Section 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
1.1 Product name：CHLORPHENESIN
CAS No.:104-29-0
Formula:C9H11ClO3
1.2. Recommended uses
Chlorphenesin is a preservative, widely used in cosmetics.
1.3 Supplier's details
EAST CHEMSOURCES LIMITED
NO.666 HAIBIN 12TH ROAD, HUANGDAO, QINGDAO, CHINA
Emergency phone number: 0532-81906761
Section 2 HAZARDS IDENTIFICATION
2.1 Overview of emergency situations
Causes skin irritation. Causes severe eye irritation.
2.1 GHS Risk category
Skin Corrosion/irritation category 2
Serious eye injury/eye irritation category 2
2.2 Label elements
2.2.1 Image
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2.2.2 Signal word: Warning
2.3Hazard description:
H315 causes skin irritation
H319 causes severe eye irritation
2.4 Precautions
● preventive measures:
-P264clean thoroughly after operation.
- P270do not eat, drink or smoke while using this product.
- P261to avoid inhalation of dust/smoke/gas/smoke/Vapour/mist.
-P271 they should only be used outdoors or in well-ventilated places.
● Incident Response:
-P302+P352if skin is contaminated, wash thoroughly with water.
- P332+P313in case of skin irritation: seek medical attention.
-P362+P364 remove soiled clothing and wash before reuse
-P305+P351+P338 if it enters the eye, rinse gently with water for a few minutes. If wearing contact lens and can be easily removed, remove contact lens. Keep Flushing.
- P337+P313 if eye irritation was still present, seek medical attention/seek medical attention.
-P304+P340If inhaled: people will be moved to fresh air, keep breathing comfortable position.
-P312If you feel unwell, call a doctor at the detoxification centre
●Safe storage:
-P403 + P233 in a well-ventilated place. Keep the container closed.
- P405 storage area should be locked.
● waste disposal:
-P501 disposal of contents/containers in accordance with local regulations.
Physical and chemical hazards: no information.
Health hazards: causing skin irritation. Causing severe eye irritation.
Environmental Hazards: no data.
Section 3 COMPOSITION/INFORMAT1ON ON INGREDIENTS
Check the substance, the mixture
Dangerous components | A concentration or range of concentrations | CAS No. |
CHLORPHENESIN | 100%
| 104-29-0 |
Section 4 FIRST AID MEASURES
First aid:
inhalation: if inhaled, move the patient to fresh air.
Skin contact: remove contaminated clothing and rinse skin thoroughly with soap and water. Seek medical advice if feeling unwell.
Eye contact: separate eyelids and rinse with running water or normal saline. Seek medical advice if feeling unwell. Food Intake: drinking water, do not induce vomiting. Seek medical advice if feeling unwell.
Advice for the protection of rescuers: move the patient to a safe place. Consult a doctor. Show this chemical safety technical specification to the doctor on site.
Special note for doctors: no information.
Section 5 FIREFIGHTING MEASURES
Extinguishing agent:
extinguish fire with water mist, dry powder, foam or carbon dioxide extinguishing agent. Avoid using direct current water to extinguish a fire.
Direct current water may cause the flammable liquid to splash and spread the fire.
Special Danger: no data.
Fire fighting precautions and protective measures:
Firemen should wear portable breathing apparatus and full-body fire fighting clothing to put out fire in the upwind direction. Move the container from the fire to an open area as far as possible. If the container in the fire has changed color or made a sound from the safety pressure relief device, it must be evacuated immediately. Isolate the scene of the accident and forbid the irrelevant people to enter.
Receive and treat fire water to prevent pollution of the environment.
Section 6EMERGENCY HANDING OF LEAKAGE
Workers protective measures, protective equipment and emergency procedures: emergency personnel are advised to wear air-breathing apparatus, wear anti-static clothing, wear rubber oil-resistant gloves.
Do not touch or cross the spill. All equipment used during the operation should be grounded. Cut off the source of the leak as much as possible. Eliminate all ignition sources. According to the liquid flow, steam or dust diffusion of the impact of the area designated Warning Zone, irrelevant personnel from the crosswind, the windward direction to evacuate to the safety zone. Environmental protection measures: containment of leakage, to avoid pollution of the environment. Prevent leakage into sewers, surface water and groundwater.
Containment, removal, and disposal materials used for leaking chemicals: small leakage: as far as possible, the leakage of liquid collected in an airtight container. Absorb with sand, activated carbon or other inert materials and transfer to a safe place. No flushing into the sewers.
Mass leakage: building an embankment or digging a pit for shelter. Seal the drain. Cover with foam to suppress evaporation. Use explosion-proof pump to transfer to tank or special collector, recovery or delivery to the waste disposal site for disposal.
Section 7 OPERATIONAL HANDING AND STORAGE OPEOPER
Operating Precautions:
operators should be specially trained to strictly abide by the operating procedures. The operation should be carried out in a place with local ventilation or full ventilation. Avoid eye-to-skin contact and inhalation of steam.
See section 8 for individual protective measures. Keep away from fire and heat source, smoking is strictly prohibited in the workplace. Use explosion-proof ventilation systems and equipment. If Canning is required, the flow rate should be controlled and grounded to prevent the accumulation of static electricity. Avoid contact with forbidden ligands such as oxidants (see part 10 for forbidden ligands) . When handling to light loading and unloading, to prevent packaging and container damage. Emptied containers may leave harmful residues. Wash hands after use and do not eat or drink in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment.
Storage notes: store in a cool, ventilated warehouse. The temperature should not exceed 37 °C. Should be stored separately from oxidants, food chemicals, avoid mixing (see part 10 for banned compounds) . Keep the container sealed. Keep away from fire and heat.
Lightning protection equipment must be installed in the storeroom.
The ventilation system shall be provided with a grounding device for removing static electricity. Explosion-proof lighting and ventilation are adopted. Do not use sparking equipment or tools. The storage area shall be equipped with leak emergency treatment equipment and appropriate storage materials.
Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational exposure limits.
No information.
Biological limits
No information.
Monitoring methods
GBZ/T160.1 ~ GBZ/T160.81 -2004 workplace air toxic substances determination (series standards) .
Engineering Control: the work site is recommended to be separated from other work sites. Airtight operation to prevent leakage. Enhance ventilation. Set up automatic alarm device and accident ventilation facilities. Set up emergency evacuation routes and necessary evacuation areas. Set Red area warning line, warning logo and Chinese warning description, and set up communication alarm system. Provide a safe shower and eye wash. Respiratory System protection: when the concentration in the air exceeds the standard, wear filter gas mask (half mask) . During emergency rescue or evacuation, you should wear an air-breathing apparatus.
Hand protection: wear rubber oil-resistant gloves.
Eye Protection: wear chemical safety eye protection.
Skin and body protection: wear protective clothing to prevent the penetration of toxic substances.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance | White to grayish white crystalline powder |
PH value (indicating concentration) |
No information
|
Boiling Point, initial boiling point and boiling range (° C) | 369.5 |
Relative vapor density (air = 1) | No information
|
Saturated vapor pressure (kPa) | No information
|
Evaporation rate | No information
|
Flash Point (° C) | 177.2 |
Decomposition temperature (° C) | No information
|
Odor:
| No information
|
Melting/freezing point (° C) :
| 77-79 |
odor threshold | No information
|
Relative density (water = 1) | 1.317 |
viscosity (mm2 s) | No information
|
N-octanol water partition coefficient: | No information
|
Ignition temperature (° C)
| No information
|
Section 10 STABILITY AND REACTIVITY
Stability: under the normal environment temperature storage and use, this product is stable.
Hazard reaction: no information.
Avoid contact conditions: electrostatic discharge, heat, moisture, etc. .
Forbidden Ligand: no data.
Dangerous breakdown products: no data.
Section 11 TOXICOLOGICAL INFORMATION
Acute toxicity: no data. Carcinogenicity: no data.
Skin irritant or corrosive: does not meet classification criteria based on available data.
Eye irritation or corrosion: does not meet classification criteria based on available data.
Skin sensitization: according to the available information, does not meet the classification criteria.
Respiratory sensitization: according to the available data, does not meet the classification criteria.
Germ cell mutagenicity: based on the available data, it does not meet the classification criteria.
Reproductive toxicity: does not meet classification criteria based on available data.
Specific target organ system toxicity-one contact may: does not meet classification criteria based on available data. Specific target organ system toxicity-repeated exposure: does not meet classification criteria based on available data.
Inhalation hazards: according to the available information, does not meet the classification criteria.
Section 12 ECOLOGICAL INFORMATION
Acute aquatic toxicity: no data.
Chronic aquatic toxicity: no data.
Persistence and degradation: no data.
Potential bioaccumulation: no data.
Mobility in soil: no data.
Other harmful effects: no data.
Section 13 DISPOSAL CONSIDERATIONS
13.1Waste disposal method
Waste Chemicals:
Recycle as much as possible. If recycling is not possible, incineration is used for disposal. This product shall not be disposed of by discharge into the sewers. Contaminated packaging: return the container to the manufacturer or dispose of it in accordance with national and local regulations.
Notice of abandonment: before disposal, should refer to the relevant national and local laws and regulations. See Part 8 for safety precautions for handling personnel.
Section 14 TRANSPORT INFORMATION
UN Dangerous Goods Code (UN） : non-dangerous goods.
United Nations transport name: non-dangerous goods.
United Nations classification of hazards: non-dangerous goods. Packing type: non-dangerous goods.
Packaging label: Marine contaminants (yes/No) : No.
Packing method according to the method recommended by the manufacturer, for example: open steel drum. Ampoule outside the ordinary wooden box. Screw mouth glass bottles, iron cap pressure mouth glass bottles, plastic bottles or metal drums (cans) outside the ordinary wooden box. The transport vehicles should be equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly prohibited to mix with oxidants, edible chemicals, etc. .
The exhaust pipe of the vehicle in which the article is to be shipped shall be fitted with a fire arrester. When the tank truck is used for transportation, there should be a grounding chain, and a perforated partition board can be arranged in the tank to reduce the vibration and produce static electricity. It is forbidden to use mechanical equipment and tools that are liable to spark. It's best to ship early and late in summer. Transportation should be protected against the sun, rain, high temperature. Stopover should be far away from the fire, heat source, high temperature zone. When transporting goods by road, please follow the prescribed route and do not stay in residential areas or densely populated areas. It is forbidden to slip in railway transportation. It is strictly prohibited to transport in bulk by wooden ship or cement ship. Danger Signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements.
Section 15 REGULATORY INFORMATION
List of chemicals management in China
Components | A | B | C | D | E | F | G | H |
CHLORPHENESIN
| Not included | Not included | Not included | Not included | Not included | Not included | Not included | Not included |
[ A ] catalogue of Hazardous Chemicals (2015 edition) , Circular No. 5 of 2015 of the State Administration of safety and supervision
[ B ] list of hazardous chemicals under key environmental management, Ministry of Environmental Protection General Office No. 33 of 2014
[ C ] list of severely restricted hazardous chemicals in China, mEP notice No. 74 of 2017
[ D ] Catalogue of Narcotic Drugs and Psychotropic Substances (2013 edition) ,FDA Circular No. 230 of 2013
[ E ]“List of hazardous chemicals under key regulatory control (batches 1 and 2)”, circular No. 95 of 2011 and No. 12 of 2013
[ F ]“List of controlled ozone-depleting substances imported and exported to and from China (batches 1 to 6)”, ministry of Environmental Protection Announcement Series 2000-2012
[ G ]“List of dangerous chemicals liable to explode (2017 edition)”, Ministry of Public Security announcement on May 11,2017
[ H ]“List of highly toxic substances”, ministry of Health Circular No. 142 of 2003
Section 16 OTHER INFORMATION
Last revision date: 2023/03/22
revision instructions this SDS has been revised in accordance with the standards of“Contents and order of items in the technical instructions for chemical safety”(GB/T16483-2008) and“Guidelines for the preparation of technical instructions for chemical safety”(GB/T17519-2013) . The classification results of GHS for chemicals were based on the implementation guidelines for the Catalogue of Hazardous Chemicals (2015 edition) and the series of standards in the Code for classification and labelling of chemicals (GB30000.2-2013-gb3000.29-2013) .
