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Hexamethylene diacrylate HDDA

TDS 21 Inquiries

Unit Price: Get Latest Price
CAS No.:

13048-33-4

Grade:

Industrail Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2026-01-16

Company Type:
Trader
Location:
China
Qualification:
Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

  • Product Description

  • Seller Information

  • Inquiry History

  • Description
    Product Name: Hexamethylene diacrylate
    Synonyms: HDODA;HEXAMETHYLENE GLYCOL DIACRYLATE;Zinc02019846;1,6-BIS(ACRYLOYLOXY)HEXANE;1,6-HEXANEDIOL DIACRYLATE;1,6-HEXAMETHYLENE DIACRYLATE;Bisacrylic acid 1,6-hexanediyl ester;Bispropenoic acid 1,6-hexanediyl ester
    CAS: 13048-33-4
    MF: C12H18O4
    MW: 226.27
    EINECS: 235-921-9
    Product Categories: Industrial/Fine Chemicals;Diacrylates & Dimethacrylates;monomer;Functional Materials;Reagent for High-Performance Polymer Research
    Mol File: 13048-33-4.mol
    Shop Hexamethylene diacrylate HDDA-Detailed Image 1

    Hexamethylene diacrylate Chemical Properties
    Melting point  6°C
    Boiling point  295°C
    density  1.01 g/mL at 25 °C (lit.)
    vapor density  >1 (vs air)
    vapor pressure  <0.01 mm Hg ( 20 °C)
    refractive index  n20/D 1.456(lit.)
    Fp  >230 °F
    storage temp.  under inert gas (nitrogen or Argon) at 2–8 °C
    solubility  Chlroform (Slightly), DMSO (Slightly)
    form  Liquid
    color  Colourless
    Specific Gravity 1.01
    Odor Mild ester-like odor
    Water Solubility  Slightly miscible with water.
    FreezingPoint  6
    Sensitive  Hygroscopic
    Stability: Light Sensitive
    InChIKey FIHBHSQYSYVZQE-UHFFFAOYSA-N
    LogP 2.81 at 25℃
    CAS DataBase Reference 13048-33-4(CAS DataBase Reference)
    NIST Chemistry Reference Hexamethylene diacrylate(13048-33-4)
    EPA Substance Registry System 1,6-Hexanediol diacrylate (13048-33-4)

    Safety Information
    Hazard Codes  Xi
    Risk Statements  36/38-43
    Safety Statements  39
    RIDADR  UN 3082 9/PG 3
    WGK Germany  2
    RTECS  AT1430000
    TSCA  Yes
    HazardClass  9
    PackingGroup  III
    HS Code  29161290
    Hazardous Substances Data 13048-33-4(Hazardous Substances Data)
    MSDS Information


    Hexamethylene diacrylate Usage And Synthesis
    Description Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.
    Sources
    1. https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
    2. Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
    3. https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf
    Description Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.
    Chemical Properties Colorless transparent liquid
    Uses 1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.
    Uses 1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.
    General Description Clear yellow liquid.
    Air & Water Reactions Insoluble in water.
    Reactivity Profile Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.
    Fire Hazard Hexamethylene diacrylate is probably combustible.

    First aid measures

    If inhaled

    Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

    Following skin contact

    Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

    Following eye contact

    Rinse with pure water for at least 15 minutes. Consult a doctor.

    Following ingestion

    Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

    Accidental release measures


    Personal precautions, protective equipment and emergency procedures

    Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak. Environmental precautions

    Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up

    Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

    Firefighting measures


    Extinguishing media

    Use dry chemical, carbon dioxide or alcohol-resistant foam.

    Specific Hazards Arising from the Chemical

    no data available

    Advice for firefighters

    Wear self-contained breathing apparatus for firefighting if necessary.

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    ——  Q&A  ——

    Q1:Do you provide sample?

    A: Yes, we can provide free sample, you only need pay the shipping cost.

    Q2: What is the lead time?

    A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

    Q3: How can I buy? What is the payment method?

    A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer, 

    Q4:What if there are quality issues?

    A:We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.



    Certificates

    Basic Info
    Product Name:

    1,6-Hexanediol diacrylate

    Other Name:

    2-Propenoic acid,1,1′-(1,6-hexanediyl) ester;Acrylic acid,hexamethylene ester;2-Propenoic acid,1,6-hexanediyl ester;1,6-Hexanediol diacrylate;Hexamethylene diacrylate;Hexamethylene acrylate;Hexamethyleneglycol diacrylate;1,6-Hexanediyl diacrylate;SR 238;1,6-Hexamethylene diacrylate;Sartomer SR 238;Setalux UV 2243;Hexaneglycol diacrylate;HDDA;Kayarad HDDA;Light Acrylate 1,6HX-A;1,6-HDDA;1,6-Hexenediol diacrylate;NK Ester A-HD;C 716;Viscoat 230;Photomer 4017;1,6HX-A;AHD;Sartomer 238;1,6-Hexamethylenediol diacrylate;Kayarad KS-HDDA;Actilane 425;Light Ester 1.6HX-A;Laromer HDDA;HDODA;Hexamethylenediol diacrylate;Genomer 1223;NK Ester A-HD-N;KS-HDDA;SR 238F;AgiSyn 2816;A-HD-N;1.6HX;EM 221;C 6DA;V 230;M 200;SM 626;M 200 (acrylate);Photomer 4017F;SR 2389;EM 221TF;SR 238NS;Light Acrylate SR 238F;SR 238B;FA 126AS;1,2-Bisacryloyloxyhexane;Miramer M 200;1,6-Hexandiol diacrylate;Newfrontier HDDA;LM 254;Hexylene-1,6-diacrylate;Doublemer HDDA;Cognis 4017;Fancryl FA 126AS;1,6-Hexyleneglycol diacrylate;SR 238TFN;EM 2021;74872-03-0;88250-32-2;106717-06-0;126038-89-9;174845-65-9;181826-08-4;198694-76-7;671774-75-7;1220287-86-4;1934258-74-8

    CAS No.:

    13048-33-4

    Molecular Formula:

    C12H18O4

    InChIKeys:

    InChIKey=FIHBHSQYSYVZQE-UHFFFAOYSA-N

    Molecular Weight:

    226.27

    Exact Mass:

    226.27

    EC Number:

    235-921-9

    UNII:

    FY751V5MMY

    UN Number:

    3082

    DSSTox ID:

    DTXSID9025401

    HScode:

    29161290

    Characteristics
    PSA:

    52.6

    XLogP3:

    2.6

    Appearance:

    1,6-hexanediol diacrylate is a clear yellow liquid. (NTP, 1992)

    Density:

    1.01 g/cm3

    Melting Point:

    <25 °C

    Boiling Point:

    158-165 °C @ Press: 5 Torr

    Flash Point:

    >230 °F

    Refractive Index:

    n 20/D 1.456(lit.)

    Water Solubility:

    Slightly miscible with water.Insoluble in water.

    Storage Conditions:

    The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. Moisture may cause rust-initiated polymerization. /Acrylic acid & derivatives/

    Vapor Pressure:

    <0.01 mm Hg ( 20 °C)

    Vapor Density:

    >1 (vs air)

    Henrys Law Constant:

    Henry's Law constant = 3.7X10-8 atm cu m/mol @ 25 °C /Estimated/

    Experimental Properties:

    Reacts readily with electrophilic, free-radical, and nucleophilic agents /Acrylic acids and esters/|Hydroxyl radical reaction rate constant = 2.7X10-11 cu cm/molecule-sec @ 25 °C /Estimated/

    Air and Water Reactions:

    Insoluble in water.

    Reactive Group:

    Acrylates and Acrylic Acids

    Reactivity Alerts:

    Polymerizable

    Reactivity Profile:

    1,6-HEXANEDIOL DIACRYLATE is temperature sensitive (NTP, 1992). May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.

    Hazard Identification

    Classification of the substance or mixture

    Skin irritation, Category 2

    Eye irritation, Category 2

    Skin sensitization, Category 1

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Warning

    Hazard statement(s)

    H315 Causes skin irritation

    H319 Causes serious eye irritation

    H317 May cause an allergic skin reaction

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

    P272 Contaminated work clothing should not be allowed out of the workplace.

    Response

    P302+P352 IF ON SKIN: Wash with plenty of water/...

    P321 Specific treatment (see ... on this label).

    P332+P317 If skin irritation occurs: Get medical help.

    P362+P364 Take off contaminated clothing and wash it before reuse.

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P333+P317 If skin irritation or rash occurs: Get medical help.

    Storage

    none

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. Moisture may cause rust-initiated polymerization. Acrylic acid & derivatives

  • Seller Information
    Business Type:

    Trader

    Main Products:

    pharmaceutical intermediates,peptides,electronic chemicals

    Location:

    Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

    Payment Terms:

    100% TT in advance

    Average lead Time:

    10

    Total Annual Revenue:

    $10 million-$25 million

    Total Employees:

    51-100

    Year of Establishment:

    2024

    A reliable supplier is like insurance.

    We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals,food additives, and other fine chemical products.
    Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

    Website: orientchem.cc
    Email: scarlett@orientchem.cc
    WhatsApp: +86 17753254221

  • Inquiry History
    21 Inquiries
    Country Product Purchase Quantity Date Posted
    India

    HDDA 1,6 Hexanediol Diacrylate

    1.00 MT Jan 8, 2024
    India

    HDDA 1,6 Hexanediol Diacrylate

    1.00 MT Nov 21, 2023
    India

    HDDA 1,6 Hexanediol Diacrylate

    1.00 20' Fcl Sep 22, 2023
    India

    HDDA 1,6 Hexanediol Diacrylate

    1.00 MT Aug 24, 2023
    India

    HDDA 1,6 Hexanediol Diacrylate

    1.00 MT Dec 15, 2023
    India

    1,6-Hexanediol Diacrylate

    200 KG May 22, 2025
    South Korea

    1, 6-Hexanediol Diacrylate

    20 KG Apr 11, 2025
    Turkey

    Sample product

    1 KG May 27, 2024
    United States

    1, 6-Hexanediol Diacrylate

    1 KG Jul 23, 2025
    United States

    1, 6-Hexanediol Diacrylate

    1 KG Jul 22, 2025
    India

    1,6-Hexanediol Diacrylate

    500 KG May 9, 2025
    India

    Hexanediol diacrylate

    6 MT Mar 14, 2024
    India

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    10.00 MT Jan 8, 2024
    India

    Sorbitol Liquid 70%

    10.00 MT Jan 8, 2024
    India

    2-Hydroxypropyl Methacrylate (HPMA)

    1.00 20' Fcl Sep 22, 2023
    India

    Paraformaldehyde (PFA)

    1.00 MT Aug 24, 2023
    India

    TCCA 90% Trichloroisocyanuric Acid Chlorine Tablet Granular Powder for swimming pool

    1.00 MT Aug 24, 2023
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    Glycine

    1.00 20' Fcl Sep 22, 2023
    India

    Sodium formate

    1.00 MT Aug 24, 2023
    India

    2-Hydroxyethyl Methacrylate

    20.00 MT Aug 24, 2023
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