gloves.

Wear safety goggles.

LD50 Rat oral 29,700 mg/kg

Patients with severe malabsorption secondary to disease or resection ... may have deficiency of other disaccharidases and large amounts of sucrose should be avoided /in enteral formulations/.

Occurs in low percentages in honey and maple sap|Sugar cane contains from 15-20% and sugar beet from 10-17% sucrose|The quantity of sucrose synthesized by all plants on earth is estimated to be 150X10+9 t/a.

MEDICATION (VET): ITS ORAL USE IN ACETONEMIA OF CATTLE IS CONTROVERSIAL BUT STILL POPULAR. IT IS OFTEN USED ORALLY WITH VINEGAR...IN EMERGENCY TREATMENT OF ACUTE UREA TOXICITY IN CATTLE. DAILY ORAL USE CAN OCCASIONALLY REDUCE INCIDENCE OF BLOAT IN CATTLE ON SPRING PASTURE LOW IN CARBOHYDRATES.|MEDICATION (VET): 20% ORAL SOLN CAUSE REFLEX CLOSURE OF ESOPHAGEAL GROOVE. ... SUGAR IS OCCASIONALLY USED...TO FACILITATE REDN OF EDEMA & EASE OF REPLACEMENT OF PROLAPSED UTERI IN COWS, EWES, BITCHES, ETC, & HAS BEEN USED LOCALLY ON WOUNDS, FOOT ROT, ETC BY LAYMEN & PROFESSIONALS.|IV ADMIN OF HYPERTONIC SOLN OF SUCROSE HAS BEEN EMPLOYED CHIEFLY TO INITIATE OSMOTIC DIURESIS. SUCH PROCEDURE IS NOT COMPLETELY SAFE & RENAL TUBULAR DAMAGE MAY RESULT, PARTICULARLY IN PATIENTS WITH EXISTING RENAL PATHOLOGY. SAFER & MORE EFFECTIVE DIURETICS ARE AVAILABLE. /FORMER USE/

VET: ORAL ADMIN TO YOUNG ANIMALS UNABLE TO DIGEST IT WILL CAUSE OR ACCENT DIARRHEAS.

1. 1= PRACTICALLY NONTOXIC: PROBABLE ORAL LETHAL DOSE (HUMAN) ABOVE 15 G/KG, MORE THAN 1 QUART (2.2 LB) FOR 70 KG PERSON (150 LB).

Substances that sweeten food, beverages, medications, etc., such as sugar, saccharine or other low-calorie synthetic products. (From Random House Unabridged Dictionary, 2d ed) (See all compounds classified as Sweetening Agents.)

None (USCG, 1999)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. If symptoms (such as redness or irritation) develop, immediately transport the victim to a hospital. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)|(See procedures)

Fresh air, rest.

Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Liquid medicines, particularly those intended for children, often formulated as syrups, usually based on sucrose. Total sugar content may be up to 80% (w/v). Complicated diabetes management. Increased dental caries especially in chronically sick children (eg, asthmatics or epileptics) who frequently take liquid medicine.|Sucrose is reported to be capable of producing dermatoses in bakers, candy makers, and related occupations. It is well established that uncontrolled glucose conc in maternal blood are associated with elevated embryonic and fetal death and increased neonatal morbidity and mortality.

Saccharose

The substance can be absorbed into the body by inhalation and by ingestion.|inhalation, skin and/or eye contact

irritation eyes, skin, upper respiratory system; cough

Cough.

Redness. Roughness.

Redness.

Eyes, respiratory system

(DELIVERIES OF REFINED SUGAR): 35% WAS CONSUMED DIRECTLY FOR SWEETENING FOODS & BEVERAGES; THE REMAINING 65% WAS USED INDUSTRIALLY IN BEVERAGES (22%); IN BAKERY & CEREAL PRODUCTS (12%); IN CONFECTIONS (9%); IN CANNED, BOTTLED, & FROZEN FOODS (6%); IN ICE CREAM & DAIRY PRODUCTS (5%); IN MISC FOODS (5%); & IN NON-FOOD & UNSPECIFIED USES (6%) (1976)

USEPA/OPP Pesticide Code 000023; Trade Names: None.|Grade: Reagent, USP, technical, refined.|Also sold as syrup .. liquid sugar

Furniture and related product manufacturing|.alpha.-D-Glucopyranoside, .beta.-D-fructofuranosyl: ACTIVE|CARBOHYDRATE (QV) PRODUCT OF PHOTOSYNTHESIS COMPRISED OF 1, 2, OR MORE SACCHAROSE GROUPS. ... SUGAR IS IMPORTANT SOURCE OF METABOLIC ENERGY IN FOODS, & ITS FORMATION IN PLANTS IS ESSENTIAL FACTOR IN LIFE PROCESS.|Sucrose is the most important industrial sugar|Sucrose was first synthesized enzymatically in the laboratory from potassium D-glucosyl-1-phosphate and D-fructose. The first chemical synthesis was accomplished by reaction of 3,4,6-tri-O-acetyl-1,2-anhydro-alpha-D-glucopyranose with 1,3,4,6-tetra-O-acetyl-D-fructofuranose|Traditionally, the standard /sweetening agent/ is sucrose, both in terms of quality of taste and taste profile|For more General Manufacturing Information (Complete) data for SUCROSE (6 total), please visit the HSDB record page.

SUGARS & SUGAR PRODUCTS BY POLARIMETRIC METHODS.|DETERMINATION IN FOODSTUFF BY SPECTROPHOTMETRY @ 340, 334, OR 365 NM.

EPA Safer Chemical Functional Use Classes -> Processing Aids and Additives|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern|Cosmetics -> Humectant; Skin conditioning; Soothing