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(+)-Diisopropyl L-tartrate

(+)-Diisopropyl L-tartrate structure

CAS No:
2217-15-4
Formula:
C10H18O6
Chemical Name:
(+)-Diisopropyl L-tartrate
Synonyms:
2,3-dihydroxy-(R-(R*,R*))-butanedioicacid,bis(1-methylethyl)ester;2,3-dihydroxy-R-R*,R*-butanedioicacid,bis1-methylethylester;2,3-dihydroxy-succinicaciddiisopropylester;Lg-tartaricaciddiisopropylester;Lg-threaricaciddiisopropylester;(2R,3R)-(+)-diisopropyltartrate;(R,R)-2,3-dihydroxy-succinicaciddiisopropylester;L(+)-DIISOPROPYL TARTRATE
Categories:
Biochemical Engineering > Biochemical Reagents

Description

Colorless to light yellow liqui

Diisopropyl tartrate (DIPT) is a diester of tartaric acid. It has a two chiral carbon atoms giving rise to three stereoisomeric variants. It is commonly used in asymmetric synthesis as a catalyst and as chiral building block for pharmaceuticals and agrochemicals. Its main application is in Sharpless epoxidation, where it serves as a chiral ligand to titanium after reaction with titanium isopropoxide.

(+)-Diisopropyl L-tartrate Basic Attributes

Molecular Weight：

234.25

Exact Mass：

234.25

BRN：

1727863

EC Number：

218-709-0

UNII：

7Z907X7UEY

DSSTox ID：

DTXSID70206895

Color/Form：

Clear colorless

HScode：

29181300

Characteristics

PSA：

93.1

XLogP3：

0.6

Appearance：

clear, colorless liquid

Density：

1.114 g/mL at 25 °C (lit.)

Boiling Point：

152 °C/12 mmHg (lit.)

Flash Point：

110 ºC

Refractive Index：

n20/D1.439(lit.)

Storage Conditions：

Store in a cool, dry place. Store in a tightly closed container.

Vapor Pressure：

0.00106mmHg at 25°C

Toxicity：

mouse,LD50,oral,6300uL/kg (6.3mL/kg),Journal of Pharmacology and Experimental Therapeutics. Vol. 93, Pg. 26, 1948.

PKA：

11.70±0.20(Predicted)

Critical Temperature & Pressure：

Refrigerator

Safety Information

Transport codes：

NONH for all modes of transport

wgk germany：

hazard class code：

safety instructions：

24/25-36-26

RTECS Number：

WW8100000

Marks：

Xi: Irritant;

Precautionary statement(s)：

S24/25

Hazard Statements：

36/37/38

(+)-Diisopropyl L-tartrate Use and Manufacturing

(+)-Diisopropyl L-Tartrate is a reagent for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

Both D- and L-forms are reagents for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

Computed Properties

Molecular Weight:234.25
XLogP3:0.6
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:7
Exact Mass:234.11033829
Monoisotopic Mass:234.11033829
Topological Polar Surface Area:93.1
Heavy Atom Count:16
Complexity:222
Defined Atom Stereocenter Count:2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

Synthesis Route

1061180-99-1

1061180-99-1

76110-78-6

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Kaival chemicals Private Limited Contact Supplier

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Trader Supplier of Tartaric acid

Di IsoPropyl L Tartrate 99% Colourless to pale yellow liquid Kaival Chemicals

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Guide of (+)-Diisopropyl L-tartrate

Description
Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
Computed Properties
Synthesis Route
Recommended Suppliers
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(+)-Diisopropyl L-tartrate

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