L-tryptophan 73-22-3

L-Tryptophan

L-Tryptophan;Tryptophan,L-;l-β-3-Indolylalanine;Tryptophane;Tryptophan;L-Tryptophane;1H-Indole-3-propanoic acid,α-amino-,(S)-;L-(-)-Tryptophan;l-α-Aminoindole-3-propionic acid;2-Amino-3-indolylpropanoic acid;(S)-α-Aminoindole-3-propionic acid;(-)-Tryptophan;1H-Indole-3-alanine,(S)-;EH 121;(S)-Tryptophan;(S)-α-Amino-1H-indole-3-propanoic acid;(S)-α-Amino-β-indolepropionic acid;3-Indol-3-ylalanine;L-Alanine,3-(1H-indol-3-yl)-;Lyphan;NSC 13119;(2S)-2-Amino-3-(1H-indol-3-yl)propanoic acid;(S)-2-Amino-3-(1H-indol-3-yl)propanoic acid;(2S)-2-Amino-3-(1H-indol-3-yl)propanoic acid;(2S)-2-Azaniumyl-3-(1H-indol-3-yl)propanoate;6912-86-3;80206-30-0;154635-35-5;2416148-24-6

73-22-3

C11H12N2O2

InChIKey=QIVBCDIJIAJPQS-VIFPVBQESA-N

204.22500

204.23

200-795-6

8DUH1N11BX

757373

DTXSID5021419

C29603

Leaflets or plates from dilute alcohol|White to slightly yellowish-white ... crystals or crystalline powder

N - Nervous system

2933990090

Bulk Drug Intermediates

79.11000

-1.1

L-tryptophan is a white powder with a flat taste. An essential amino acid; occurs in isomeric forms. (NTP, 1992)

1.4±0.1 g/cm3

282 °C

447.9°C at 760 mmHg

224.7±25.9 °C

1.698

H2O: 13.4 mg/mL at 25 °C

Protect from light

2.1X10-9 mm Hg at 25 deg C (est)

LD508mmol / kg (rat, intraperitoneal injection). It is safe when used in food (FDA, §172.320, 2000).

Specific optical rotation: -31.5 deg at 23 °C/D (water, 1%), +2.4 deg at 20 °C/D (hydrochloric acid, 0.5 N); +0.15 deg at 20 °C/D (sodium hydroxide, 2.43% in 0.5 N)

Odorless

FLAT TASTE

A 1% solution in water has a pH of 5.5 to 7.

7.38(at 25 °C)

7.38 (at 25 °C)|pK1 = 2.38 /SRC: carboxylic acid/; pK2 = 9.39 /SRC: primary amine/

154.22 Ų [M+H]+ [CCS Type: DT, Method: stepped-field]|158.58 Ų [M-H]- [CCS Type: DT, Method: stepped-field]|145 Ų [M+H]+ [CCS Type: TW, Method: calibrated with polyalanine]|150.1 Ų [M+H]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|150.3 Ų [M+H]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|147.6 Ų [M+Na]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|147.7 Ų [M+Na]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|142.3 Ų [M-H]- [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|142.5 Ų [M-H]- [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|151.5 Ų [M-H]- [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|149.1 Ų [M-H]-

Decomposes at 289 °C (rapid heating)|Needles from methanol, decomposes at 251 °C /Tryptophan hydrochloride/|UV: 3453 (Sadtler Research Laboratories Spectral Collection) /Tryptophan (DL)/

Slightly soluble in water.

Salts, Acidic

Acidic salts, such as L-TRYPTOPHAN, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.