1,3-Benzenediol, 2,4,6-trinitro-, lead(2+) salt (1:1)

450.28744

450.95302 g/mol

239-290-0

0T8SE91KOP

0130

Orange-yellow to dark brown crystalline solid

184 Ų

0.99-1.11 g/cm³

Decomposes at 235 °C

310-330 °C (590-626 °F)

Practically insoluble in most organic solvents|Practically insoluble in water

DOT Class A explosive. Initiating explosive. Keep away from fire, heat, flame, spark, static, friction, percussion. Do not store with flammable liquids, solids, gases, oxidizers, acids, corrosive liquids, non-flammable compressed gases. Storage and distribution of explosives is regulated by the U.S. Department of the Treasury, Bureau of Alcohol, Tobacco, and Firearms (BAFT). Procedural requirements are described in 25 CFR 55, "Commerce in Explosives"

Enthalpy of formation = -1785 kJ/kg; non-hygroscopic

61-3-20/22-33-50/53-62

53-45-60-61

E,T,N

It is very stable at room and elevated temperatures (eg, 75 °C) and is non-hygroscopic.

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with environmental and public health regulations.|Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Sodium hydroxide in water to alkaline pH, followed by sodium sulfide, heat to boil, hold at temperature overnight.

Incompatible with corrosive liquids.

|Danger|H200: Unstable Explosive [Danger Explosives]|P201, P202, P260, P261, P264, P270, P271, P273, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P372, P373, P380, P391, P401, P405, and P501|H201: Explosive; mass explosion hazard [Danger Explosives]|P201, P202, P210, P230, P240, P250, P260, P261, P264, P270, P271, P273, P280, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P370+P380, P372, P373, P391, P401, P405, and P501|H200 (70.45%): Unstable Explosive [Danger Explosives]|P201, P202, P210, P230, P240, P250, P260, P261, P264, P270, P271, P273, P280, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P370+P380, P372, P373, P380, P391, P401, P405, and P501|Aggregated GHS information provided by 44 companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|P201, P202, P260, P264, P270, P273, P281, P301+P312, P308+P313, P314, P330, P372, P373, P380, P391, P401, P405, and P501|P201, P202, P260, P264, P270, P281, P307+P311, P308+P313, P314, P321, P372, P373, P380, P401, P405, and P501

Wear appropriate chemical protective gloves and goggles. /Lead styphnate, wetted/

If it should dry out, it can explode due to shock, heat, flame, or friction ... Under prolonged exposure to heat or fire /it/ can explode. /Lead styphnate, wetted/

If material on fire or involved in fire: Dangerously explosive. Do not fight fires in a cargo of explosives. Evacuate area and let burn. /Lead styphnate, wetted/|Evacuation: If the material is on fire or involved in fire consider evacuation of one (1) mile radius. /Lead styphnate, wetted/|Wear positive pressure self-contained breathing apparatus when fighting fires involving this material. /Lead styphnate, wetted/

The primary hazard is from blast where the entire load can explode instanteously and not from flying projectiles or fragments. /Lead styphnate, wetted/

Keep material moist. Do not attempt to pick up material. Flush material to explosives disposal tank.

If material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep spilled material wet. Wet spilled material before picking it up. Do not attempt to sweep up dry material. /Lead styphnate, wetted/|Personnel protection: Avoid breathing dusts, and fumes from burning material ... Do not handle broken packages unless wearing appropriate personal protective equipment. Wash away any material which may have contacted the body with copious amounts of water or soap and water. /Lead styphnate, wetted/

D008; A solid waste containing lead may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Lead/

D008; A solid waste containing lead may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Lead/

According to the 2006 TSCA Inventory Update Report, the number of persons reasonably likely to be exposed in industrial manufacturing, processing, and use of lead styphnate is 100 to 999; the data may be greatly underestimated(1).|NIOSH (NOES Survey 1981-1983) has statistically estimated that 3,704 workers (454 of these were female) were potentially exposed to lead styphnate in the US(1).

Carcinogens

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Lead and related compounds/|/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Administer activated charcoal ... . /Lead and related compounds/|/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious or is in severe respiratory distress. Moderate hyperventilation (20 respiration per minute) may be beneficial for increased intracranial pressure. Start IV administration of 0.9% saline (NS) or lactated Ringer's (LR) /SRP: "To keep open", minimal flow rate/. For hypotension ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Lead and related compounds/

/OTHER TOXICITY INFORMATION/ Toxicity of lead-styphnate depends on whether it occurs in water as organic or inorganic lead. Toxicity can then be presumed on the basis of information available about lead.

Explosives manufacturing|1,3-Benzenediol, 2,4,6-trinitro-, lead(2+) salt (1:1): ACTIVE

Health Hazards -> Carcinogens