Diisopropyl tartrate
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Diisopropyl tartrate
structure -
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CAS No:
2217-15-4
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Formula:
C10H18O6
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Chemical Name:
Diisopropyl tartrate
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Synonyms:
Butanedioic acid,2,3-dihydroxy- (2R,3R)-,1,4-bis(1-methylethyl) ester;Tartaric acid,diisopropyl ester,(+)-;Butanedioic acid,2,3-dihydroxy-[R-(R*,R*)]-,bis(1-methylethyl) ester;Butanedioic acid,2,3-dihydroxy- (2R,3R)-,bis(1-methylethyl) ester;Tartaric acid,diisopropyl ester;Diisopropyl tartrate;(+)-Tartaric acid diisopropyl ester;Diisopropyl (+)-tartrate;(+)-DIPT;L-(+)-Diisopropyl tartrate;Diisopropyl L-(+)-tartrate;Bis(1-methylethyl) [R-(R*,R*)]-2,3-dihydroxybutanedioate;Diisopropyl (2R,3R)-tartrate;Diisopropyl L-tartrate;Diisopropyl (+)-L-tartrate;L-(+)-Tartaric acid diisopropyl ester;L-DIPT;Diisopropyl R,R-tartrate;(+)-Diisopropyl L-tartrate;4055-05-4;91007-92-0;116654-05-8;1427677-03-9
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CAS No:
Description
Colorless to light yellow liqui
Diisopropyl tartrate (DIPT) is a diester of tartaric acid. It has a two chiral carbon atoms giving rise to three stereoisomeric variants. It is commonly used in asymmetric synthesis as a catalyst and as chiral building block for pharmaceuticals and agrochemicals. Its main application is in Sharpless epoxidation, where it serves as a chiral ligand to titanium after reaction with titanium isopropoxide.
Characteristics
93.1
0.6
clear, colorless liquid
1.114
150-151°C at 11 mmHg
110 ºC
1.468
Store in a cool, dry place. Store in a tightly closed container.
0.00106mmHg at 25°C
Safety Information
NONH for all modes of transport
3
R36/37/38
S24/25
WW8100000
Xi: Irritant;
S24/25
Computed Properties
Molecular Weight:234.25
XLogP3:0.6
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:7
Exact Mass:234.11033829
Monoisotopic Mass:234.11033829
Topological Polar Surface Area:93.1
Heavy Atom Count:16
Complexity:222
Defined Atom Stereocenter Count:2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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