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Hypophosphorous acid CAS:6303-21-5

TDS 29 Inquiries

Unit Price: Get Latest Price
CAS No.:

6303-21-5

Grade:

Industrial Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25kg/bag,500kg/bag, customized

Price valid (until):

2025-12-26

Company Type:
Trader
Location:
China
Qualification:
Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

  • Product Description

  • Seller Information

  • Inquiry History

  • Description
    Hypophosphorous acid Chemical Properties
    Melting point  -25 °C
    Boiling point  108 °C (759.8513 mmHg)
    density  1.206 g/mL at 20 °C(lit.)
    vapor pressure  <17 mmHg ( 20 °C)
    storage temp.  no restrictions.
    solubility  very soluble in H2O, ethanol, ethyl ether
    pka pK1 1.1.
    form  hygroscopic crystals or colorless oily liquid
    color  Colorless
    PH pKa1= 1.00(25℃)
    Water Solubility  SOLUBLE
    Merck  13,4894
    Stability: Stable. Incompatible with strong bases. Reacts violently with oxidizing agents, strong bases, mercury (II) nitrate and mercury (II) oxide. Do not heat above 100 C.
    InChIKey GQZXNSPRSGFJLY-UHFFFAOYSA-N
    CAS DataBase Reference 6303-21-5(CAS DataBase Reference)
    NIST Chemistry Reference Hypophosphorous acid(6303-21-5)
    EPA Substance Registry System Phosphinic acid (6303-21-5)




    Hypophosphorous acid Usage And Synthesis
    Outline Hypophosphorous acid is also known as "hypophosphite" It is colorless oil or deliquescence crystal , it is an important fine chemical product. The main use is as reducing agent for electroless plating, phosphoric prevent discoloration of resins, it can also be used in the esterification reaction catalyst, the refrigerant, in particular for the production of high purity product sodium hypophosphite. There are several methods for preparation, the common industrial method for producing is ion exchange resin method and electrodialysis method.
    The chemical properties of hypophosphorous acid, uses, toxicity, and production methods are edited by andy of Chemicalbook. (2016-12-04)
    Chemical properties It is deliquescent crystals or colorless oil. Melting point: 26.5℃. The relative density (specific gravity): 1.439 (solid, 19℃). It is soluble in water, ethanol and ether, and it can be mixed in any proportion with water, ethanol, acetone. In the air, it easily deliquesce to syrupy liquid, and the aqueous solution is acidic.
    Hypophosphorous acid is monobasic acid, in aqueous solution, Hypophosphorous acid is strong acid, Ka = 10-2 (25℃); it is relatively stable at room temperature; disproportionation reaction can proceed at 130℃, decompose into phosphine and phosphorous acid:
    2H3PO2=H3PO4+PH3
    It has strong reduction, heavy metal salt solution can be restored to metals such as Cu2 +, Hg2 +, Ag +, such as:
    4Ag+H3PO2+2H2)=4Ag+H3PO4+4H+
    It is weak oxidizer, it can be reduced to phosphine, phosphine when encounters strong reducing agent.
    Uses 1. Hypophosphorous acid is used as reducing agent for electroless plating;
    2. It can be used to prevent discoloration of phosphoric acid resin;
    3. It is used as esterification catalyst, the refrigerant;
    4. It is used to produce hypophosphite, sodium salts, manganese salts, iron salts are generally used as nourishing substances;
    5. Hypophosphorous acid is used in medicine and as reducing agent, the determination of arsenic, tellurium and separation of tantalum, niobium and other reagents.
    6. It is strong reducing agent, It can be used for the preparation of sodium hypophosphite, calcium phosphate and other hypophosphite.
    7. It can be used for the plating bath. Pharmaceuticals. reducing agent. general reagents.
    8. It is strong reducing agent, it can be used in making sodium hypophosphite, calcium phosphate and other hypophosphite.
    9. This product is widely used as reducing agent, Ag, Cu, Ni, Hg and other metals are reduced to the corresponding metal, for the verification of As, Nb, Ta and other reagents, it can be used for the preparation of Na, K, Ca, Mn, Fe and other types of hypophosphite.



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    ——  Q&A  ——

    Q1:Do you provide sample?

    A: Yes, we can provide free sample, you only need pay the shipping cost.

    Q2: What is the lead time?

    A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

    Q3: How can I buy? What is the payment method?

    A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer,

    A:We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.



    Certificates

    Basic Info
    Product Name:

    Hypophosphorous acid

    Other Name:

    HYPOPHOSPHOROUSACID,30%(W/V)SOLUTION;HYPOPHOSPHOROUSACID,50%(W/V)SOLUTION;Hypophosphorus acid: (Phosphinic acid);Hypophosphorus acid, 50% w/w aq. soln.;hypophosphorous;hypophosphorousacid(corrosiveliquid,acidic,inorganic,n.o.s.);Hypophosphorousacid,50%w/waq.soln.;HYPOPHOSPHOROUS ACID SOLUTION 50% AQUEOUS

    CAS No.:

    6303-21-5

    Molecular Formula:

    HO2P

    InChIKeys:

    GQZXNSPRSGFJLY-UHFFFAOYSA-N

    Molecular Weight:

    63.980501

    Exact Mass:

    66.00

    EC Number:

    228-601-5

    TSCA:

    TSCA listed

    DSSTox ID:

    DTXSID70162386

    Color/Form:

    Colorless

    HScode:

    28111990

    Characteristics
    Physical Properties:

    Colorless deliquescent crystals or oily liquid; sour odor; density 1.493 g/cm3;melts at 26.5°C; boils at 130°C; very soluble in water, alcohol and ether; den-sity of a 50% aqueous solution is 1.13 g/mL.

    Density:

    1.206 g/mL at 20 °C(lit.)

    Melting Point:

    -25 °C

    Boiling Point:

    108 °C (759.8513 mmHg)

    Water Solubility:

    SOLUBLE

    Vapor Pressure:

    <17 mmHg ( 20 °C)

    Toxicity:

    It is non-combustible. But when contacts with the hole H agent, it will cause fire. When meets oxidizing agent, violent reaction and combustion can proceed. When it is heated to high, it can decompose into highly toxic phosphine gas, or even explode. It is corrosive. Hypophosphorous acid is often added into soft drinks, and because it is not absorbed. So the risk is small, but particularly strong hypophosphite hurt gastrointestinal. Accidentally it splashes into the eyes or contacts skin, plenty of water is used to washed. Production operators should wear protective clothing and other protective clothing. Production equipment should be sealed, workshop should be ventilated well.

    PH:

    pKa1= 1.00(25℃)

    PKA:

    pK1 1.1.

    Air and Water Reactions:

    Deliquescent. Water soluble.

    Reactivity Profile:

    HYPOPHOSPHOROUS ACID decomposes when heated into phosphoric acid and spontaneously flammable phosphine. Is oxidized by sulfuric acid with release of sulfur dioxide and sulfur. Reacts explosively with mercury(II) oxide [Mellor, 1940, Vol. 4, 778]. Reacts violently with mercury(II) nitrate [Mellor, 1940, Vol. 4, 993]. Neutralizes bases in exothermic reactions.

    Critical Temperature & Pressure:

    no restrictions.

    Hazard Identification

    Classification of the substance or mixture

    Corrosive to metals, Category 1

    Skin corrosion, Sub-category 1B

    Serious eye damage, Category 1

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H290 May be corrosive to metals

    H314 Causes severe skin burns and eye damage

    Precautionary statement(s)
    Prevention

    P234 Keep only in original packaging.

    P260 Do not breathe dust/fume/gas/mist/vapours/spray.

    P264 Wash ... thoroughly after handling.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    Response

    P390 Absorb spillage to prevent material damage.

    P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

    P363 Wash contaminated clothing before reuse.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P316 Get emergency medical help immediately.

    P321 Specific treatment (see ... on this label).

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P317 Get medical help.

    Storage

    P406 Store in a corrosion resistant/...container with a resistant inner liner.

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

  • Seller Information
    Business Type:

    Trader

    Main Products:

    pharmaceutical intermediates,peptides,electronic chemicals

    Location:

    Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

    Payment Terms:

    100% TT in advance

    Average lead Time:

    10

    Total Annual Revenue:

    $10 million-$25 million

    Total Employees:

    51-100

    Year of Establishment:

    2024

    A reliable supplier is like insurance.

    We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals,food additives, and other fine chemical products.
    Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

    Website: orientchem.cc
    Email: scarlett@orientchem.cc
    WhatsApp: +86 17753254221

  • Inquiry History
    29 Inquiries
    Country Product Purchase Quantity Date Posted
    Australia

    6303-21-5 Hypophosphorous acid

    1 MT Sep 29, 2023
    France

    Hypophosphorous acid 99% liquid 6303-21-5

    1 MT Sep 25, 2023
    New Zealand

    Hypophosphorous acid

    1 KG Mar 4, 2026
    Australia

    Hypophosphorous Acid

    100 L Feb 24, 2026
    New Zealand

    Hypophosphorous acid

    1 KG Dec 23, 2025
    Australia

    Hypophosphorous Acid H3po2 99%

    1 KG Jul 18, 2025
    New Zealand

    Hypophosphorous Acid

    1 MT Sep 18, 2024
    Australia

    Hypophosphorous acid

    500 L Sep 2, 2024
    Australia

    Hypophosphorous Acid

    1 KG Jun 6, 2024
    Australia

    Hypophosphorus Acid

    1 KG Apr 2, 2024
    Canada

    Hypophosphorous Acid

    1 KG May 18, 2026
    Australia

    hypophosphuros acid

    500 G Mar 9, 2026
    Russia

    Hypophosphorous Acid

    500 KG Mar 28, 2025
    Lithuania

    Hypophosphorous acid

    200 L Jan 11, 2025
    Australia

    Hypophosphorous acid

    1 KG Oct 14, 2024
    New Zealand

    Hypophosphorous Acid

    1 MT Sep 18, 2024
    Australia

    Hypophosphorous Acid

    20 KG Jun 14, 2024
    Australia

    Hypophosphorous Acid

    20 KG Jun 13, 2024
    Australia

    Liquid Hypophosphorous Acid 50%

    2 KG Jan 24, 2024
    New Zealand

    Hypophosphorous Acid

    1 KG Jan 12, 2024
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