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Home > Encyclopedia > Prosulfocarb

Prosulfocarb

Prosulfocarb structure

Prosulfocarb 

structure
  • CAS No:

    52888-80-9

  • Formula:

    C14H21NOS

  • Chemical Name:

    Prosulfocarb

  • Synonyms:

    Carbamothioic acid,N,N-dipropyl-,S-(phenylmethyl) ester;Carbamothioic acid,dipropyl-,S-(phenylmethyl) ester;Carbamic acid,dipropylthio-,S-benzyl ester;S-Benzyl dipropylthiocarbamate;Benzyl dipropylthiolcarbamate;S-Benzyl N,N-dipropylthiocarbamate;R 15574;S-Benzyl dipropylthiolcarbamate;SC 0574;Prosulfocarb;Boxer;Boxer (ICI Agrochemicals);Arkade;Defi;Boxer EC;Boxer 800EC;123780-41-6

  • Categories:

    Analytical Chemistry  >  Standard

Description

ChEBI: A monothiocarbamic ester that is carbamothioic S-acid substituted by two propyl groups at the nitrogen atom and a benzyl group at the the sulfur atom.


Prosulfocarb is a monothiocarbamic ester that is carbamothioic S-acid substituted by two propyl groups at the nitrogen atom and a benzyl group at the the sulfur atom. It has a role as an environmental contaminant, a xenobiotic and a herbicide. It is a member of benzenes and a monothiocarbamic ester.

Prosulfocarb Basic Attributes

251.39

251.39

401-730-6

8VCE6FU50D

3082|3077

DTXSID3058119

2930200014

Characteristics

45.6

3.99

1.0±0.1 g/cm3

<25 °C

129 °C

100 °C

1.541

5.25e-05 M

5.18e-07 mmHg

156.95 Ų [M+H]+ [CCS Type: TW]|157.93 Ų [M+H]+

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts

CARBAMOTHIOIC ACID, DIPROPYL-, S-(PHENYLMETHYL) ESTER is a thiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Safety Information

UN30829/PG3

2

22-43-51/53

24-37-61

FD3835000

Xn,N

P273-P280

H302-H317-H411

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)

|Warning|H302: Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P272, P273, P280, P301+P312, P302+P352, P321, P330, P333+P313, P363, P391, and P501|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|Aggregated GHS information provided by 147 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Aggregated GHS information provided by 198 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Danger|H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P260, P261, P264, P271, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P363, P403+P233, P405, and P501

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Do not scatter spilled material with high-pressure water streams. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal. FIRE INVOLVING TANKS: Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. Avoid inhalation of asbestos dust. SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)

Drug Information

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. (ERG, 2016)

prosulfocarb

Prosulfocarb Use and Manufacturing

Agrochemicals -> Herbicides|Herbicides|Environmental transformation -> Pesticides (parent, predecessor)

Prosulfocarb has known environmental transformation products that include prosulfocarb sulfoxide.|Prosulfocarb has known environmental transformation products that include Prosulfocarb sulfoxide.

Computed Properties

Molecular Weight:251.39
XLogP3:3.9
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:251.13438547
Monoisotopic Mass:251.13438547
Topological Polar Surface Area:45.6
Heavy Atom Count:17
Complexity:208
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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