Tempo
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Tempo
structure -
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CAS No:
2564-83-2
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Formula:
C9H18NO
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Chemical Name:
Tempo
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Synonyms:
1-Piperidinyloxy,2,2,6,6-tetramethyl-;Piperidinooxy,2,2,6,6-tetramethyl-;2,2,6,6-Tetramethyl-1-piperidinyloxy;1,1,5,5-Tetramethylpentamethylene nitroxide;2,2,6,6-Tetramethylpiperidinooxy;2,2,6,6-Tetramethylpiperidine-1-oxyl;2,2,6,6-Tetramethylpiperidine N-oxyl;2,2,6,6-Tetramethylpiperidin-1-oxy;2,2,6,6-Tetramethylpiperidinooxy radical;2,2,6,6-Tetramethylpiperidinoxyl radical;Tanane;Tanan;2,2,6,6-Tetramethylpiperidine N-oxide radical;2,2,6,6-Tetramethylpiperidine N-oxyl radical;2,2,6,6-Tetramethylpiperidinoxyl;2,2,6,6-Tetramethyl-1-piperadoxyl;2,2,6,6-Tetramethylpiperidoxyl;2,2,6,6-Tetramethylpiperidinyloxy;2,2,6,6-Tetramethylpiperidinyl-N-oxy;1-Oxyl-2,2,6,6-tetramethylpiperidine;2,2,6,6-Tetramethyl-1-piperidinoxyl;2,2,6,6-Tetramethyl-1-oxylpiperidine;2,2,6,6-Tetramethylpiperidinooxyl;2,2,6,6-Tetramethylpiperidinyl-1-oxyl;2,2,6,6-Tetramethylpiperidine nitroxide;2,2,6,6-Tetramethyl-1-piperidyloxy;2,2,6,6-Tetramethylpiperidine nitroxide radical;Tempo;2,2,6,6-Tetramethylpiperidinyl 1-oxide;2,2,6,6-Tetramethylpiperidin-1-oxyl radical;HO 6;2,2,6,6-Tetramethylpiperidino-1-oxy;2,2,6,6-Tetramethylpiperidin-N-oxyl;2,2,6,6-Tetramethylpiperidine N-oxy;2,2,6,6-Tetramethylpiperidine N-oxide;2,2,6,6-Tetramethylpiperidine oxide;TMPO;2,2,6,6-Tetramethyl-1-piperidine-N-oxyl;2,2,6,6-Tetramethylpiperidinoxy;T 3751;25657-03-8;26933-82-4;54637-06-8;64104-42-3;125012-91-1;126517-51-9;1357396-80-5
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CAS No:
Description
orange crystals or powder
TEMPO is a member of the class of aminoxyls that is piperidine that carries an oxidanediyl group at position 1 and methyl groups at positions 2, 2, 6, and 6, respectively. It has a role as a ferroptosis inhibitor, a catalyst and a radical scavenger. It is a member of piperidines and a member of aminoxyls.
Characteristics
4.2
1.85 (LogP)
orange crystals or powder
1 g/cm3
35 °C
193ºC
154 °F
Soluble in all organic solvents. Insoluble in water.
2-8ºC
0.4 hPa (20 °C)
Safety Information
Ⅱ
8
3263
3
8
S26-S36/37/39-S45-S24/25
TN8991900
C:Corrosive; Xi:Irritant
Stable. Incompatible with strong acids, strong oxidizing agents. Refrigerate.
P280-P305 + P351 + P338-P310
H314
|Danger|H314 (91.76%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P260, P264, P273, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, and P501|Aggregated GHS information provided by 284 companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Drug Information
Naturally occurring or synthetic substances that inhibit or retard oxidation reactions. They counteract the damaging effects of oxidation in animal tissues. (See all compounds classified as Antioxidants.)
2,2,6,6-tetramethyl-1-piperidinyloxyl
Tempo Use and Manufacturing
TEMPO(2,2,6,6-Tetramethylpiperidinooxy) is a stable radical prepared through the oxidation of 2,2,6,6-tetramethylpiperidine. TEMPO has a wide range of applications including use as a free radical scavenger, a reagent in organic synthe sis and as a structural probe in electron spin resonance spectroscopy. TEMPO can also be used as a mediator in free radical polymerization. In organic chemistry as a radical trap, 2,2,6,6-Tetramethylpiperidinooxy can be used as a catalyst and in polymerization mediation.
1-Piperidinyloxy, 2,2,6,6-tetramethyl-: ACTIVE|PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.
Computed Properties
Molecular Weight:156.25
XLogP3:1.4
Hydrogen Bond Acceptor Count:1
Exact Mass:156.138839198
Monoisotopic Mass:156.138839198
Topological Polar Surface Area:4.2
Heavy Atom Count:11
Complexity:136
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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